ChemicalBook--->CAS DataBase List--->15699-18-0

15699-18-0

15699-18-0 Structure

15699-18-0 Structure
IdentificationMore
[Name]

NICKEL AMMONIUM SULFATE
[CAS]

15699-18-0
[Synonyms]

AMMONIUM NICKEL(II) SULFATE
AMMONIUM NICKEL SULPHATE
NICKEL AMMONIUM SULFATE
NICKEL (II) AMMONIUM SULFATE
ammoniumdisulfatonickelate(ii)
Ammoniumnickelsulfate
Ammoniumnickelsulfate,hexah
ammoniumnickelsulfatehexahydrat
nickelammoniumsulfate(ni(nh4)2(so4)2)
Sulfuricacid,ammoniumnickel(2+)salt(2:2:1)
sulfuricacid,ammoniumnickel(2++)salt(2:2:1)
SulfuricAcid,AmmoniumNickelSalt
Ammoninm nickel sulfate
Ammonium disulfatonickelate
diammonium nickel bis(sulphate)
ammonium nickelous sulfate
double nickel salt
NICKEL AMMONIUM SULPHATE
NICKELAMMONIUMSULFATE,CRYSTAL,REAGENT
[EINECS(EC#)]

239-793-5
[Molecular Formula]

H8N2NiO8S2
[MDL Number]

MFCD00016251
[Molecular Weight]

286.9
[MOL File]

15699-18-0.mol
Chemical PropertiesBack Directory
[Appearance]

Nickel ammonium sulfate is a green, odorless powder.
[Melting point ]

85-89 °C(lit.)
[density ]

1.929
[solubility ]

slightly soluble in H2O
[color ]

blue-green crystals, crystalline
[Specific Gravity]

1.923
[Stability:]

Stable.
[Water Solubility ]

6.5@20
[Uses]

Nickel electrolyte for electroplating.
[CAS DataBase Reference]

15699-18-0(CAS DataBase Reference)
[EPA Substance Registry System]

Nickel ammonium sulfate (15699-18-0)
Safety DataBack Directory
[Hazard Codes ]

T
[Risk Statements ]

R45:May cause cancer.
R22:Harmful if swallowed.
R42/43:May cause sensitization by inhalation and skin contact .
[Safety Statements ]

S53:Avoid exposure-obtain special instruction before use .
S22:Do not breathe dust .
S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[WGK Germany ]

3
[RTECS ]

WS6061000
[Safety Profile]

Confirmed human carcinogen. Poison by ingestion. When heated to decomposition it emits toxic fumes of NOx, SOx, and Ni.
[Hazardous Substances Data]

15699-18-0(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ammonium sulfate-->Nickel sulfate
[Preparation Products]

Nickel(II) oxide
Hazard InformationBack Directory
[General Description]

NICKEL AMMONIUM SULFATE(15699-18-0) is a green crystalline solid. Mildly toxic, carcinogenic. When heated to decomposition NICKEL AMMONIUM SULFATE(15699-18-0) emits highly toxic fumes of metallic nickel, oxides of sulfur, and oxides of nitrogen (Lewis, 3rd ed., 1993, p. 910). The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. NICKEL AMMONIUM SULFATE(15699-18-0) is used for electroplating nickel.
[Reactivity Profile]

NICKEL AMMONIUM SULFATE is a "double salt" that is a weak oxidizing agent. Gives an acidic solution when dissolved in water.
[Air & Water Reactions]

Water soluble. Forms an acidic aqueous solution.
[Hazard]

See nickel
[Health Hazard]

Inhalation causes irritation of nose and throat. Ingestion causes vomiting. Contact with eyes causes irritation. Contact with skin may cause dermatitis.
[Potential Exposure]

This material is used in electroplating.
[Fire Hazard]

Special Hazards of Combustion Products: Toxic oxides of nitrogen may be formed in fire.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility for medical observation up to 2 days and tests for urine nickel. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Medical observation is recommended for 24 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy.
[Shipping]

UN3288 Toxic solids, inorganic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard Class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
[Incompatibilities]

Forms an acidic solution with water. A weak oxidizer; keep away from combustible materials, reducing agents, including hydrides. Possible violent reaction with strong acids. Incompatible with nickel nitrate, sulfur, selenium, wood, organics, and other combustibles.
[Chemical Properties]

dark green crystals
[Chemical Properties]

Nickel ammonium sulfate is a green, odorless powder.
[Definition]

ChEBI: A nickel coordination entity comprising ammonium, nickel and sulfate in which the ratio of ammonium to iron(2+) to sulfate ions is 2:1:2.
[Purification Methods]

Crystallise this salt from water (3mL/g) on cooling from 90o to 0o.
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