ChemicalBook >> CAS DataBase List >>DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)

CAS No.
134524-84-8
Chemical Name:
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
Synonyms
Dichloro [(S);RuCl2[S-BINAP];(S)-BINAP RUCL2;-binaphthyl]dichlororuthenium;-1,1'-binaphthyl]ruthenium(II);-binaphthyl]ruthenium(II),(S-BINAP)RuCl2;Dichlorobisdiphenylphosphinobinaphthylrutheniu;(S)-(-)2,2'bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II);Dichloro[(S)-(-)-,2,2'-bis(diphenylphosphino)-1,1'-binaphthy...;dichloro-R-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ruthenium
CBNumber:
CB6114507
Molecular Formula:
C44H32Cl2P2Ru
Molecular Weight:
794.65
MDL Number:
MFCD01073794
MOL File:
134524-84-8.mol
MSDS File:
SDS
Last updated:2024-04-12 23:00:59

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Properties

Melting point >300 ºC
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Benzene (Slightly, Heated), Dichloromethane (Slightly, Heated)
form Powder
color orange
Sensitive air sensitive
Stability Air Sensitive, Moisture Sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36/37/39-36/37
WGK Germany  3
HS Code  28439000
NFPA 704
0
2 0

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical B3068 [(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride 134524-84-8 250mg $318 2024-03-01 Buy
Strem Chemicals 44-0249 Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95% 134524-84-8 100mg $73 2024-03-01 Buy
Strem Chemicals 44-0249 Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95% 134524-84-8 500mg $163 2024-03-01 Buy
Strem Chemicals 44-0249 Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95% 134524-84-8 2g $486 2024-03-01 Buy
TRC B430400 [(S)-2,2''-Bis(diphenylphosphino)-1,1''-binaphthyl]dichlororuthenium 134524-84-8 250mg $80 2021-12-16 Buy
Product number Packaging Price Buy
B3068 250mg $318 Buy
44-0249 100mg $73 Buy
44-0249 500mg $163 Buy
44-0249 2g $486 Buy
B430400 250mg $80 Buy

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Chemical Properties,Uses,Production

Reaction

  1. Enantioselective catalyst for the asymmetric hydrogenation of α,β-unsaturated olefins.
  2. Efficient catalyst for the asymmetric reduction of carbonyl groups, such as β-ketoesters.
Reactions of 134524-84-8

Chemical Properties

Solid

Uses

[(S)-2,2''-Bis(diphenylphosphino)-1,1''-binaphthyl]dichlororuthenium is used as a catalyst in the asymmetric synthesis of chiral δ-lactones and in the stereoselective synthesis of (hydroxy)amino acids via asymmetric hydrogenation of aminoketo esters.

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 139)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai UCHEM Inc.
+862156762820 +86-13564624040 sales@myuchem.com China 7388 58
Hangzhou ICH Biofarm Co., Ltd
+86-0571-28186870; +undefined8613073685410 sales@ichemie.com China 998 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 18648 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49374 58
career henan chemical co
+86-0371-86658258 +8613203830695 factory@coreychem.com China 29815 58
Shaanxi Dideu Medichem Co. Ltd
+86-029-81138252 +86-18789408387 1057@dideu.com China 3958 58
Richest Group Ltd
18017061086 oled@richest-group.com CHINA 5600 58
QINGDAO KAIENSI INTERNATIONAL TRADE CO.,LTD.
+86-0532-8699-9256 +8615254267723 kaley@cnfdevelop.com China 1410 58
Neostar United (Changzhou) Industrial Co., Ltd.
+86-0519-85551759 +8613506123987 marketing1@neostarunited.com China 8835 58
Shanghai Daeyeon Chemicals Co., Ltd
021-64478606 +8615900664856 daeyeon001@vip.163.com China 2062 58

View Lastest Price from DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(S)-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium pictures 2024-09-27 (S)-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium
134524-84-8
US $43.00-208.00 / g 1g 0.98 1kg Shanghai UCHEM Inc.
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) pictures 2023-11-01 DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
134524-84-8
US $0.00 / kg 1kg 98% 200kg Hangzhou ICH Biofarm Co., Ltd
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) pictures 2023-11-01 DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
134524-84-8
US $0.00 / kg 1kg 98% 200kg Hangzhou ICH Biofarm Co., Ltd
(S)-(-)-2,2''-Bis-(diphenylphosphino)-1,1''-binaphthyl ruthenium dichloride [(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride Dichloro〔(S)-(-)-2,2-bis(diphenylphosphino)-1,1-binaphthyl〕ruthenium(Ⅱ) Dichloro[(S)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]rutheniuM(II),95% [(S)-BINAP]RuCl2 (S)-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium -binaphthyl]dichlororuthenium -binaphthyl]ruthenium(II),(S-BINAP)RuCl2 Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95% Dichloro[(S)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]rutheniuM(II),(S-BINAP)RuCl2 [(1S)-[1,1′-Binaphthalene]-2,2′-diylbis[diphenylphosphine-κP]]dichloro-ruthenium (S)-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium 95% (S)-(-)2,2'bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) (S)-BINAP RUCL2 -1,1'-binaphthyl]ruthenium(II) Dichloro [(S) DICHLORO[(R)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II) HOMOPOLYMER DICHLORO[(S)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II) HOMOPOLYMER Dichlorobisdiphenylphosphinobinaphthylrutheniu Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II),min.95% dichioro[(R)-(+)-2,2‘-bis(diphenylphosphino)-1,1‘-binaphthyl]ruthenium(II) dichloro ((S)-(-)-2,2-bis(diphenylphosphino)-1,1-binaphthyl)ruthenium(I) dichloro-R-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ruthenium RuCl2[S-BINAP] Dichloro[(S)-(-)-,2,2'-bis(diphenylphosphino)-1,1'-binaphthy... [(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride Dichloro [(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 134524-84-8 C44H32Cl2P2Ru Catalysts for Organic Synthesis Classes of Metal Compounds Homogeneous Catalysts Metal Complexes Ru (Ruthenium) Compounds Synthetic Organic Chemistry Transition Metal Compounds Ru