| Identification | More | [Name]
(R)-(-)-Benzyl glycidyl ether | [CAS]
14618-80-5 | [Synonyms]
(-)-BENZYL (R)-GLYCIDYL ETHER
BENZYL (R)-(-)-GLYCIDYL ETHER
BENZYL (R)-GLYCIDYL ETHER
(R)-(-)-1-BENZYLOXY-2,3-EPOXYPROPANE
(R)-1-BENZYLOXY-2,3-EPOXYPROPANE
(R)-(-)-2-(BENZYLOXYMETHYL)OXIRANE
RARECHEM AK HZ 0049
(R)-(-)-BENZYL GLYCIDYL ETHER
(R)-BENZYL GLYCIDYL ETHER
(R)-BENZYLOXYMETHYL-OXIRANE
(r)-o-benzylglycidol
3-epoxy-1-(benzyloxy)-(r)-propan
3-epoxy-1-(benzyloxy)-(s)-propan
2'O-Me-rC(tac) CPG500
DL-Arg(NO2)-OBzl.TosOH
Z-DL-Gln-OH
5-TMP,2Na
(S)-tert-butyl 2-propylazetidine-1-carboxylate
1-(4-isopropoxyphenyl)piperazine
1-(benzyloxycarbonyl)-4-(tert-butoxycarbonyl)piperazine-2-carboxylic acid | [Molecular Formula]
C10H12O2 | [MDL Number]
MFCD00068409 | [Molecular Weight]
164.2 | [MOL File]
14618-80-5.mol |
| Chemical Properties | Back Directory | [Appearance]
Colorless to light yellow liqui | [Melting point ]
88-93°C | [alpha ]
-5.4 º (c=5 in toluene) | [Boiling point ]
130 °C (0.1 mmHg)
| [density ]
1.077 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.517(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
2-8°C | [form ]
paste (yellow) | [Specific Gravity]
1.077 | [optical activity]
[α]20/D 5.4°, c = 5 in toluene | [Water Solubility ]
Soluble in water. | [Detection Methods]
HPLC,Optical Rotatory Dispersion | [BRN ]
3588399 | [CAS DataBase Reference]
14618-80-5(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
NA 1993 / PGIII | [WGK Germany ]
3
| [RTECS ]
TX2860020
| [HS Code ]
29109000 | [Toxicity]
mic-sat 660 nmol/plate MUREAV 298,197,1993 |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless to light yellow liqui | [Uses]
Used in the preparation of the lactone fragment of compactin and mevinolin. Chiron in the preparation of syn-1,3-polyols, dideoxynucleosides, and a spiroacetal cyanohydrin. | [Synthesis Reference(s)]
Tetrahedron Letters, 21, p. 4807, 1980 DOI: 10.1016/0040-4039(80)80145-6 | [General Description]
1H-Pyrazol-3-ylboronic acid hydrate can be used as a reactant in the Suzuki-Miyaura coupling reaction to synthesize pyrazole derivatives by reacting with different aryl halides over the palladium catalyst. | [Safety Profile]
Mutation data reported. Whenheated to decomposition it emits acrid smoke andirritating vapors. | [Purification Methods]
This ether in EtOAc is dried (Na2SO4), then purified by flash chromatography using pet ether/EtOAc (5:1) as eluent. The ether distils through a short path distillation apparatus (Kügelrohr) as a colourless liquid. Alternatively, dissolve it in CHCl3, wash it with H2O, dry (Na2SO4), evaporate and purify by silica gel chromatography. [Anisuzzamen & Owen J Chem Soc 1021 1967, Takano et al. Heterocycles 1 6 381 1981, Lipshutz et al. Org Synth 69 82 1990, Takano et al. Synthesis 539 1989, Honda et al. Chem Pharm Bull Jpn 39 1385 1991, Beilstein 12 IV 2277.] |
|
|