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(p-Chlorphenyl)metaborsure

4-Chlorophenylboronic acid Struktur
1679-18-1
CAS-Nr.
1679-18-1
Bezeichnung:
(p-Chlorphenyl)metaborsure
Englisch Name:
4-Chlorophenylboronic acid
Synonyma:
4-CHLOROBENZENEBORONIC ACID;AC 34441;NSC 25408;WLN: QBQR DG;AKOS BRN-0011;RARECHEM AH PB 0178;orobenzeneboronic Acid;p-chlorophenylboronic aci;4-Chlorophenylbronic Acid;The effects of boric acid
CBNumber:
CB0307561
Summenformel:
C6H6BClO2
Molgewicht:
156.37
MOL-Datei:
1679-18-1.mol
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(p-Chlorphenyl)metaborsure Eigenschaften

Schmelzpunkt:
284-289 °C(lit.)
Siedepunkt:
295.4±42.0 °C(Predicted)
Dichte
1.32±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
Löslichkeit
DMSO
pka
8.39±0.10(Predicted)
Aggregatzustand
Crystalline Powder
Farbe
Off-white to beige
Wasserlöslichkeit
2.5 g/100 mL
BRN 
2936346
InChI
InChI=1S/C6H6BClO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H
InChIKey
CAYQIZIAYYNFCS-UHFFFAOYSA-N
SMILES
B(C1=CC=C(Cl)C=C1)(O)O
CAS Datenbank
1679-18-1(CAS DataBase Reference)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xn,Xi
R-Sätze: 20/21/22-36/37/38
S-Sätze: 36-37/39-26
WGK Germany  3
RTECS-Nr. CY8950000
TSCA  No
HazardClass  IRRITANT
HS Code  29319090
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H302 Gesundheitsschädlich bei Verschlucken. Akute Toxizität oral Kategorie 4 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P270, P301+P312, P330, P501
Sicherheit

(p-Chlorphenyl)metaborsure Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R20/21/22:Gesundheitsschädlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

S-Sätze Betriebsanweisung:

S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.

Chemische Eigenschaften

4-Chlorophenylboronic acid is white or off-white crystalline powder. It has certain solubility in water and is soluble in strong polar organic solvents such as dimethyl sulfoxide, but insoluble in ether solvents. It has similar chemical properties to phenylboronic acid.

Chemische Eigenschaften

off-white to beige crystalline powder

Verwenden

4-Chlorophenylboronic acid can be used as a reactant in:
  • Palladium-catalyzed direct arylation.
  • Cyclopalladation.
  • Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation.
  • Copper-mediated ligandless aerobic fluoroalkylation.
  • Pd-catalyzed arylative cyclization.
  • Ruthenium catalyzed direct arylation.
  • Ligand-free copper-catalyzed coupling reactions.
  • Regioselective arylation and alkynylation by Suzuki-Miyaura and Sonogashira cross-coupling reactions.

It can also be used to prepare:
  • Substituted diarylmethylidenefluorenes via Suzuki coupling reaction.
  • Baclofen lactam by Suzuki coupling of a pyrrolinyl tosylate, followed by hydrogenation reaction.
  • Palladium(II) thiocarboxamide complexes as Suzuki coupling catalysts.
  • Biaryls by Suzuki reactions of aryl chlorides, bromides, and iodides with arylboronic acids.

(p-Chlorphenyl)metaborsure Upstream-Materialien And Downstream Produkte

Upstream-Materialien

4-CHLOROPHENYL TRIFLUOROMETHANESULFONATE Tributylborat Tripropylborat 1,4-Dichlorbenzol

Downstream Produkte

6-(4-CHLOROPHENYL)PYRIDINE-2-CARBALDEHYDE 2-chloro-4-(4-chlorophenyl)-6-phenyl-1,3,5-triazine 2-[4-(4-Chlorbenzoyl)phenoxy]-2-methylpropionsure AZD4320 4'-Chlorbiphenyl-4-ylamin 4'-CHLORO-BIPHENYL-3-CARBOXYLIC ACID 5-(4-CHLOROPHENYL)-2-FURALDEHYDE Dexchlorpheniramin 4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)CHLOROBENZENE 4,4'-dichlor-α-phenylbenzylalkohol 4'-Chloro-2-phenylacetophenone

