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Methyl geranate

CAS No.
1189-09-9
Chemical Name:
Methyl geranate
Synonyms
methyl(e)-3,7;METHYL GERANATE;METHYL GERANIAT;Methyl geranoate;E-Methylgeranate;Methyl geraniate;methyl-E-geranate;methyl (E)-geraniate;Methyl trans-geranate;GERANIC ACID METHYL ESTER
CBNumber:
CB7224117
Molecular Formula:
C11H18O2
Molecular Weight:
182.26
MDL Number:
MFCD00036571
MOL File:
1189-09-9.mol
MSDS File:
SDS
Last updated:2023-05-25 18:01:17

Methyl geranate Properties

Boiling point 70°C/4mm
Density 0.925
refractive index 1.4690
Flash point 70°C/4mm
Odor at 100.00 %. waxy green fruity flower
Odor Type waxy
LogP 3.972 (est)
FDA UNII 26YR95MGP2
EPA Substance Registry System 2,6-Octadienoic acid, 3,7-dimethyl-, methyl ester, (2E)- (1189-09-9)

SAFETY

Risk and Safety Statements

TSCA  Yes
NFPA 704
1
0 0

Methyl geranate price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich CDS001198 Methyl geranate AldrichCPR 1189-09-9 1G $81.6 2023-01-07 Buy
Alfa Aesar A19218 Methyl geranate, mixture of isomers, 94% 1189-09-9 10g $38.5 2022-04-27 Buy
Alfa Aesar A19218 Methyl geranate, mixture of isomers, 94% 1189-09-9 50g $116 2022-04-27 Buy
American Custom Chemicals Corporation FFG0000598 METHYL GERANATE 98.00% 1189-09-9 500G $4591.13 2021-12-16 Buy
Product number Packaging Price Buy
CDS001198 1G $81.6 Buy
A19218 10g $38.5 Buy
A19218 50g $116 Buy
FFG0000598 500G $4591.13 Buy

Methyl geranate Chemical Properties,Uses,Production

Uses

Methyl geranate is a key link between the lavender aspect and the geranium character for a fougere note. It gives excellent effects in many florals to develop richness and naturalness and should be tried in colognes especially with neroli and green notes in combination with galbanum. Usage levels: 0.5-10%. It is useful in imparting a natural note in re-constituted oils.

Definition

ChEBI: Methyl geranate is a monoterpenoid.

Synthesis Reference(s)

The Journal of Organic Chemistry, 40, p. 269, 1975 DOI: 10.1021/jo00890a034
Journal of the American Chemical Society, 90, p. 5616, 1968 DOI: 10.1021/ja01022a059

Methyl geranate Preparation Products And Raw materials

Raw materials

Preparation Products

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2,6-Octadienoic acid, 3,7-dimethyl-, methyl ester, (E)- 3,7-dimethyl-,methylester,(e)-6-octadienoicacid 6-Octadienoicacid,3,7-dimethyl-,methylester,(E)-2 E-Methylgeranate Methyl (2E)-3,7-dimethyl-2,6-octadienoate methyl (E)-2,6-octadienoate, 3,7-dimethyl methyl (E)-geraniate Methyl geraniate (E)-Methyl 3,7-diMethylocta-2,6-dienoate Methyl 2,6-octadienoate, 3,7-dimethyl, (E)- Methyl geranoate Methyl trans-geranate methyl(e)-3,7 methyl(e)-3,7-dimethylocta- methyl(e)-3,7-dimethylocta-2,6-dienoate methyl-E-geranate trans-Geranic acid methyl ester METHYL GERANATE METHYL 3,7-DIMETHYL-2,6-OCTADIENOATE 3,7-Dimethyl-2,6-octadienoic acid, methyl ester methylgeranate,methyl-(E)-geranate 2,6-Octadienoic acid, 3,7-dimethyl-, methyl ester, (2E)- METHYL GERANIAT Methyl-(E)-3,7-dimethylocta-2,6-dienoat Methyl geranate, mixture of isomers, 94% (E)-3,7-Dimethyl-2,6-octadienoic acid methyl ester Geranic acid b methylester GERANIC ACID METHYL ESTER METHYL GERANATE USP/EP/BP 1189-09-9 1189-9-9