ChemicalBook >> CAS DataBase List >>N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos

N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos

CAS No.
1237588-12-3
Chemical Name:
N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos
Synonyms
Mor-DalPhos;Di(1-adamantyl)-2-morpholinophenylphosphine;MorDalphos 97%;98% Mor-DalPhos;N-[2-(di-1-adamantyL;2-Morpholinophenyldi(1-adamantyl)phosphine;Bis(adamant-1-yl)(2-morpholinophenyl)phosphine;N-[2-(di-1-adaMantylphosphino)phenyl]Morpholine;4-[2-[Di(1-Adamantyl)phosphino]phenyl]morpholine;bis(1-adamantyl)-(2-morpholin-4-ylphenyl)phosphane
CBNumber:
CB12512504
Molecular Formula:
C30H42NOP
Molecular Weight:
463.63
MDL Number:
MFCD17018759
MOL File:
1237588-12-3.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Properties

Melting point 219-224°C
storage temp. 2-8°C
form crystal
pka 4.75±0.40(Predicted)
color white to yellow
Sensitive air sensitive
CAS DataBase Reference 1237588-12-3

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P280-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26
WGK Germany  3

N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 751618 Di(1-adamantyl)-2-morpholinophenylphosphine 97% 1237588-12-3 1g $344 2024-03-01 Buy
Sigma-Aldrich 751618 Di(1-adamantyl)-2-morpholinophenylphosphine 97% 1237588-12-3 5g $1010 2024-03-01 Buy
Strem Chemicals 15-1092 N-[2-(di-1-adamantylphosphino)phenyl]morpholine, 98% Mor-DalPhos 1237588-12-3 250mg $76 2024-03-01 Buy
Strem Chemicals 15-1092 N-[2-(di-1-adamantylphosphino)phenyl]morpholine, 98% Mor-DalPhos 1237588-12-3 1g $232 2024-03-01 Buy
Sigma-Aldrich 751618 Di(1-adamantyl)-2-morpholinophenylphosphine 97% 1237588-12-3 250mg $90.6 2024-03-01 Buy
Product number Packaging Price Buy
751618 1g $344 Buy
751618 5g $1010 Buy
15-1092 250mg $76 Buy
15-1092 1g $232 Buy
751618 250mg $90.6 Buy

N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Chemical Properties,Uses,Production

Reaction

  1. P-N-ligand for use in the Pd-catalyzed cross-coupling of ammonia and hydrazine. Ref. (2) with a diverse range of sterically hindered, unbiased aryl chlorides. Low catalyst loading and mild conditions. Ref (5) with diamines in a chemoselective arylation process. Ref (6) with solvent-free or aqueous conditions.
  2. P-N-ligand for the gold-catalyzed stereoselective hydroamination of internal alkynes with dialkylamines to afford E-amines.
  3. P-N-ligand for use in the Pd-catalyzed for mono-α-arylation of ketones employing aryl chlorides, bromides, iodides, mesylates (Ref. 7) and tosylates.
Reactions of 1237588-12-3

Uses

Mor-DalPhos is a versatile and efficient green catalytic system for Buchwald-Hartwig cross-coupling reaction of aryl bromides or chlorides with a large set amines, amides, ureas, and carbamates.

Uses

MorDalphos is an electronically rich, sterically hindered P,N-based ancillary ligand developed by the Stradiotto group that can be used in the Buchwald-Hartwig Amination reaction, alkyne hydroamination and monoarylation of compounds such as ammonia, hydrazine, and acetone.

N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 85)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15956 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
Richest Group Ltd
18017061086 oled@richest-group.com CHINA 5601 58
Shanghai UCHEM Inc.
+862156762820 +86-13564624040 sales@myuchem.com China 6708 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58
CR Corporation Lomited
fred.wen@crcorporation.cn CHINA 12069 58
CD Chemical Group Limited
+8615986615575 info@codchem.com China 20356 58
XINXIANG RUNYU MATERIAL CO., LTD.
+86-13592593621; +8613592593621 sales@runvmat.com China 424 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418684 +8618949823763 sales@tnjchem.com China 25363 58

View Lastest Price from N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
N-[2-(di-1-adamantylphosphino) phenyl]morpholine pictures 2023-07-27 N-[2-(di-1-adamantylphosphino) phenyl]morpholine
1237588-12-3
US $0.00-0.00 / KG 1KG 0.99 500kg XINXIANG RUNYU MATERIAL CO., LTD.
N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos pictures 2020-01-09 N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos
1237588-12-3
US $9.80 / KG 1g ≥99% 100kg Career Henan Chemical Co

1237588-12-3(N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos)Related Search:

N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos 98% Mor-DalPhos N-[2-(di-1-adaMantylphosphino)phenyl]Morpholine N-[2-(di-1-adaMantylphosphino)phenyl]Morpholine Mor-DalPhos Bis(adamant-1-yl)(2-morpholinophenyl)phosphine 4-(2-(di(adamantan-1-yl)phosphanyl)phenyl)morpholine Bis(1-adamantyl)(2-morpholinophenyl)-phosphine (Mor-DalPhos) 4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine MorDalphos 97% 4-[2-[Di(1-Adamantyl)phosphino]phenyl]morpholine bis(1-adamantyl)-(2-morpholin-4-ylphenyl)phosphane 2-Morpholinophenyldi(1-adamantyl)phosphine 4-(2-(di((3S,5S,7S)-adamantan-1-yl)phosphanyl)phenyl)morpholine N-[2-(di-1-adamantyL Morpholine, 4-[2-[bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]phenyl]- Di(1-adamantyl)-2-morpholinophenylphosphine Mor-DalPhos 4-{2-[(3R,5S,7s)-adamantan-1-yl(1s,3R,5S,7s)-adamantan-1-ylphosphanyl]phenyl}morpholine 1237588-12-3 C30H42NOP Achiral Phosphine Aryl Phosphine organophosphine ligand