1-나프탈렌아세트산

1-나프탈렌아세트산
1-나프탈렌아세트산 구조식 이미지
카스 번호:
86-87-3
한글명:
1-나프탈렌아세트산
동의어(한글):
1-나프탈렌아세트산;1-나프탈렌아세틱애씨드
상품명:
1-Naphthaleneacetic acid
동의어(영문):
ANA;Naphthylacetic acid;α-Naphthaleneacetic acid;1-Naphthalene acetic acid;1-naa;Fruitone;ANU;BTG3;TOB5;stik
CBNumber:
CB4679844
분자식:
C12H10O2
포뮬러 무게:
186.21
MOL 파일:
86-87-3.mol
MSDS 파일:
SDS

1-나프탈렌아세트산 속성

녹는점
141-143 °C(lit.)
끓는 점
280.69°C (rough estimate)
밀도
1.1032 (rough estimate)
굴절률
1.6010 (estimate)
인화점
>100°C
저장 조건
Sealed in dry,Room Temperature
용해도
에 용해됨 아세톤: 50mg/mL, 투명
산도 계수 (pKa)
4.30±0.30(Predicted)
물리적 상태
수정 같은
색상
연노랑
냄새
냄새 없는
수소이온지수(pH)
3.0 (0.6g/l, H2O, 25℃)
수용성
물, 에탄올, 아세톤, 클로로포름 및 에테르에 약간 용해됩니다.
Merck
14,6371
BRN
1308415
안정성
흡습성
InChIKey
PRPINYUDVPFIRX-UHFFFAOYSA-N
LogP
2.240
CAS 데이터베이스
86-87-3(CAS DataBase Reference)
NIST
1-Naphthaleneacetic acid(86-87-3)
EPA
1-Naphthaleneacetic acid (86-87-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi,Xn,C
위험 카페고리 넘버 36/37/38-22-68-41-37/38-34
안전지침서 26-36-24/25-36/39-22-23-45-36/37/39-27
WGK 독일 3
RTECS 번호 QJ0876000
위험 등급 IRRITANT
HS 번호 29163900
유해 물질 데이터 86-87-3(Hazardous Substances Data)
독성 LD50 orally in Rabbit: 1000 mg/kg LD50 dermal Rabbit > 5000 mg/kg
기존화학 물질 KE-25546
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H318 눈에 심한 손상을 일으킴 심한 눈 손상 또는 자극성 물질 구분 1 위험 GHS hazard pictograms P280, P305+P351+P338, P310
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
H412 장기적 영향에 의해 수생생물에 유해함 수생 환경유해성 물질 - 만성 구분 3 P273, P501
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
0
2 0

1-나프탈렌아세트산 MSDS


1-Naphthalene acetic acid

1-나프탈렌아세트산 C화학적 특성, 용도, 생산

개요

1-naphthaleneacetic acid (NAA), also known as α-naphthaleneacetic acid, belongs to a class of organic compounds of naphthalenes, which contain a naphthalene moiety of two fused benzene rings. NAA is a synthetic auxin plant hormone. It is used as a plant growth regulator to control preharvest fruit drop, flower induction and fruit thinning in various crops such as apples, potatoes, olives, and citrus fruits. It is used as a rooting agent and used for the vegetative propagation of plants from stem and leaf cutting. It is also used for plant tissue culture and as herbicide. Applied as a dust or spray it delays dissolution of the abscission layer, retarding the fruit drop. The effect of NAA on plant growth is greatly dependent on the time of admission and concentration. When used after four weeks, NAA stimulates shoot growth, while full-time use limits growth. When used in a 4-week pulse, adventitious root growth is greatly increased.

화학적 성질

White needle crystal or crystalline powder, odorless. Slightly soluble in cold water and ethanol, easily soluble in hot water, acetone, ether, chloroform, benzene, acetic acid and alkali solution.

