메틸시클로펜탄

메틸시클로펜탄
메틸시클로펜탄 구조식 이미지
카스 번호:
96-37-7
한글명:
메틸시클로펜탄
동의어(한글):
메틸사이클로펜테인;메틸사이클로펜탄;메틸시클로펜탄;메틸사이클로펜탄(METHYLCYCLOPENTANE);1-메틸-사이클로펜테인카브알데하이드
상품명:
Methylcyclopentane
동의어(영문):
MCP;1-Methylcyclopentane;NSC 24836;Methylcyclopen;Methylcyclopentan;methyl-Cyclopetane;METHYLCYCLOPENTANE;methyl-cyclopentan;Cyclopetane,methyl-;cyclopentane,methyl-
CBNumber:
CB2854726
분자식:
C6H12
포뮬러 무게:
84.16
MOL 파일:
96-37-7.mol
MSDS 파일:
SDS

메틸시클로펜탄 속성

녹는점
-142.4 °C
끓는 점
72 °C(lit.)
밀도
0.749 g/mL at 25 °C(lit.)
증기압
232.8 mm Hg ( 37.7 °C)
굴절률
n20/D 1.409(lit.)
인화점
−11 °F
저장 조건
Store below +30°C.
용해도
In methanol, g/L: 380 at 5 °C, 415 at 10 °C, 500 at 15 °C, 595 at 20 °C, 740 at 25 °C, 1,100 at 30 °C. Miscible at higher temperatures (Kiser et al., 1961).
물리적 상태
결정체
색상
하얀색
냄새
휘발유처럼.
폭발한계
8.35%
Odor Threshold
1.7ppm
수용성
41.8mg/L(25℃)
BRN
1900214
Henry's Law Constant
0.362 atm?m3/mol at 25 °C (Hine and Mookerjee, 1975)
Dielectric constant
2.0(20℃)
LogP
3.37 at 20℃
CAS 데이터베이스
96-37-7(CAS DataBase Reference)
EPA
Methylcyclopentane (96-37-7)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 F,Xn
위험 카페고리 넘버 11-22-36/37/38-65
안전지침서 16-26-33-36-62
유엔번호(UN No.) UN 2298 3/PG 2
WGK 독일 3
RTECS 번호 GY4640000
자연 발화 온도 624 °F
TSCA Yes
HS 번호 2902 19 00
위험 등급 3
포장분류 II
유해 물질 데이터 96-37-7(Hazardous Substances Data)
기존화학 물질 KE-23724
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H225 고인화성 액체 및 증기 인화성 액체 구분 2 위험 GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H304 삼켜서 기도로 유입되면 치명적일 수 있음 흡인 유해성물질 구분 1 위험 GHS hazard pictograms
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P233 용기를 단단히 밀폐하시오. 용기는 환기가 잘 되는 곳에 단단히 밀폐하여 보관하시오.
P240 용기와 수용설비를 접지 및 접합시키시오.
P241 폭발 방지용 장비[전기적/환기/조명/...]을(를) 사용하시오.
P301+P310 삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
P331 토하게 하지 마시오.
NFPA 704
3
2 0

메틸시클로펜탄 C화학적 특성, 용도, 생산

화학적 성질

Methylcyclopentane is a colorless, flammable liquid with a sweet gasoline-like odor. An odor threshold concentration of 1.7 ppmv was reported by Nagata and Takeuchi (1990). Soluble in ether, miscible with alcohol and benzene, insoluble in water.

용도

Methylcyclopentane can undergo ring opening or ring enlargement to yield various hydrocarbons including branched and unbranched hexanes, cyclohexane and benzene.

정의

ChEBI: Methylcyclopentane is a cycloalkane that is cyclopentane substituted by a single methyl group. It has a role as a human metabolite and a plant metabolite. It is a cycloalkane and a volatile organic compound. It derives from a hydride of a cyclopentane.

제조 방법

Methylcyclopentane mainly exists in industrial hexane, accounting for about 5%. However, because its boiling point is close to that of n-hexane (68.74°C), it is difficult to completely separate it by general rectification methods. Therefore, methylcyclopentane with a purity of more than 99% can be obtained by azeotropic distillation with methanol.

일반 설명

Methylcyclopentane appears as a colorless liquid. Insoluble in water and less dense than water. Flash point near 20 °F. Very dangerous fire risk. Vapors may be narcotic and irritating. Used to make other chemicals.

공기와 물의 반응

Highly flammable. Insoluble in water.

반응 프로필

Methylcyclopentane can react vigorously with oxidizers. (NTP, 1992).

위험도

Flammable, dangerous fire and explosionrisk. May be irritant and narcotic.

건강위험

Inhalation causes dizziness, nausea, and vomiting; concentrated vapor may cause unconsciousness and collapse. Liquid causes irritation of eyes and mild irritation of skin if allowed to remain. Ingestion causes irritation of stomach. Aspiration causes severe lung irritation, rapidly developing pulmonary edema, and central nervous system excitement followed by depression.

화재위험

Behavior in Fire: Vapor is heavier than air and may travel a considerable distance to a source of ignition and flash back.

Safety Profile

Mildly toxic by inhalation. Probably irritating and narcotic in high concentration. Very dangerous fire hazard when exposed to heat, flame, or oxidizers. Can react vigorously with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.

잠재적 노출

This material is used as a solvent; as a fuel; and in chemical synthesis.

환경귀착

Photolytic. A photooxidation rate constant of 7.0 x 10-12 cm3/molecule?sec was reported for the reaction of methylcyclopentane and OH radicals in the atmosphere (Atkinson, 1990).
Chemical/Physical. Complete combustion in air produces carbon dioxide and water vapor. Methylcyclopentane will not hydrolyze because it does not contain a hydrolyzable functional group.
At elevated temperatures, rupture of the ring occurs and 1-propene is produced in a 40% yield. Other products include hydrogen and cyclic mono- and diolefins (Rice and Murphy, 1942).

운송 방법

UN2298 Methyl cyclo pentane, Hazard Class: 3; Labels: 3-Flammable liquid

Purification Methods

Purification procedures include passage through columns of silica gel (prepared by heating in nitrogen to 350o prior to use) and activated basic alumina, distillation from sodium-potassium alloy, and azeotropic distillation with MeOH, followed by washing out the methanol with water, drying and distilling. It can be stored with CaH2 or sodium. [Vogel J Chem Soc 1331 1938, Beilstein 5 III 55, 5 IV 84.]

비 호환성

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.

폐기물 처리

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

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