2,3-Didehydro-3-O-natrio-D-erythro-hexono-1,4-lacton

Sodium erythorbate Struktur
6381-77-7
CAS-Nr.
6381-77-7
Bezeichnung:
2,3-Didehydro-3-O-natrio-D-erythro-hexono-1,4-lacton
Englisch Name:
Sodium erythorbate
Synonyma:
Ery;isona;erbitn;ozoban;eribaten;mercate20;C5H704COOH;isoascorbic;neo-cebitate;kanghuaixuesuanna
CBNumber:
CB9421390
Summenformel:
C6H9NaO6
Molgewicht:
200.12
MOL-Datei:
6381-77-7.mol

2,3-Didehydro-3-O-natrio-D-erythro-hexono-1,4-lacton Eigenschaften

Schmelzpunkt:
154-164°C (decomposes)
alpha 
97 º (c=1,DMF)
Dichte
1.702[at 20℃]
Dampfdruck
0Pa at 25℃
Brechungsindex
97 ° (C=10, H2O)
storage temp. 
Sealed in dry,Room Temperature
Löslichkeit
Soluble in DMSO
Aggregatzustand
solid
Farbe
Light yellow to yellow
Geruch (Odor)
at 100.00?%. odorless
Wasserlöslichkeit
146g/L at 20℃
InChI
InChI=1/C6H8O6.Na.H/c7-1-2(8)5-3(9)4(10)6(11)12-5;;/h2,5,7-10H,1H2;;/t2-,5-;;/s3
InChIKey
RALCFXKKGFGHCA-DJDVHRGRNA-N
SMILES
[C@@H]([C@@]1([H])OC(=O)C(O)=C1O)(O)CO.[NaH] |&1:0,1,r|
LogP
-3.29
CAS Datenbank
6381-77-7(CAS DataBase Reference)
EPA chemische Informationen
Sodium erythorbate (6381-77-7)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
RTECS-Nr. MP8910000
HS Code  2918.29.7500
Giftige Stoffe Daten 6381-77-7(Hazardous Substances Data)
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H320 Causes eye irritation Serious eye damage/eye irritation Category 2B Warnung P264, P305+P351+P338,P337+P313
Sicherheit
P264 Nach Gebrauch gründlich waschen.
P264 Nach Gebrauch gründlich waschen.

2,3-Didehydro-3-O-natrio-D-erythro-hexono-1,4-lacton Chemische Eigenschaften,Einsatz,Produktion Methoden

Chemische Eigenschaften

Sodium erythorbate is a white to yellow-white crystalline powder or granules that are slightly salty and almost odorless. It is stable in the dry state but can deteriorate when exposed to air, trace metals, heat and light in solution. The compound has a melting point above 200℃ (decomposition) and is soluble in water (17g/100m1) but almost insoluble in ethanol. The pH of a 2% aqueous solution ranges from 5.5 to 8.0.

Verwenden

Sodium Erythorbate is an antioxidant that is the sodium salt of erythorbic acid. in the dry crystal state it is nonreactive, but in water solution it readily reacts with atmospheric oxygen and other oxidizing agents, a property that makes it valuable as an antioxidant. during preparation, a minimal amount of air should be incorporated and it should be stored at a cool temperature. it has a solubility of 15 g in 100 ml of water at 25°c. on a comparative basis, 1.09 parts of sodium erythorbate are equivalent to 1 part of sodium ascorbate; 1.23 parts of sodium erythorbate are equivalent to 1 part erythorbic acid. it functions to control oxidative color and flavor deterioration in a variety of foods. in meat curing, it controls and accelerates the nitrite curing reaction and maintains the color brightness. it is used in frankfurters, bologna, and cured meats and is occasionally used in beverages, baked goods, and potato salad. it is also termed sodium isoascorbate.

synthetische

It is produced through using D-glucose fermentation of Pseudomonas fluorescens Kl005 or Arthrobacter globiformis K1022 to produce 2-keto-D-gluconic acid (or calcium salt), followed by being esterified, transformed and refined. The composition of the fermentation medium is: glucose: 18; yeast extract 0.3; K2HPO4 ? 3H2O: 0.05; KH2PO4: 0.05; MgSO4 ? 7H2O: 0.025,;CaCO:34.5. The fermentation temperature is controlled at 30~35 ℃, the fermentation period is 30h, and the fermentation conversion ratio (%) is 79.9%. The fermentation broth is supplemented with sulfate and activated carbon for acidification and decoloring, followed by pressurized filtrate to obtain the clean liquid with a yield of 96.6%.
The purified fermentation broth was concentrated by decompression, and methanol and sulfuric acid were added for refluxed esterification of 5h, followed by frozen and centrifuged filtering to obtain methyl ester with a yield of 82.1%. The methyl ester was transformed with basic methanol solution under refluxing conditions, and the product was further frozen and crystallized to dryness to obtain the crude product of D-isoascorbic acid. The conversion yield was 87.3%, and it was dissolved in hot water and decolorized with activated carbon. The filtrate is pressurized filtrated and the supernatant liquid is frozen, crystallized, centrifugalized, washed and vacuum dried to obtain finished product.
The mother liquid is recovered and the yield is 88.0%.

