3-Nitrobenzoic acid
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3-Nitrobenzoic acid 속성
- 녹는점
- 139-141 °C(lit.)
- 끓는 점
- 295.67°C (rough estimate)
- 밀도
- 1,494 g/cm3
- 증기 밀도
- 5.76 (vs air)
- 증기압
- 0.005Pa at 25℃
- 굴절률
- 1.6280 (estimate)
- 인화점
- 190 °C
- 저장 조건
- no restrictions.
- 용해도
- 물: 25°C에서 용해성3g/L
- 물리적 상태
- 결정 또는 분말
- 산도 계수 (pKa)
- 3.47(at 25℃)
- 색상
- 약간 녹색에서 연한 노란색
- pH 범위
- 3
- 수소이온지수(pH)
- 3 (5g/l, H2O, 20℃)(aqueous suspension)
- 수용성
- 18°C에서 <0.01g/100mL
- Merck
- 14,6588
- BRN
- 908644
- 안정성
- 안정적인. 타기 쉬운. 강한 산화제와 호환되지 않습니다.
- InChIKey
- AFPHTEQTJZKQAQ-UHFFFAOYSA-N
- LogP
- 1.1 at 25℃
- CAS 데이터베이스
- 121-92-6(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | Xn,Xi | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 22-36/37-33-36/37/38 | ||
| 안전지침서 | 26-24/25 | ||
| WGK 독일 | 3 | ||
| RTECS 번호 | DH5000000 | ||
| 자연 발화 온도 | 490 °C | ||
| 위험 참고 사항 | Irritant | ||
| TSCA | Yes | ||
| HS 번호 | 29163900 | ||
| 유해 물질 데이터 | 121-92-6(Hazardous Substances Data) |
3-Nitrobenzoic acid C화학적 특성, 용도, 생산
화학적 성질
White or light yellow monoclinic leaf-like crystal. Soluble in acetone, chloroform, ethanol and ether, slightly soluble in benzene, water, carbon disulfide and petroleum ether, more soluble in hot water. It smells like almonds. 3-nitrobenzoic acid is quite a strong acid, it is soluble in a relatively weak base. It is about ten times more acidic than benzoic acid.The conjugate base of benzoic acid is stabilised by the presence of the electron withdrawing nitro group which explains its increased acidity in comparison to unsubstituted benzoic acid.용도
3-Nitrobenzoic acid was used to investigated the role of ozone as additional decomposition or finishing reagent in the degradation of o-, m- and p-nitobenzoic acids제조 방법
3-Nitrobenzoic acid is prepared by nitrating benzoic acid at low temperature. Approximately 20% of the 2-nitro isomer and 1.5% of the 4-nitro isomer are co-produced. The 3-nitrobenzoic acid can be purified by recrystallization of the sodium salt. The oxidation of 3-nitrobenzaldehyde, prepared by the controlled oxidation of benzaldehyde, gives a higher yield.일반 설명
Off white to yellowish-white crystals. Bitter taste. Melts in hot water.공기와 물의 반응
Insoluble in water.반응 프로필
3-Nitrobenzoic acid is incompatible with strong oxidizers. 3-Nitrobenzoic acid is also incompatible with strong bases. 3-Nitrobenzoic acid may react with cyanides.화재위험
Flash point data for 3-Nitrobenzoic acid are not available but 3-Nitrobenzoic acid is probably combustible.Purification Methods
Crystallise the acid from *benzene, H2O, EtOH (charcoal), glacial acetic acid or MeOH/H2O. Dry and store it in a vacuum desiccator. The amide has m 143o (from H2O or *C6H6). [Beilstein 9 III 1489, 9 IV 1055.]3-Nitrobenzoic acid 준비 용품 및 원자재
원자재
준비 용품
3-디메틸아미노안식향산
2,5-BIS(3-NITROPHENYL)-1,3,4-OXADIAZOLE
m-Nitrobenzoyl chloride
3-Aminobenzoic acid
2,3-Dihydro-3-(MethoxyphenylMethylene)-2-oxo-1H-indole-6-carboxylic acid Methyl ester
4,4'-Dinitrodiphenic acid
3-AMINOBENZOYLMETHYLAMIDE
3-NITROBENZHYDRAZIDE
3-Nitropropiophenone
3-AMINO-5-BROMOBENZOATE
4-Iodo-3-nitrobenzoic acid
3-Nitrobenzyl alcohol
N-(2-methylphenyl)-3-nitrobenzamide
3-Nitrobenzoic acid 공급 업체
글로벌( 621)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 |
sales@hbmojin.com | China | 12471 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 |
info@fdachem.com | China | 18229 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21689 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 |
fandachem@gmail.com | China | 9341 | 55 |
| career henan chemical co | +86-0371-86658258 |
sales@coreychem.com | China | 29914 | 58 |
| Shenzhen Nexconn Pharmatechs Ltd | +86-755-89396905 +86-15013857715 |
admin@nexconn.com | China | 10248 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28180 | 58 |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 |
alice@crovellbio.com | China | 8822 | 58 |
| Xiamen AmoyChem Co., Ltd | +86-592-6051114 +8618959220845 |
sales@amoychem.com | China | 6387 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22968 | 58 |
3-Nitrobenzoic acid 관련 검색:
3,4-다이하이드로-2,5,7,8-테트라메틸-2-(4,8,12-트라이메틸트 라이데실)-2H-벤조피란-6-올 4-니트로안식향산 아세트산 시트르산 니트로벤조산 엽산 스테아르산 3,5-디나이트로벤조 산 3-나이트로벤젠설폰산 나트륨 염 나이트로벤젠 4-클로로-3-니트로 안식향산 M-디니트로벤젠 메틸 옥시레인, 중합체 ,함유 옥시레인, 에테르 ,함유 (1,2-에탄딜- 디니트리로)테트라키스(프로판올)
3-Nitrobenzonitrile
4-Nitrophenyl chloroformate
Hyaluronic acid
3-Nitrobenzaldehyde
5-Chlorovaleric acid