Carboxyferrocen

Ferrocenecarboxylic acid Struktur
1271-42-7
CAS-Nr.
1271-42-7
Bezeichnung:
Carboxyferrocen
Englisch Name:
Ferrocenecarboxylic acid
Synonyma:
FEPRAZONE;CARBOXYFERROCENE;Ferocene monocarboxylic acid;Ferroncene Monocarboxylic Acid;Cyclopentadienecarboxylic acid;cyclopenta-2,4-diene-1-carboxylic acid;(CARBOXYCYCLOPENTADIENYL)-CYCLOPENTADIENYLIRON;JACS-1271-42-7;Ferrocenoic acid;Carboxylferrocene
CBNumber:
CB3215027
Summenformel:
C11H10FeO210*
Molgewicht:
230.04
MOL-Datei:
1271-42-7.mol

Carboxyferrocen Eigenschaften

Schmelzpunkt:
210 °C (dec.)(lit.)
storage temp. 
Inert atmosphere,Room Temperature
Löslichkeit
Chloroform (Sparingly), DMSO (Slightly), Methanol (Slightly)
Aggregatzustand
crystal
Farbe
yellow
Wasserlöslichkeit
Insoluble in water.
Expositionsgrenzwerte
ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3
Stabilität:
Stable. Incompatible with strong oxidizing agents.
InChI
InChI=1S/C6H5O2.C5H5.Fe/c7-6(8)5-3-1-2-4-5;1-2-4-5-3-1;/h1-4H,(H,7,8);1-5H;
InChIKey
VUJLGCHOGQEAED-UHFFFAOYSA-N
SMILES
[C]1(C(=O)O)[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1.[Fe] |^1:0,4,5,6,7,8,9,10,11,12|
CAS Datenbank
1271-42-7(CAS DataBase Reference)
NIST chemische Informationen
Ferrocene carboxylic acid(1271-42-7)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xn
R-Sätze: 36/37/38-22
S-Sätze: 37/39-26
WGK Germany  3
HS Code  29319090
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizität (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
Sicherheit
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.

Carboxyferrocen Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R22:Gesundheitsschädlich beim Verschlucken.

S-Sätze Betriebsanweisung:

S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.

Beschreibung

Ferrocenecarboxylic acid is a metal-organic compound characterized by connecting two ferrocene molecules through a carboxy ligand. Notably, ferrocene is a stable yet highly reactive metal-organic compound that has been extensively researched due to its potential applications in catalysis, materials science, and medicine. It serves as a catalyst in catalysis, facilitating the synthesis of diverse compounds through polymerization, oxidation, and reduction reactions. In materials science, it acts as a fundamental molecular building block for synthesizing polymers and nanomaterials. Although the precise mechanism of action of Ferrocenecarboxylic acid remains fully elucidated, it is believed that the carboxy ligand binds to the ferrocene molecules, forming a stable complex. This complex, in turn, engages with other molecules, including proteins, to facilitate various reactions[1-2].

Chemische Eigenschaften

dark brown powder

läuterung methode

It crystallises as yellow crystals from pet ether (m 225-230odec), CHCl3 (m 208.5odec), toluene/pet ether (m 195-205odec), or aqueous ethanol. [Matsue et al. J Am Chem Soc 107 3411 1985.] The acid chloride m 49o crystallises from pentane, and has max at 458nm [Lau & Hart J Org Chem 24 280 1959]. The methyl ester crystallises from aqueous MeOH with m 70-71o. The anhydride has m 143-145o when recrystallised from pet ether [Acton & Silverstein J Org Chem 24 1487 1959]. The amide has m 168-170o when crystallised from CHCl3/Et2O or m 167-169o when crystallised from *C6H6/MeOH. [Arimoto & Haven J Am Chem Soc 77 6295 1955, Benkeser et al. J Am Chem Soc 76 4025 1954.] [Beilstein 16 IV 1807.]

Carboxyferrocen Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Carboxyferrocen Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 351)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Jinan Qinmu Fine Chemical Co.,Ltd.
+8618660799346
sales@qinmuchem.com China 1009 58
Shaanxi Dideu Medichem Co. Ltd
+86-29-81148696 +86-15536356810
1022@dideu.com China 3882 58
Hebei Mojin Biotechnology Co., Ltd
+86 13288715578 +8613288715578
sales@hbmojin.com China 12835 58
Hebei Yanxi Chemical Co., Ltd.
+8617531190177
peter@yan-xi.com China 5858 58
Hebei Chuanghai Biotechnology Co,.LTD
+86-13131129325
sales1@chuanghaibio.com China 5893 58
Hebei Weibang Biotechnology Co., Ltd
+8617732866630
bess@weibangbio.com China 18155 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652
info@fdachem.com China 20288 58
Capot Chemical Co.,Ltd.
+86-(0)57185586718 +86-13336195806
sales@capot.com China 29791 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21637 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795
ivan@atkchemical.com China 32951 60

1271-42-7(Carboxyferrocen)Verwandte Suche:


  • FERROCENE MONOCARBOXYLIC ACID
  • FERROCENE, CARBOXY-
  • FERROCENECARBOXYLIC ACID
  • FERROENECARBOXYLIC ACID
  • Ferrocenemonocarboxylicacid,min.97%
  • FERROCENECARBOXYLIC ACID (controlled chemical)
  • Ferrocene monocarboxylic acid, min. 97%
  • Ferrocenecarboxylic acid,97%
  • Ferrocenecarboxylic acid ,98%
  • Ferrocenecarboxylic acid 97%
  • Cyclopentadienecarboxylic acid ferrocenoic acid
  • Ferrocenecarboxylic acid≥ 99% (HPLC)
  • Ferrocenecarboxylic acid puruM, >=97.0% (Fe)
  • Carboxylferrocene
  • Ferrocenoic acid
  • Ferrocenecarboxylic acid, >=99%
  • FerrocenecarboxyL
  • JACS-1271-42-7
  • FerrocenecarboxylicAcid>
  • Ferrocenecarboxylic acid ISO 9001:2015 REACH
  • Ferrocene, carboxy- (9CI)
  • (CARBOXYCYCLOPENTADIENYL)-CYCLOPENTADIENYLIRON
  • CARBOXYFERROCENE
  • Ferroncene Monocarboxylic Acid
  • Ferocene monocarboxylic acid
  • FEPRAZONE
  • Cyclopentadienecarboxylic acid
  • cyclopenta-2,4-diene-1-carboxylic acid
  • errocenecarboxylic acid
  • 1271-42-7
  • HOOCC5H4FeC5H5
  • C11H10FeO2
  • Catalysis and Inorganic Chemistry
  • metallocene
  • Pyridines ,Heterocyclic Acids
  • Piperazine derivates
  • Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts
  • Ferrocene series
  • bc0001
  • 1271-42-7
Copyright 2019 © ChemicalBook. All rights reserved