ChemicalBook--->CAS DataBase List--->5267-64-1

5267-64-1

5267-64-1 Structure

5267-64-1 Structure
IdentificationMore
[Name]

D(+)-Phenylalaninol
[CAS]

5267-64-1
[Synonyms]

BENZENEPROPANOL, B-AMINO-, (BR)-
D(+)-2-AMINO-3-PHENYL-1-PROPANOL
D-2-PHENYLALANINOL
D-ALPHA-PHENYLALANINOL
(+)-D-PHENYLALANINOL
D(+)-PHENYLALANINOL
D-PHENYLALANINOL
D-(R)-PHENYLALANINOL
H-D-PHENYLALANINOL
H-D-PHE-OL
PHENYLALANINOL-D
(R)-(+)-2-AMINO-3-PHENYL-1-PROPANOL
(R)-2-AMINO-3-PHENYL-1-PROPANOL
(R)-2-AMINO-3-PHENYL-PROPAN-1-OL
(R)-(+)-PHENYLALANINOL
(R)-PHENYLALANINOL
(R)-2-amino-3-phenylpropanol
D-(+)-Phenylalinol
S/R-Phenylalaninol
(2R)-2-amino-3-phenylpropan-1-ol
[EINECS(EC#)]

226-086-1
[Molecular Formula]

C9H13NO
[MDL Number]

MFCD00064298
[Molecular Weight]

151.21
[MOL File]

5267-64-1.mol
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystal powde
[Melting point ]

93-95 °C(lit.)
[alpha ]

23 º (c=1.2, 1 N HCl 22 ºC)
[Boiling point ]

122 °C / 4mmHg
[density ]

1.0406 (rough estimate)
[refractive index ]

23.5 ° (C=1.2, 1mol/L HCl)
[storage temp. ]

0-6°C
[solubility ]

Soluble in Dichloromethane, Ethyl Acetate, Methanol.
[form ]

Crystalline Powder and Chunks
[pka]

12.85±0.10(Predicted)
[color ]

White to yellow
[optical activity]

[α]/D +22.8°, c = 1.2 in 1 M HCl
[Sensitive ]

Air Sensitive
[Detection Methods]

GC,NMR,Rotation
[BRN ]

4665408
[CAS DataBase Reference]

5267-64-1(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

C,Xi
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S27:Take off immediately all contaminated clothing .
[RIDADR ]

UN 3259 8/PG 3
[WGK Germany ]

3
[F ]

10-23
[HazardClass ]

8
[HazardClass ]

IRRITANT
[PackingGroup ]

III
[HS Code ]

29221990
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

D(+)-Phenylalaninol(5267-64-1).msds
Questions And AnswerBack Directory
[Detected method]

Phenomena, including gelation and fluorescence, are used as easily detected sensors of chiral recognition. Qin et al. have developed a new type of isomerized diphenylalanine-based supramolecular gel (LFDF), which showed the visible enantiomeric discrimination of phenylalaninol enantiomers via fluorescence and gelation measurements. The addition of L- or D-phenylalaninol to the peptide gel led to complete collapse within one minute after adding the L-form, which was not observed in D-phenylalaninol. Meanwhile, by doping with the fluorescent dye thioflavin T (ThT), the prepared ThT-LFDF gel system can sensitively detect the L/D-phenylalanine enantiomer through fluorescence quenching, which has the advantages of visualization, easy manipulation, and high detection sensitivity.
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow crystal powde
[Uses]

Enantiomer of L-Phenylalaninol, an inhibitor of intestinal Phenylalanine absorption.
[Purification Methods]

It can be recrystallised from Et2O, *C6H6/pet ether (b 40-60o) or toluene and distilled in a vacuum. It has been purified by dissolving in Et2O, drying over K2CO3, filtering, evaporating to a small volume, cooling in ice and collecting the plates. Store them in the presence of KOH (i.e. CO2—free atm). [Karrer & Ehrhardt Helv Chim Acta 34 3203 1951, Oeda Bull Chem Soc Jpn 13 465 1938.] The picrate has m 141-141.5o (from EtOH/pet ether). The hydrogen oxalate has m 177o, 161-162o [Hunt & McHale J Chem Soc 2073 1957]. The racemate has m 87-88o from *C6H6/pet ether (75-77o from Et2O), and the hydrochloride has m 139-141o [Fodor et al. J Chem Soc 1858 1951]. [Beilstein 13 IV 1920.]
Spectrum DetailBack Directory
[Spectrum Detail]

D(+)-Phenylalaninol(5267-64-1)MS
D(+)-Phenylalaninol(5267-64-1)1HNMR
D(+)-Phenylalaninol(5267-64-1)13CNMR
D(+)-Phenylalaninol(5267-64-1)IR1
D(+)-Phenylalaninol(5267-64-1)IR2
D(+)-Phenylalaninol(5267-64-1)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

D(+)-2-Amino-3-phenyl-1-propanol, 98%(5267-64-1)
[Alfa Aesar]

D-Phenylalaninol, 98%(5267-64-1)
[Sigma Aldrich]

5267-64-1(sigmaaldrich)
[TCI AMERICA]

D-Phenylalaninol,>98.0%(T)(5267-64-1)
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