ChemicalBook >> CAS DataBase List >>(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)

CAS No.
192139-90-5
Chemical Name:
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)
Synonyms
RuCl(p-cymene)[(S,S)-Ts-DPEN];RuCl[(S,S)- Tsdpen](p-cyMene);(S,S)-N-(p-ToL;)-1,2-diphenyL;ethanediamine(chL;-N-(p-Toluenesulfonyl);oro)(p-cymene)ruthenium(II);-1,2-diphenylethanediamine(chloro);[RuCl(η6-p-cyMene)(H2NC(Ph)C(Ph)NTs)];RuCl(p-cyMene)[(S,S)-Ts-DPEN], 16% Ru, Product of UMicore
CBNumber:
CB91569347
Molecular Formula:
C31H30ClN2O2RuS
Molecular Weight:
631.17
MDL Number:
MFCD09953484
MOL File:
192139-90-5.mol
MSDS File:
SDS
Last updated:2024-03-18 16:05:02

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Properties

Melting point >175 °C
alpha 178o (C=0.5 IN CHLOROFORM)
storage temp. 2-8°C
solubility soluble in Chloroform, DCM, Ethyl Acetate
form solid
color yellow to dark brown
optical activity [α]20/D +178°, c = 0.5 in chloroform
Sensitive air sensitive
InChIKey DCJKLKCGNMDXFR-MNPNNRAMNA-M
SMILES [Cl-][Ru+2]123456(N[C@@H](C7C=CC=CC=7)[C@H](C7C=CC=CC=7)[N-]1S(C1C=CC(C)=CC=1)(=O)=O)C1(C)C2=C3C4(C(C)C)=C5C6=1 |&1:3,10,r|

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xn
Risk Statements  22
Safety Statements  24/25
WGK Germany  3
HS Code  28439000

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) price More Price(28)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 703915 RuCl(p-cymene)[(S,S)-Ts-DPEN] 192139-90-5 100mg $48.3 2024-03-01 Buy
Sigma-Aldrich 703915 RuCl(p-cymene)[(S,S)-Ts-DPEN] 192139-90-5 500mg $136 2024-03-01 Buy
TCI Chemical R0124 RuCl[(S,S)-Tsdpen](p-cymene) >90%(HPLC) 192139-90-5 200mg $55 2024-03-01 Buy
TCI Chemical R0124 RuCl[(S,S)-Tsdpen](p-cymene) >90%(HPLC) 192139-90-5 1g $177 2024-03-01 Buy
Strem Chemicals 44-0149 Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](p-cymene) 192139-90-5 250mg $53 2024-03-01 Buy
Product number Packaging Price Buy
703915 100mg $48.3 Buy
703915 500mg $136 Buy
R0124 200mg $55 Buy
R0124 1g $177 Buy
44-0149 250mg $53 Buy

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Chemical Properties,Uses,Production

Reaction

This catalyst has shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester. Reactions of 192139-90-5

Chemical Properties

Solid

Uses

Catalyst involved in:

  • Asymmetric transfer hydrogenation of imines and ketones
  • Intramolecular asymmetric reductive amination
  • Tandem hydroformylation / hydrogenation of terminal olefins

Reactant involved in studies of thermal decomposition of areneruthenium chiral amido-amine alkyl complexes

Uses

Catalyst involved in: ? Asymmetric transfer hydrogenation of imines and ketones ? Intramolecular asymmetric reductive amination ? Tandem hydroformylation / hydrogenation of terminal olefins Reactant involved in studies of thermal decomposition of arenerut

General Description

RuCl(p-cymene)[(S,S)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium, which can be used for the asymmetric transfer hydrogenation of a variety of imines.

