ChemicalBook >> CAS DataBase List >>P-Toluenesulfonic anhydride
P-Toluenesulfonic anhydride
- CAS No.
- 4124-41-8
- Chemical Name:
- P-Toluenesulfonic anhydride
- Synonyms
- 4-Methylbenzenesulfonic anhydride;p-Tolylsulfonyl 4-methylbenzenesulfonate;Tosic anhydride;Toluene-p-anhydride;3-Toluenesulfonicanhydride;4-TOLUENESULFONIC ANHYDRIDE;P-TOLUENESULFONIC ANHYDRIDE;p-Toluenesulfonyl anhydride;TOLUENE-4-SULFONIC ANHYDRIDE;P-TOLUENESULPHONIC ANHYDRIDE
- CBNumber:
- CB1292293
- Molecular Formula:
- C14H14O5S2
- Molecular Weight:
- 326.38
- MDL Number:
- MFCD00008548
- MOL File:
- 4124-41-8.mol
- MSDS File:
- SDS
Last updated:2024-05-18 08:51:57
| Melting point | 121-127 °C(lit.) |
|---|---|
| Boiling point | 478.0±48.0 °C(Predicted) |
| Density | 1.361±0.06 g/cm3(Predicted) |
| storage temp. | Inert atmosphere,2-8°C |
| form | Powder, Crystals and/or Chunks |
| color | Off-white to gray |
| Sensitive | Moisture Sensitive |
| BRN | 2223702 |
| InChIKey | PDVFSPNIEOYOQL-UHFFFAOYSA-N |
| CAS DataBase Reference | 4124-41-8(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314 | |||||||||
| Precautionary statements | P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 34 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | UN 2585 8/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-21 | |||||||||
| Hazard Note | Irritant | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29041000 | |||||||||
| NFPA 704 |
|
P-Toluenesulfonic anhydride price More Price(30)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 259764 | p-Toluenesulfonic anhydride 97% | 4124-41-8 | 5g | $54.8 | 2024-03-01 | Buy |
| Sigma-Aldrich | 259764 | p-Toluenesulfonic anhydride 97% | 4124-41-8 | 25g | $142 | 2024-03-01 | Buy |
| TCI Chemical | T1485 | p-Toluenesulfonic Anhydride >95.0%(T) | 4124-41-8 | 5g | $28 | 2024-03-01 | Buy |
| TCI Chemical | T1485 | p-Toluenesulfonic Anhydride >95.0%(T) | 4124-41-8 | 25g | $134 | 2024-03-01 | Buy |
| Alfa Aesar | L00160 | p-Toluenesulfonic anhydride, 97% | 4124-41-8 | 5g | $41.65 | 2024-03-01 | Buy |
P-Toluenesulfonic anhydride Chemical Properties,Uses,Production
Chemical Properties
Off-white to cream powder
Uses
p-Toluenesulfonic anhydride has been employed as reagent in palladium-catalyzed allylic alkenylation of allylic alcohols with n-butyl acrylate.
General Description
p-Toluenesulfonic anhydride acts as electrophilic species and activates 2-deoxy-sugar hemiacetals in situ, which reacts stereoselectively with nucleophilic acceptors to afford β-anomers.
Synthesis
Add p-toluenesulfonic acid and an m-phosphorous compound used as raw materials into a reaction kettle, dropwise adding thionyl chloride while stirring. Controlling the temperature in the reaction kettle at 68-76 ℃ and heating to perform condensation after dropwise addition; inputting water and hydrochloric acid into the reaction kettle, cooling to 0 ℃. The reaction solution generated in the previous step was drawn into the water, vacuum filtration was performed, and centrifuging was used to obtain a crude product, p-toluenesulfonic anhydride. Furthermore, it was inputting ethyl acetate, performing heating reflux, and freezing to perform crystallization, thus obtaining the qualified finished product.
