클로르프로팜

클로르프로팜
클로르프로팜 구조식 이미지
카스 번호:
101-21-3
한글명:
클로르프로팜
동의어(한글):
클로프로팜;클로르프로팜
상품명:
Chlorpropham
동의어(영문):
CIPC;CHLOROPROPHAM;y3;Y 3;CICP;DECCO;budnip;ci-ifk;CI-IPC;Cl-IFK
CBNumber:
CB3136324
분자식:
C10H12ClNO2
포뮬러 무게:
213.66
MOL 파일:
101-21-3.mol
MSDS 파일:
SDS

클로르프로팜 속성

녹는점
41°C
끓는 점
247°C
밀도
1.18
굴절률
nD20 1.5388
인화점
247°C
저장 조건
2-8°C
용해도
클로로포름(약간 용해됨), 메탄올(약간 용해됨)
물리적 상태
수정 같은
산도 계수 (pKa)
13.06±0.70(Predicted)
색상
베이지색
냄새
희미한 숯. 냄새
수용성
0.009g/100ml 매우 나쁨
분해온도
247 ºC
Merck
14,2187
BRN
2211397
노출 한도
An experimental carcinogen and neoplastigen
안정성
안정적인. 강산, 강염기, 강산화제와 호환되지 않습니다.
CAS 데이터베이스
101-21-3(CAS DataBase Reference)
IARC
3 (Vol. 12, Sup 7) 1987
NIST
Chlorpropham(101-21-3)
EPA
Chlorpropham (101-21-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,N,F
위험 카페고리 넘버 22-51/53-36-20/21/22-11
안전지침서 61-36/37-26-16
유엔번호(UN No.) UN 3077 9/PG 3
WGK 독일 2
RTECS 번호 FD8050000
HS 번호 2924.29.4300
위험 등급 9
포장분류 III
유해 물질 데이터 101-21-3(Hazardous Substances Data)
독성 LD50 orally in rats: 1.2 g/kg (Boyd, Carsky)
기존화학 물질 97-3-18
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H351 암을 일으킬 것으로 의심됨 (노출되어도 암을 일으키지 않는다는 결정적인 증거가 있는 노출경로가 있다면 노출경로 기재) 발암성 물질 구분 2 경고 P201, P202, P281, P308+P313, P405,P501
H373 장기간 또는 반복 노출되면 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킬 수 있음 특정 표적장기 독성 - 반복 노출 구분 2 경고 P260, P314, P501
H411 장기적 영향에 의해 수생생물에 유독함 수생 환경유해성 물질 - 만성 구분 2
예방조치문구:
P201 사용 전 취급 설명서를 확보하시오.
P202 모든 안전 조치 문구를 읽고 이해하기 전에는 취급하지 마시오.
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P273 환경으로 배출하지 마시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P308+P313 노출 또는 접촉이 우려되면 의학적인 조치· 조언를 구하시오.
NFPA 704
0
2 0

클로르프로팜 MSDS


Isopropyl 3-chlorocarbanilate

클로르프로팜 C화학적 특성, 용도, 생산

화학적 성질

beige to brown solid

용도

Chlorpropham is particularly useful in agricultural settings. It is used in pesticide products for treatment of plants and soil.

정의

ChEBI: A carbamate ester that is the isopropyl ester of 3-chlorophenylcarbamic acid.

일반 설명

Brown chunky solid.

공기와 물의 반응

Insoluble in water.

반응 프로필

Chlorpropham is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.

위험도

Toxic by ingestion.

화재위험

Flash point data for Chlorpropham are not available, however Chlorpropham is probably combustible.

농업용

Herbicide, Plant growth regulator: Chlorpropham is a plant growth regulator that is used primarily in the U.S. to inhibit post-harvest potato sprouting. Other uses include pre-emergence control of grass weeds in alfalfa, beans, blueberries, cane berries, carrots, cranberries, ladino clover, garlic, seed grass, onions, spinach, sugar beets, tomatoes, safflower, soybeans, gladioli and woody nursery stock. It is used to control suckers in tobacco

상품명

ATLAS® CIPC 40; BEET-KLEEN® (with Fenuron® and isopropyl carbanilate); BUDNIP®; CAMPBELL’S® CIPC 40%; CHLORO IPC®; ELBANIL®; FASCO® WY-HOE; FURLOE®; FURLOE® 4EC; JACK WILSON® CHLORO 51 (OIL); LIRO METOXON®; MIRVALE®; MORCRAN® (with n-1-naphthylphthalamic acid); MSS® CICP; NEXOVAL®; PREVENOL® 56; PREVENTOL®; PREVENTOL® 56; PREWEED®; RESIDUREN®; RESIDUREN® EXTRA; SPROUT NIP®; SPROUT-NIP® EC; SPUDNIC®; SPUD-NIE®; STOPGERME®-S; TATERPEX®; TRIPEC® (with carbamic acid, phenyl-, 1-methylethyl ester); TRIHERBICIDE® CIPC; UNICROP® CIPC; WAREFOG®; Y3®

환경귀착

Soil. Hydrolyzes in soil forming 3-chloroaniline (Bartha, 1971; Hartley and Kidd, 1987; Smith, 1988; Rajagopal et al., 1989). In soil, Pseudomonas striata Chester, a Flavobacterium sp., an Agrobacterium sp. and an Achromobacter sp. readily degraded chlorpropham to 3-chloroaniline and 2-propanol. Subsequent degradation by enzymatic hydrolysis yielded carbon dioxide, chloride ions and unidentified compounds (Kaufman, 1967; Rajagopal et al., 1989). Hydrolysis products that may form in soil and in microbial cultures include N-phenyl-3-chlorocarbamic acid, 3-chloroaniline, 2-amino-4-chlorophenol, monoisopropyl carbonate, 2-propanol, carbon dioxide and condensation products (Rajagopal et al., 1989). The reported half-lives in soil at 15 and 29°C are 65 and 30 days, respectively (Hartley and Kidd, 1987)
Plant. Chlorpropham is rapidly metabolized in plants (Ashton and Monaco, 1991). Metabolites identified in soybean plants include isopropyl-N-4-hydroxy-3-chlorophenylcarbamate, 1-hydroxy-2-propyl-3′-chlorocarbanilate and isopropyl-N-5-chloro-2-hy
Photolytic. The photodegradation rate of chlorpropham in aqueous solution was enhanced in the presence of a surfactant (TMN-10) (Tanaka et al., 1981). In a later study, Tanaka et al. (1985) studied the photolysis of chlorpropham (50 mg/L) in aque
Chemical/Physical. Emits toxic phosgene fumes when heated to decomposition (Sax and Lewis, 1987). In a 0.50 N sodium hydroxide solution at 20°C, chlorpropham was hydrolyzed to aniline derivatives. The half-life of this reaction was 3.5 days (El-Dib and Aly, 1976). Simple hydrolysis leads to the formation of 3-chlorophenylcarbamic acid and 2-propanol. The acid is very unstable and is spontaneously converted to 3-chloroaniline and carbon dioxide (Still and Herrett, 1976)

클로르프로팜 준비 용품 및 원자재

원자재

준비 용품


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