클로피랄리드

클로피랄리드
클로피랄리드 구조식 이미지
카스 번호:
1702-17-6
한글명:
클로피랄리드
동의어(한글):
클로피랄리드;클로피랄리드(CLOPYRALID)
상품명:
Clopyralid
동의어(영문):
3,6-DICHLOROPICOLINIC ACID;lontrel;reclaim;format;shield;LONCID;cyronal;3,6-DCP;XRM-3972;benzalox
CBNumber:
CB7186620
분자식:
C6H3Cl2NO2
포뮬러 무게:
192
MOL 파일:
1702-17-6.mol
MSDS 파일:
SDS

클로피랄리드 속성

녹는점
151-152°C
끓는 점
0°C
밀도
1.4313 (rough estimate)
굴절률
1.6100 (estimate)
인화점
0°C
저장 조건
Keep in dark place,Sealed in dry,Room Temperature
용해도
DMSO: Slightly Soluble
산도 계수 (pKa)
2.02±0.25(Predicted)
색상
White to Light yellow to Light orange
수용성
1.0g/L
Merck
14,2400
BRN
473755
LogP
1.060
CAS 데이터베이스
1702-17-6(CAS DataBase Reference)
EPA
Clopyralid (1702-17-6)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi;N,Xi,N,X
위험 카페고리 넘버 41-51/53
안전지침서 26-30-61-39
유엔번호(UN No.) UN 3077
WGK 독일 3
RTECS 번호 TJ7550700
TSCA Yes
위험 등급 9
포장분류 III
HS 번호 2933399990
유해 물질 데이터 1702-17-6(Hazardous Substances Data)
독성 LD50 in male, female rats (mg/kg): >5000, 4300 orally; LC50 (96 hr) to rainbow trout: 103.5 mg/l (Brown, Uprichard)
그림문자(GHS): GHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H318 눈에 심한 손상을 일으킴 심한 눈 손상 또는 자극성 물질 구분 1 위험 GHS hazard pictograms P280, P305+P351+P338, P310
예방조치문구:
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
0
2 0

클로피랄리드 C화학적 특성, 용도, 생산

개요

Clopyralid is an herbicide that selectively inhibits the growth of the broadleaf weed L. palustris over a panel of 17 New Zealand native non-broadleaf plant species when applied at a concentration of 1.5 mg/L. It does not inhibit growth of human pluripotent stem cells (IC50 = >100 μM) or decrease nuclear translocation of the transcription factor SOX17, a marker of teratogenic risk. In vivo, clopyralid induces brain defects in rabbits, but not rats, when administered at a dose of 250 mg/kg.

화학적 성질

White Crystalline Solid

용도

Systemic post-emergence herbicide for use in food crops and mesquite.

정의

ChEBI: An organochlorine pesticide having a 3,6-dichlorinated picolinic acid structure.

농업용

Herbicide: Clopyralid is used to control annual and perennial broadleaf weeds on rangeland, pastures, turf and lawns, rights-of-way and a few agricultural products such as sugar beets, oats, barley, mint and wheat.

상품명

ACCENT®; CONFRONT®; CURTAIL®; CURTAIL M®; DOWCO®-290; HORNET®; LONTREL®; LONTREL® 3; LONTRIL® F; LONTRIL® T; MATRIGON®; MILLENNIUM®; NAF®-280; PARADIGM®; RECLAIM®; REDEEM®; RIVERDALE®; SCORPION®; STINGER®; TRANSLINE®; WIDEMATCH®; XRM-3972®

Pharmacology

Clopyralid is systemic herbicides that is actively absorbed by foliage and, is also readily absorbed through root tissues. Once absorbed, it is translocated, primarily in the phloem, throughout the entire plant. At normal field doses, this herbicide controls many broadleaf species and are selective in pasturelands and most grass crops. The exact weed spectrum and use is specific to the compound.

잠재적 노출

Clopyralid is a pyralid herbicide used to control annual and perennial broadleaf weeds on rangeland, pastures, turf, and lawns, rights-of-way and a few agricultural products such as sugarbeets, oats, barley, mint, and wheat.

환경귀착

Clopyralid is a relatively strong acid and water soluble, making it susceptible to leaching. Most studies, however, indicate that it is metabolized relatively quickly by soilmicrobes, significantly decreasing the amount of clopyralid that is available for this process. Clopyralid is dissociated in soil because of its low pKa, and thus, its adsorption to most soils is weak and governed by the anion exchange capacity. Soils with relatively large anion exchange capacities will bind relatively large quantities of clopyralid,making it biologically unavailable. Clopyralid is not volatile.

신진 대사

Chemical. Clopyralid is stable to hydrolytic decomposition in acidic conditions becoming unstable above pH 5. It does not undergo significant photolytic degradation. Clopyralid decomposes above its melting point.
Plant. Hall and Vanden Born (29) showed that clopyralid underwent substantial metabolism in tolerant Brasica napus; i.e., 70% of applied clopyralid was metabolized 144 hours after application. Themetabolites were not fully characterized. Relatively little metabolism is thought to occur in susceptible plants.
Soil. Clopyralid is readily degraded by soil microbes, e.g., the field dissipation DT50 ranges from 8 to 66 days. The major metabolic pathway in soil microbes is decarboxylation.

운송 방법

UN3077 Environmentally Hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required

비 호환성

May react violently with strong oxidizers, bromine, 90% hydrogen peroxide, phosphorus trichloride, silver powders, or dust. Incompatible with silver compounds. Mixture with some silver compounds forms explosive salts of silver oxalate. Keep away from oxidizers, sulfuric acid, caustics, ammonia, aliphatic amines, alkanolamines, isocyanates, alkylene oxides, epichlorohydrin. Solutions are strong acids; corrosive to aluminum, iron, and tin. Compounds of the carboxyl group react with all bases, both inorganic and organic (i.e., amines) releasing substantial heat, water, and a salt that may be harmful. Incompatible with arsenic compounds (releases hydrogen cyanide gas), diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, sulfides (releasing heat, toxic, and possibly flammable gases), thiosulfates, and dithionites (releasing hydrogen sulfate and oxides of sulfur).

폐기물 처리

Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an Clopyralid 877 afterburner and scrubber. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers.

클로피랄리드 준비 용품 및 원자재

원자재

준비 용품


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