ChemicalBook >> CAS DataBase List >>Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
![Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Structure](CAS/20150408/GIF/1375325-71-5.gif)
- CAS No.
- 1375325-71-5
- Chemical Name:
- Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
- Synonyms
- P(tBu)3 Pd G2;tBu3PPdG2 catalyst;P(t-Bu)3 Palladacycle Gen.2;Chloro[(tri-t-butylphosphine)-2-(2-aminobiphenyl)]palladium(II);Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)pal...;Chloro(tri-tert-butylphosphine)(2'-aminobiphenylyl)palladium(II);Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II);Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II);Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)>Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
- CBNumber:
- CB42673226
- Molecular Formula:
- C24H37ClNPPd
- Molecular Weight:
- 512.41
- MDL Number:
- MFCD21608496
- MOL File:
- 1375325-71-5.mol
Last updated:2024-04-28 19:50:54
| Melting point | 158-160°C |
|---|---|
| form | Powder |
| color | yellow |
| InChI | InChI=1S/C12H9N.C12H27P.ClH.Pd/c13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-10(2,3)13(11(4,5)6)12(7,8)9;;/h1-6,8-9,13H;1-9H3;1H;/q-2;;;+2 |
| InChIKey | CCFGXRYKSYUWKT-UHFFFAOYSA-N |
| SMILES | P([Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-])(C(C)(C)C)(C(C)(C)C)C(C)(C)C |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319 |
| Precautionary statements | P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313 |
| WGK Germany | 3 |
| HS Code | 2931.90.6000 |
Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) price More Price(18)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 756482 | P(tBu)3 Pd G2 | 1375325-71-5 | 2g | $471 | 2024-03-01 | Buy |
| Sigma-Aldrich | 756482 | P(tBu)3 Pd G2 | 1375325-71-5 | 5g | $792 | 2024-03-01 | Buy |
| TCI Chemical | C2734 | Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II) >98.0%(T) | 1375325-71-5 | 1g | $288 | 2024-03-01 | Buy |
| Strem Chemicals | 46-0028 | Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% | 1375325-71-5 | 250mg | $60 | 2024-03-01 | Buy |
| Strem Chemicals | 46-0028 | Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% | 1375325-71-5 | 1g | $177 | 2024-03-01 | Buy |
Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Chemical Properties,Uses,Production
Physical Form
Light yellow to Amber to Dark green powder to crystal.
Reaction
Catalyst for the Suzuki Coupling of brominated 2,1-borazaronaphthalenes and potassium organotrifluoroborates.
Uses
P(t-Bu)3 Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II), Pd/P(t-Bu)3) may be used as catalyst in the following studies:
- Synthesis of sterically hindered biaryls (tetra-ortho-substituted), via cross-coupling reactions of aryl chlorides.
- Stille cross-couplings reactions of aryl chloride.
- Synthesis of chloropeptin I, via Stille cross-coupling reaction.
- Heck reaction.
- Negishi cross-coupling reactions.
Application
Catalyst for the Suzuki Coupling of brominated 2,1-borazaronaphthalenes and potassium organotrifluoroborates.
General Description
P(t-Bu)3 Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II)) is a second generation (G2) precatalyst containing a biphenyl-based ligand. Product participates in various palladium catalyzed cross-coupling reactions, C-C, C-N and C-O bond formation reactions, and Suzuki-Miyaura coupling reactions. It generates active Pd catalyst at room temperature in the presence of weak phosphate or carbonate bases. It has been proposed as an active catalyst for use in Stille reactions of aryl halides (bromides and chlorides).
Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 119)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Wuhan Huahan Dingcheng New Material Technology Co., Ltd | +undefined-027-81388558 +undefined086-1878077615 | huahandingcheng@sina.com | China | 342 | 58 |
| XINXIANG RUNYU MATERIAL CO., LTD. | +86-13592593621; +8613592593621 | sales@runvmat.com | China | 425 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 18219 | 58 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15956 | 58 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Jinan Liheng Biotechnology Co., Ltd. | 15865262812 | info@lihengpharm.com | CHINA | 938 | 58 |
| Richest Group Ltd | 18017061086 | oled@richest-group.com | CHINA | 5601 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9641 | 58 |
| SHANGHAI T&W PHARMACEUTICAL CO., LTD. | +86-021-61551413 +8618813727289 | contact@trustwe.com | China | 5738 | 58 |
| QINGDAO KAIENSI INTERNATIONAL TRADE CO.,LTD. | +86-0532-8699-9256 +8615254267723 | kaley@cnfdevelop.com | China | 1410 | 58 |
View Lastest Price from Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
![Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) pictures](/ProductImageEN/2024-04/Small/7ec89584-0a2e-41b3-beee-8e4e93c534f3.png) |
2024-04-28 | Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
1375325-71-5
|
US $10.00-2.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
![Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) pictures](/ProductImageEN/2022-07/Small/2937370e-ce27-490e-8e53-a60bd85287c3.jpg) |
2022-07-25 | Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
1375325-71-5
|
US $1.10 / g | 1g | 99.00% | 100 Tons Min | Dideu Industries Group Limited | |
 |
2021-06-11 | Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II) / P(tBu)3 Pd G2
1375325-71-5
|
US $10.00-10.00 / g | 1g | 0.98 | 50KG | Wuhan LPBchem Technology Co.,Ltd |
-
- Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
1375325-71-5
- US $10.00-2.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-
- Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
1375325-71-5
- US $1.10 / g
- 99.00%
- Dideu Industries Group Limited
-
- Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II) / P(tBu)3 Pd G2
1375325-71-5
- US $10.00-10.00 / g
- 0.98
- Wuhan LPBchem Technology Co.,Ltd
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Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) in stock Factory
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Palladium, [2'-(amino-kN)[1,1'-biphenyl]-2-yl-kC]chloro[tris(1,1-dimethylethyl)phosphine)-
Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)pal...
(2'-Amino-2-biphenylyl)(chloro)palladium - tris(2-methyl-2-propanyl)phosphine (1:1)
P(tBu)3 Pd G2 / Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II)
P(tBu)3 Pd G2
Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)
[P(tbu)3 PD g2]
1375325-71-5
C24H37ClNPPd
Pd