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2-Bromofluorene

2-Bromofluorene Structure
2-Bromofluorene structure
CAS No.
1133-80-8
Chemical Name:
2-Bromofluorene
Synonyms
2-bromo-9h-fluorene;EAFC;2-BromofL;2-Brom-fluoren;2-BROMOFLUORENE;2-Bromofluorene>2-Bromofluorene 95%;2-Bromofluorene,95%;2-broMo-2H-fluorene;9H-Fluorene, 2-bromo-
CBNumber:
CB5493993
Molecular Formula:
C13H9Br
Molecular Weight:
245.11
MDL Number:
MFCD00001115
MOL File:
1133-80-8.mol
MSDS File:
SDS
Last updated:2023-12-25 13:23:17
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2-Bromofluorene Properties

Melting point 112-114 °C (lit.)
Boiling point 185 °C/135 mmHg (lit.)
Density 1.4187 (rough estimate)
refractive index 1.6290 (estimate)
Flash point 185°C/135mm
storage temp. Sealed in dry,Room Temperature
solubility Soluble in chloroform and ethyl acetate.
form Slightly Crystalline Powder or Flakes
color White to slightly yellow
BRN 1946701
InChIKey FXSCJZNMWILAJO-UHFFFAOYSA-N
CAS DataBase Reference 1133-80-8(CAS DataBase Reference)
FDA UNII J2DF3P68J2
NIST Chemistry Reference 9H-Fluorene, 2-bromo-(1133-80-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
HazardClass  IRRITANT
HS Code  29039990
NFPA 704
0
2 0

2-Bromofluorene price More Price(43)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 124060 2-Bromofluorene 95% 1133-80-8 5g $96.3 2024-03-01 Buy
Sigma-Aldrich 124060 2-Bromofluorene 95% 1133-80-8 25g $182.8 2024-03-01 Buy
TCI Chemical B3069 2-Bromofluorene >98.0%(GC) 1133-80-8 5g $41 2024-03-01 Buy
TCI Chemical B3069 2-Bromofluorene >98.0%(GC) 1133-80-8 25g $123 2024-03-01 Buy
Alfa Aesar L07589 2-Bromofluorene, 95% 1133-80-8 5g $42.65 2024-03-01 Buy
Product number Packaging Price Buy
124060 5g $96.3 Buy
124060 25g $182.8 Buy
B3069 5g $41 Buy
B3069 25g $123 Buy
L07589 5g $42.65 Buy

2-Bromofluorene Chemical Properties,Uses,Production

description

2-Bromofluorene is an isolated product of coal tar and its derivatives are used as important raw materials for fine chemicals. It is often used as synthetic intermediate of the OLED material in industry, by the reaction of barbier-type ultrasonic radiation, It is also used to study the conversion of aryl bromides to aryl triethoxy silane.
Lab Preparation Methods: propylene carbonate is used as solvent, N-bromosuccinimide (NBS) is used as brominated reagent to carry bromination reaction of fluorine, and this reaction can synthesize 2-bromofluorene and 2,7-dibromofluorene. By the investigation of reaction temperature, NBS amount, the adding methods, the optimal reaction conditions for the synthesis of 2-bromofluorene is confirmed. The optimal reaction conditions are: reaction temperature is 23℃, the molar ratio of NBS with fluorine is 1.1:1, NBS is added by stage addition. First fluorene and propylene carbonate is preheated to 60℃, so fluorine is all dissolved, and then it drops to the reaction temperature, NBS is added by stage addition. 2-bromofluorene and 2,7-dibromofluorene recrystallizes with ethanol and acetic acid respectively, the purity of target product of liquid chromatography can reach more than 99%.

Uses

(1) It can be used as pharmaceutical intermediate, it is also important intermediate in the synthesis of optoelectronic material.
(2) By ultrasonic radiation of Barbier-type reaction, 2-bromofluorene is used for the study of aryl bromide (aryl bromides) converts to aryl triethoxysilane (aryltriethoxysilanes). It is also for the preparation of N-carbazole fluorene oligomers end-capped. It can be used as intermediates of OLED materials in industry.

Chemical Properties

white to slightly yellow crystalline powder

Uses

2-Bromofluorene was used in the synthesis of end-capping reagent 2-bromo-9,9-di-nhexylfluorene. It has been used in the preparation of poly(di-n-hexylfluorene)s end capped with 2-bromofluorene, 2-bromo-9,9-di-n-hexylfluorene and 9-bromoanthracene through Ni(0) mediated polymerization. It was also used in the synthesis of 2-bromo-9,9-dihexylfluorene.

Synthesis Reference(s)

Journal of the American Chemical Society, 80, p. 4327, 1958 DOI: 10.1021/ja01549a053

General Description

2-Bromofluorene is a nonintrusive end-capping reagent to control molecular weights and to generate well-defined oligomers. It is used as a reagent for the preparation of dibromofluorene-labelled polystyrene by nitroxide-mediated polymerization. It is also being used in the agricultural sector as a fungicide for tomato disease control. Its carcinogenic effects on humans are currently being investigated.