Allgemeine Beschreibung

Almost odorless fluffy, white to off-white crystalline powder. Used as an antioxidant and preservative.

Air & Water Reaktionen

Water soluble.

Reaktivität anzeigen

Sodium erythorbate may be sensitive to prolonged exposure to light. Incompatible with strong oxidizing agents .

Brandgefahr

Flash point data for Sodium erythorbate are not available; however, Sodium erythorbate is probably combustible.

2,3-Didehydro-3-O-natrio-D-erythro-hexono-1,4-lacton Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


2,3-Didehydro-3-O-natrio-D-erythro-hexono-1,4-lacton Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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6381-77-7(2,3-Didehydro-3-O-natrio-D-erythro-hexono-1,4-lacton)Verwandte Suche:


  • 3-keto-d-gulofuranolactose
  • erbitn
  • eribaten
  • isoascorbic
  • isona
  • mercate20
  • 2,3-Didehydro-3-O-sodio-D-erythro-hexono-1,4-lactone
  • D-Erythro-hex-2-enonic acid gamma-lactone monosodium salt
  • D-Sodium isoascorbiate
  • D-2,3,5,6-tetra-hydroxy-2-hexenic acid-γ-lactone sodium salt
  • D-Erythro-hex-2-enonic acid, g-lactone, monosodium salt
  • Sodium Isovitamin C
  • D-erythro-Hex-2-enonic acid γ-lactone monosodium salt
  • Isoascorbic acid sodium
  • D(+)-Isoascorbic acid, sodium salt,98%
  • Ery
  • SodiuM Isoascorbate 
  • D-Isoascorbic acid Na
  • D-Araboascorbic Acid Sodium Salt Erythorbic Acid Sodium Salt Isoascorbic Acid Sodium Salt Sodium D-Araboascorbate Sodium Erythorbate
  • SodiuM Isoascorbate Monohydrate, 98.0%,(T)
  • Ascorbic Acid Impurity F Sodium Salt
  • neo-cebitate
  • ozoban
  • sodiumd-erythro-3-oxohexonatelactone
  • sodiumenolatemonohydrate
  • SODIUM D-ISOASCORBATE
  • SODIUM ERYTHORBATE
  • SODIUM-ISO-ASCORBATE
  • D-Isoascorbic acid Na salt
  • Araboascorbinicacidsodiumsalt
  • ISOASCORBIC ACID SODIUM SALT
  • ERYTHORBIC ACID SODIUM SALT
  • d-araboascorbic acid sodium salt
  • sodium d-araboascorbate
  • SODIUMERYTHORBATE,FCC(BULK
  • ISOASCORBIC ACID(RG)
  • SODIUMERYTHORBICACID
  • 2,3-Didehydro-3-O-natrio-D-erythro-hexono-1,4-lacton
  • D-Sodium isoascorbiate D-Erythro-hex-2-enonic acid gamma-lactone monosodium salt 2,3-Didehydro-3-O-sodio-D-erythro-hexono-1,4-lactone Sodium erythorbate Sodium Isoascorbate Monohydrate D-Araboascorbic Acid Sodium Salt Erythorbi
  • sodium (R)-2-((R)-1,2-dihydroxyethyl)-4-hydroxy-5-oxo-2,5-dihydrofuran-3-olate
  • sodium D-isoascorbate、erythorbic acid
  • kanghuaixuesuanna
  • Ascorbic Acid EP Impurity F Sodium Salt
  • SodiumIsoascorbateMonohydrate>
  • Araboascorbic acid monosodium salt
  • Isoascorbate C sodium
  • sodium erythorbatr
  • C5H704COOH
  • Sodium erythorbate-100
  • Sodium Erythorbat
  • D-erythro-Hex-2-enonic acid, .gamma.-lactone, sodium salt (1:1)
  • Vitamin Impurity 33
  • 6381-77-7
  • C6H9O7Na
  • C6H7NaO6H2O
  • C6H8O6
  • C6H7O6Na
  • Inhibitors
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