(p-Chlorphenyl)metaborsure Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 696)Lieferanten
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1679-18-1((p-Chlorphenyl)metaborsure)Verwandte Suche:

4-Chlorbenzoesure Natrium-(4-chlorphenoxy)acetat Dipikrylamin 4-Chlorbenzaldehyd Benzolboronsäure 4-Fluorobenzeneboronic acid gamma-(4-Chlorphenyl)-N,N-dimethyl-2-pyridin-propanamin-,(Z)-2-butendioat (1:1) 1,2,4-Trichlorbenzol Borsure, Zinksalz 1-Chlor-4-nitrobenzol p-Dichlorobenzene PARA NITRO CHLOROBENZENE (PNCB) (p-Chlorphenyl)metaborsure
  • 4-Chlorophenylboronic acid,97%
  • 4-Chlorophenylboronic acid, May contain varying amounts of anhydride, 97%
  • 4-Chlorophenylboronic acid,4-Chlorobenzeneboronic acid
  • p-chlorophenylboronic aci
  • (4-chlorophenyl)boronic acid(SALTDATA: 0.7H2O)
  • 4-Chlorophenylboronic acid, 97% 5GR
  • NSC 25408
  • BORONIC ACID, (4-CHLOROPHENYL)-;P-CHLOROBENZENEBORONIC ACID;
  • p-chloro-benzeneboronicaci
  • (p-chlorophenyl)metaboric acid
  • 4-Chlorophenylboronicacid,min.97%
  • 4-CHLOROBENZENEBORONIC ACID / 4-CHLOROPHENYLBORONIC ACID
  • PARACHLOROPHENYLBORONIC ACID
  • 4-Chlorophenylboronic acid ,98%
  • 4-Chlorophenylboronic acid, min. 97%
  • (4-Chlorophenyl)boranic acid
  • 4-Chlorophenylboranic acid
  • 4-Chlorophenylboron dihydoxide
  • 4-Chlorobenzeneboronic acid, 98+%
  • 4-Chlorophenylboronic Acid (contains varying amounts of Anhydride)
  • 4-Chlorophenylbronic Acid
  • The effects of boric acid
  • 4-Chlorophenylboronic acid 95%
  • AC 34441
  • Benzeneboronic acid, p-chloro-
  • WLN: QBQR DG
  • B-(4-Chlorophenyl)boronic acid
  • BORONIC ACID, (4-CHLOROPHENYL)-
  • AKOS BRN-0011
  • 4-CHLOROPHENYLBORNIC ACID
  • 4-CHLOROPHENYLBORONIC ACID
  • P-CHLOROPHENYLBORONIC ACID
  • P-CHLORO BENZENE BORONIC ACID
  • RARECHEM AH PB 0178
  • boronicacid,p-chlorophenyl
  • orobenzeneboronic Acid
  • 4-Chlorophenylboronic acid,99%
  • Boronic acid, B-(4-chlorophenyl)-
  • 4-Chlorophenylboronic Acid extrapure, 97%
  • 4-CHLOROBENZENEBORONIC ACID
  • 4-Chlorophenylboornic acid
  • 4-Chlorophenylboronic acid supplier in China CAS NO.1679-18-1 CAS NO.1679-18-1
  • 13C6]-4-Chlorobenzeneboronic acid
  • 1679-18-1
  • 1679-81-1
  • B (Classes of Boron Compounds)
  • Boronic Acids
  • Organometallic Reagents
  • Boronic Acids and Derivatives
  • Aryl
  • blocks
  • BoronicAcids
  • Boronic Acid series
  • Fluorin-contained phenyl boronic acid series
  • Heterocyclic Compounds
  • Boronic Acid
  • Aryl
  • Organoborons
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