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 180)Suppliers
Supplier Tel Email Country ProdList Advantage
XINXIANG RUNYU MATERIAL CO., LTD.
+86-13592593621; +8613592593621 sales@runvmat.com China 435 58
Hangzhou ICH Biofarm Co., Ltd
+86-0571-28186870; +undefined8613073685410 sales@ichemie.com China 998 58
Capot Chemical Co.,Ltd.
+86-(0)57185586718 +86-13336195806 sales@capot.com China 29791 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 18648 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21639 55
Nanjing ChemLin Chemical Industry Co., Ltd.
025-83697070 product@chemlin.com.cn CHINA 3009 60
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32820 60
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29886 58
Shenzhen Nexconn Pharmatechs Ltd
+86-755-89396905 +86-15013857715 admin@nexconn.com China 10310 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28172 58

View Lastest Price from (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
RuCl[(S,S)-Tsdpen](p-cymene) pictures 2024-10-31 RuCl[(S,S)-Tsdpen](p-cymene)
192139-90-5
US $0.00 / G 50G 98%min 30kg/month WUHAN FORTUNA CHEMICAL CO., LTD
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) pictures 2023-11-01 (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)
192139-90-5
US $0.00 / KG 1KG 98% 200KG Hangzhou ICH Biofarm Co., Ltd
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) pictures 2023-07-27 (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)
192139-90-5
US $0.00-0.00 / g 1g 98% 500 XINXIANG RUNYU MATERIAL CO., LTD.
-1,2-diphenylethanediamine(chloro) -N-(p-Toluenesulfonyl) (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Chloro{[(1S,2S)-(+)-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II) [N-[(1S,2S)-2-(Amino-kN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro[(1,2,3,4,5,6-n)-1-methyl-4-(1-methylethyl)benzene]ruthenium Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-
cymene)ruthenium(II), min. 95% RuCl[(S,S)-Tsdpen](p-cymene)
Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% RuCl[(S,S)-Tsdpen](p-cymene) Chloro{[(1S,2S)-(+)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II) Chloro{[(1S,2S)-(+)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),95% RuCl[(S,S)-Tsdpen](p-cyMene) [RuCl(η6-p-cyMene)(H2NC(Ph)C(Ph)NTs)] Chloro{[(1S,2S)-(+)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),RuCl[(S,S)-Tsdpen](p-cyMene) RuCl(p-cyMene)[(S,S)-Ts-DPEN], 16% Ru, Product of UMicore [(η-6-CyMene)[(S,S)-1,2-diphenyl-N-tosyl-1,2-ethanediaMinato]rutheniuM] chloride] Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](p-cymene) RuCl(p-cymene)[(S,S)-Ts-DPEN] Chloro{[(1S,2S)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II) [(1S,2S)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide,chlororuthenium(1+),1-methyl-4-propan-2-ylbenzene [N-[(1S,2S)-2-(Amino-KN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-KN]chloro[(1,2,3,4,5,6-η:)-1-methyl-4-(1- Ruthenium,[N-[(1S,2S)-2-(amino-kN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro[(1,2,3,4,5,6-h)-1-methyl-4-(1-methylethyl)benzene]- (S,S)-N-(p-ToL ethanediamine(chL oro)(p-cymene)ruthenium(II) )-1,2-diphenyL Chloro(p-cymene)[(S,S)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II) [(S,S)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide]chloro(p-cymene)ruthenium(II) (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) ISO 9001:2015 REACH (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro... [(1S,2S)-2-amino-1,2-diphenyl-ethyl]-(p-tolylsulfonyl)azanide RuCl(p-cymene)[(S,S)-Ts-DPEN] RuCl[(S,S)- Tsdpen](p-cyMene) [((S,S)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)( p -cymene)ruthenium(II) RuCl[(S,S)-Tsdpen](p-cymene)/Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II) ((S,S)-2-Amino-1,2-Diphenylethyl)[(4-Tolyl)Sulfonyl]Amido](P-Cymene)Ruthenium (II)Chloride N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium (ACI) 192139-90-5 C32H44ClN2O2RuS organometallic complex Ru