Synthesis of P-Toluenesulfonic anhydride from Phosphinous amide, N,N-diethyl-P,P-bis(trifluoromethyl)- and p-Toluenesulfonic acid
P-Toluenesulfonic anhydride Preparation Products And Raw materials
Global( 320)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shaoxing Fangxiao Chemical Co., LTD | +86-13456999252 +86-13868192239 | kenny@fangxiaochem.com | China | 50 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | 18192627656 | 1012@dideu.com | China | 2766 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 18229 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15957 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21689 | 55 |
| Nanjing Finetech Chemical Co., Ltd. | 025-85710122 17714198479 | sales@fine-chemtech.com | CHINA | 885 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32686 | 60 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Jinan Carbotang Biotech Co.,Ltd. | +8615866703830 | figo.gao@foxmail.com | China | 7019 | 58 |
View Lastest Price from P-Toluenesulfonic anhydride manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-05-18 | P-Toluenesulfonic anhydride
4124-41-8
|
US $1.00-50.00 / KG | 1KG | 99%+ | 500KG | Shaanxi Dideu Medichem Co. Ltd | |
 |
2024-01-18 | 4-Methylbenzenesulfonic Anhydride
4124-41-8
|
US $6.00-0.60 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
 |
2022-11-24 | p-Toluenesulfonic Anhydride
4124-41-8
|
US $0.00 / kg | 1kg | 97% | 20tons | Shandong Promise New Material Co.,Ltd. |
-
- P-Toluenesulfonic anhydride
4124-41-8
- US $1.00-50.00 / KG
- 99%+
- Shaanxi Dideu Medichem Co. Ltd
-
- 4-Methylbenzenesulfonic Anhydride
4124-41-8
- US $6.00-0.60 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-
- p-Toluenesulfonic Anhydride
4124-41-8
- US $0.00 / kg
- 97%
- Shandong Promise New Material Co.,Ltd.
4124-41-8(P-Toluenesulfonic anhydride)Related Search:
CIS-BUTENEDIOIC ANHYDRIDE
Glutaric anhydride
Tosyl cyanide
Trifluoromethanesulfonic anhydride
TOLBUTAMIDE
Succinic anhydride
Isatoic Anhydride
p-Toluenesulfonic acid
Iron(III) p-toluenesulfonate
p-Toluenesulfonamide
1of4
P-TOLUENESULFONIC ANHYDRIDE
P-TOLUENESULPHONIC ANHYDRIDE
TOLUENE-4-SULFONIC ANHYDRIDE
1,3-BIS(4-METHYLPHENYL)-1,1,3,3-TETRAOXO-1LAMBDA6,3LAMBDA6-DITHIOXANE
4-TOLUENESULPHONIC ANHYDRIDE
Tosic anhydride
toluene-p-sulphonic anhydride
4-Toluenesulphonic acid anhydride
4-TOLUENESULFONIC ANHYDRIDE
3-Toluenesulfonicanhydride
p-Toluenesulfonic anhydride 5GR
(4-Methylphenyl)sulfonyl 4-methylbenzenesulfonate
Toluene-4-sulfonic acid anhydride
Toluene-p-anhydride
Bis(4-methylbenzenesulfonic)anhydride
Bis(p-toluenesulfonic)anhydride
Di-p-toluenesulfonic anhydride
p-Toluenesulfonic Anhydride
p-Toluenesulfonyl anhydride
(4-Methylbenzene)sulfonyl 4-Methylbenzene-1-sulfonate
4-Methylbenzenesulphonic anhydride, Tosic anhydride
Toluene-4-sulphonic anhydride
p-Toluenesulfonic anhydride 97%
p-Methylbenzenesulfonic anhydride
p-Toluenesulfonic anhydride, 98%+
Toluene-4-sulphonic anhydride 95%
p-Toluenesulfonic anhydride, 95%, for synthesis
Benzenesulfonic acid, 4-methyl-, 1,1'-anhydride
High Quality Pharmaceutical Intermediates P-Toluenesulfonic Anhydride
4-Methylbenzenesulfonic anhydride
p-Tolylsulfonyl 4-methylbenzenesulfonate
7-butoxybenzene-sulfonylchloride
p-Toluenesulfonic anhydride (6CI, 7CI, 8CI)
Toluenesulfonic anhydride (stored in the freezer, easy to decompose at high temperatures)
4124-41-8
CH3C6H4SO22O
C14H14O5S2
Protection & Derivatization Reagents (for Synthesis)
Building Blocks
Organic Building Blocks
Sulfur Compounds
Sulfonic/Sulfinic Acid Anhydrides
Sulfonic/Sulfinic Acid Anhydrides
Sulfur Compounds
Pyridines
Sulfonic/Sulfinic Acid Anhydrides
Building Blocks
Chemical Synthesis
Organic Building Blocks
Sulfur Compounds
Protection & Derivatization Reagents (for Synthesis)
Synthetic Organic Chemistry
Organic Building Blocks
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