ChemicalBook--->CAS DataBase List--->88284-48-4

88284-48-4

88284-48-4 Structure

88284-48-4 Structure
IdentificationBack Directory
[Name]

2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE
[CAS]

88284-48-4
[Synonyms]

(TriMethylsilyl)phenyl Triflate
2-(Trimethylsilyl)phenyl Triflate
TriMethylsilyl)phenyl trifluoroMethanesulfona
2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFOTE
2-(trimethylsilyl)phenyl trifluoromethane-sulfona
2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE
2-(TriMethylsilyl)phenyl trifluoroMethanesulfonate 97%
Trifluoromethanesulfonic Acid 2-(Trimethylsilyl)phenyl Ester
Methanesulfonic acid, 1,1,1-trifluoro-, 2-(trimethylsilyl)phenyl ester
2-(Trimethylsilyl)phenyl Triflate Trifluoromethanesulfonic Acid 2-(Trimethylsilyl)phenyl Ester
[Molecular Formula]

C10H13F3O3SSi
[MDL Number]

MFCD00799598
[MOL File]

88284-48-4.mol
[Molecular Weight]

298.35
Chemical PropertiesBack Directory
[Boiling point ]

70 °C2 mm Hg(lit.)
[density ]

1.229 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.456(lit.)
[Fp ]

205 °F
[storage temp. ]

Inert atmosphere,2-8°C
[form ]

clear liquid
[color ]

Colorless to Light yellow
[Specific Gravity]

1.229
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[InChIKey]

XBHPFCIWRHJDCP-UHFFFAOYSA-N
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

34
[Safety Statements ]

26-27-36/37/39-45
[RIDADR ]

UN 3265 8/PG 2
[WGK Germany ]

3
[HazardClass ]

8
[PackingGroup ]

[HS Code ]

29319090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Diethyl ether-->Sodium-->Toluene-->n-Butyllithium-->Chlorotrimethylsilane-->Trifluoromethanesulfonic anhydride-->2-Chlorophenol
[Preparation Products]

Triphenylene-->Thianaphthene-->2-NITRO-6(5H)-PHENANTHRIDINONE-->3-Chloro-1,2-benzisothiazole-->4-Fluoro-N,N-diphenylbenzenamine-->1,2-Diiodobenzene-->1H-Indazole-3-carboxylic acid, 1-phenyl-, ethyl ester-->PHENYL P-TOLYL SULFONE-->DIETHYL PHENYLPHOSPHONATE
Hazard InformationBack Directory
[Physical properties]

bp 70 °C/2 mmHg; d 1.229 g mL?1
[Uses]

2-(Trimethylsilyl)phenyl Triflate is a useful reagent applied in reactions of Polycyclic Arenes, Heteroatom Arylation,Heteroarenes and Benzannulated Heterocycles, Carbon Arylations, etc.

[General Description]

2-(Trimethylsilyl)phenyl trifluoromethanesulfonate is an important ortho-benzyne precursor in aryne chemistry.
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