| Identification | Back Directory | [Name]
Serpentinine | [CAS]
36519-42-3 | [Synonyms]
Serpentinine
3,5,6,16,17-Pentadehydro-6-[(16S,19E)-19,20-didehydro-16-(methoxycarbonyl)corynan-17-yl]-16-methoxycarbonyl-19α-methyl-18-oxayohimban-4-ium
OxayohiMbaniuM, 3,4,5,6,16,17-hexadehydro-6-[ (16S,19E)-19, 20-didehydro-16-(Methoxycarbonyl)corynan-17-yl]-16-(Methoxycarbony l)-19-Methyl-, (19.alpha.)- | [Molecular Formula]
C42H45N4O5+ | [MOL File]
36519-42-3.mol | [Molecular Weight]
685.84 |
| Hazard Information | Back Directory | [Description]
Also present in Rauwolfia serpentina Benth, this base was originally given the empirical formula C20H2005N2, later shown to be dimeric. It yields a hydrochloride, m.p. 27l-2°C (dec.);[α]34D + 166.93° (H20); aurichloride, m.p.
194-5°C (dec.) and a picrate, m.p. 263-4°C. | [References]
Siddiqui, Siddiqui.,J. Ind. Chem. Soc., 8,667 (1931)
Siddiqui, Siddiqui., ibid, 9, 539 (1932)
Siddiqui, Siddiqui., ibid, 12, 37 (1935)
Crystal structure:
lrie et al., J. Chem. Soc., Chem. Commun., 871 (1972) |
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