2-Bromofluorene synthesis

86-73-7
1133-80-8
Synthesis of 2-Bromofluorene from Fluorene

2-Bromofluorene Preparation Products And Raw materials

Raw materials

Preparation Products

2-Bromo-9,9-dimethylfluorene 2-Aminofluorene 2-Bromo-7-iodofluorene 2-Bromo-9,9-diphenylfluorene

2-Bromofluorene Suppliers

Global( 415)Suppliers
Supplier Tel Email Country ProdList Advantage
Puyang Huicheng Electronic Materials Co., Ltd.
+86-0393-+86-0393-8910800 +8615839383373 info@huichengchem.com China 516 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 18225 58
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 15956 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21689 55
Hangzhou FandaChem Co.,Ltd. 		008657128800458; +8615858145714 fandachem@gmail.com China 9341 55
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 32686 60
Speranza Chemical Co., Ltd. 		+86-86-075521030354 +8618688942810 sophieliu@speranzachem.com China 723 55
AB PharmaTech,LLC 		323-480-4688 United States 989 55
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
Zhejiang ZETian Fine Chemicals Co. LTD 		18957127338 stella@zetchem.com China 2141 58
Supplier Advantage
Puyang Huicheng Electronic Materials Co., Ltd.
58
Henan Fengda Chemical Co., Ltd 		58
Shanghai Daken Advanced Materials Co.,Ltd 		58
Henan Tianfu Chemical Co.,Ltd. 		55
Hangzhou FandaChem Co.,Ltd. 		55
ATK CHEMICAL COMPANY LIMITED 		60
Speranza Chemical Co., Ltd. 		55
AB PharmaTech,LLC 		55
career henan chemical co 		58
Zhejiang ZETian Fine Chemicals Co. LTD 		58

Related articles

View Lastest Price from 2-Bromofluorene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Bromofluorene pictures 2024-05-23 2-Bromofluorene
1133-80-8
 US $210.00 / KG 1KG 98% 300MT/year Speranza Chemical Co., Ltd.
2-Bromofluorene pictures 2024-03-28 2-Bromofluorene
1133-80-8
 US $0.00 / kg 25kg 98%-99% Inquiry PNP Biotech Co. Ltd
2-Bromofluorene pictures 2023-12-26 2-Bromofluorene
1133-80-8
 US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
  • 2-Bromofluorene pictures
  • 2-Bromofluorene
    1133-80-8
  • US $100.00-1.00 / KG
  • 99%
  • Henan Fengda Chemical Co., Ltd

2-Bromofluorene Spectrum

2-Bromofluorene(1133-80-8)MS2-Bromofluorene(1133-80-8)1HNMR2-Bromofluorene(1133-80-8)13CNMR2-Bromofluorene(1133-80-8)IR12-Bromofluorene(1133-80-8)IR22-Bromofluorene(1133-80-8)Raman

1133-80-8(2-Bromofluorene)Related Search:

Fluorene 2,7-Dibromo-9,9-diethylfluorene 2-AMINO-7-BROMOFLUORENE,7-AMINO-2-BROMOFLUORENE 2,2'-DIBROMO-9,9'-SPIROBIFLUORENE 2,2',7,7'-Tetrabromo-9,9'-spirobifluorene
2-Bromo-9-fluorenone 2,7-Dibromofluorene 2,7-Dibromo-9H-fluoren-9-one 9,9-Dioctyl-2,7-dibromofluorene 9,9-DIDODECYL-2 7-DIBROMOFLUORENE
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2-Bromo-9,9-dimethylfluorene 9-BROMOFLUORENE,9-Bromofluorene97%,9-Bromofluorene, 98+% 2-BROMO-7-NITROFLUORENE

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2-Bromofluorene,95% 4-Bromo-2,2'-methylenebiphenyl 2-BroMofluorene, 95% 25GR 2-BroMofluorene, BroMofluorene 2-broMo-2H-fluorene 2-broMo-9H-fluorene (2BF) 2-BroMofluorene, 98.0%(GC) 2-Bromofluorene 95% 2-Brom-fluoren 2-bromo-9h-fluorene / 2-bromo-fluorene 9H-Fluorene, 2-bromo- 2-BROMOFLUORENE 2-Bromofluorene, Pract. 2-Bromofluorene, Tech. 2-Bromofluorene,2-fluorenylbromide,2-bromo-fluorene 2-Bromofluorene> 2-Bromofluorene, 95%, for synthesis 2-BromofL 2-Bromofluorene ISO 9001：2015 REACH EAFC TIANFU-CHEM CAS:1133-80-8 2-Bromofluorene 2-bromo-9h-fluorene 1133-80-8 C13H9Br ARYL HALIDE C13 to C37+ Aryl Building Blocks Organic Building Blocks Halogenated Hydrocarbons alkyl bromide Pyridines OLED materials,pharm chemical,electronic Fluorene Series Aryl C13 to C37+ Halogenated Hydrocarbons Fluorenes, Flurenones Electronic Chemicals Fluorenes Fluorenes & Fluorenones Fluorene Derivatives 1133-80-8