용도

1-Naphthaleneacetic acid is widely employed in agriculture as a synthetic plant hormone in the auxin family or a plant growth regulator, which can find applications in tissue culture.  Inducing rooting of plant cuttings, spraying apple trees to prevent early drop, fruit thinner.
1-Naphthaleneacetic acid has been used:
to modify MS media for the initiation of callus
as a supplement in solid K3 medium for the selection of transformants
in the preparation of culture medium like V-KM medium and Cg medium

주요 응용

1-Naphthaleneacetic acid (NAA) is a synthetic phytohormone auxin that is added to cell culture media such as Murashige & Skoog media and Chu′s N6 media.

제조 방법

Industrially, 1-naphthaleneacetic acid is prepared by condensation reaction of naphthalene and chloroacetic acid in the presence of catalyst potassium chloride or aluminum powder.

정의

ChEBI: 1-naphthaleneacetic acid is a naphthylacetic acid substituted by a carboxymethyl group at position 1. It has a role as a synthetic auxin. It is a conjugate acid of a 1-naphthaleneacetate.

일반 설명

1-Naphthaleneacetic acid is widely employed in agriculture as a synthetic plant hormone in the auxin family or a plant growth regulator, which can find applications in tissue culture. It is used for the vegetative propagation of plants from stem and leaf cutting, abscission promoter and substrate for auxin inducers of specific plant enzymes. Further, it stimulates root formation in cuttings of woody and herbaceous plants. It is also used to prevent premature flower and fruit drop. It is also employed to control regrowth of tree sprouts after trimminguse. In addition to this, it is used in ornaments and serves as an ingredient in many commercial plant rooting horticultural products.

위험도

Skin irritant.

농업용

Plant growth regulator: An agent for thinning fruit sets in apples, pears, olives and some citrus. Induces root formation on cuttings and transplants. Inhibits fruit drops. Not currently registered in EU countries (pending). Registered for use in the U.S. and Canada.

상품명

AGRONAA®; ALCO® NAA; ALPHASPRA ®; AMCOTONE® APPL-SET®; CELMONE®; DESTRUXOL®; DIP’N GROW®; FRUITONE®; GOLDENGRO®; HORMEX®; KLINGTITE®; LIQUISTIK ®; NAA 800®; NAFUSAKU®; NIAGARASTIK ®; NU-TONE®; PARMONE®; PHYMONE®; PIMACOL-SOL®; PLANOFIX®; PLUCKER®; PRIMACOL®; RHIZOPON B ROOTING POWDER; ROOTONE® (component, with Indole-3-butyric acid and 1-Naphthaleneacetamide); STAFAST®; STIK®; STOPDROP ®; TEKKAM®; TIPOFF®; TRANSPLANTONE® (component, with 1-Naphthaleneacetamide); TREHOLD ®; VARDHAK®

Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion. Mutation data reported. A skin, mucous membrane, and severe eye irritant. Can cause depression. A pesticide, When heated to decomposition it emits acrid smoke and irritating fumes.

잠재적 노출

1-Naphthaleneacetic acid is a carboxylic acid plant growth regulator used for thinning fruit sets in apples, pears, olives, and some citrus. Induces root formation on cuttings and transplants. Inhibits fruit drops. Not currently registered in EU countries (may be pending).

운송 방법

UN1759 Corrosive solids, n.o.s., Hazard Class: 8; Labels: 8-Corrosive material, Technical Name Required.

Purification Methods

Crystallise the acid from EtOH or water. [Beilstein 9 H 666, 9 IV 2424.]

비 호환성

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, chlorates nitrates, ammonia, aliphatic amines, alkanolamines, isocyanates, alkylene oxides, epichlorohydrin. Compounds of the carboxyl group react with all bases, both inorganic and organic (i.e., amines) releasing substantial heat, water and a salt that may be harmful. Incompatible with arsenic compounds (releases hydrogen cyanide gas), diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides (releasing heat, toxic, and possibly flammable gases), thiosulfates and dithionites (releasing hydrogen sulfate and oxides of sulfur).

폐기물 처리

Incineration. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers.

참고 문헌

[1] https://en.wikipedia.org/wiki/1-Naphthaleneacetic_acid
[2] http://pmep.cce.cornell.edu/profiles/herb-growthreg/naa-rimsulfuron/naa/herb-prof-naa.html

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