2-메톡시에틸 아세테이트

2-메톡시에틸 아세테이트
2-메톡시에틸 아세테이트 구조식 이미지
카스 번호:
110-49-6
한글명:
2-메톡시에틸 아세테이트
동의어(한글):
2-메톡시에틸아세테이트;아세트산2-메톡시에탄올;메틸셀로솔브아세트산;2-메톡시에틸아세테이트(메톡시에탄올아세테이트);메틸 셀로솔브 아세트산
상품명:
2-Methoxyethyl acetate
동의어(영문):
ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE;egmea;2-Methoxyacetate;METHYL GLYCOL ACETATE;MeCsAc;EM ACETATE;2-methoxyethyl;3-OXABUTYL ACETATE;CH3C(O)O(CH2)2OCH3;Methylglykolacetat
CBNumber:
CB8852810
분자식:
C5H10O3
포뮬러 무게:
118.13
MOL 파일:
110-49-6.mol
MSDS 파일:
SDS

2-메톡시에틸 아세테이트 속성

녹는점
−65 °C(lit.)
끓는 점
145 °C(lit.)
밀도
1.009 g/mL at 25 °C(lit.)
증기압
4.7 hPa (20 °C)
굴절률
n20/D 1.402(lit.)
인화점
111 °F
저장 조건
Store below +30°C.
용해도
알코올과 에테르에 용해됩니다(Weast, 1986).
물리적 상태
고체
물리적 상태
단단한 모양
색상
하얀색
폭발한계
1.7-8.8%(V)
수용성
혼화성(Lyman et al., 1982)
최대 파장(λmax)
λ: 254 nm Amax: 1.00
λ: 275 nm Amax: 0.15
λ: 300 nm Amax: 0.05
λ: 350-400 nm Amax: 0.01
Merck
14,6039
BRN
1700761
Henry's Law Constant
(x 10-6 atm?m3/mol): 3.28 at 30.00 °C (headspace-GC, Hovorka et al., 2002)
노출 한도
NIOSH REL: TWA 0.1 ppm (0.5 mg/m3), IDLH 200 ppm; OSHA PEL: TWA 25 ppm (120 mg/m3); ACGIH TLV: TWA 5 ppm (24 mg/m3).
CAS 데이터베이스
110-49-6(CAS DataBase Reference)
EPA
Ethylene glycol monomethyl ether acetate (110-49-6)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T
위험 카페고리 넘버 60-61-20/21/22
안전지침서 53-45
유엔번호(UN No.) UN 1189 3/PG 3
WGK 독일 1
RTECS 번호 KL5950000
자연 발화 온도 380 °C DIN 51794
HS 번호 2915 39 00
위험 등급 3
포장분류 III
유해 물질 데이터 110-49-6(Hazardous Substances Data)
독성 LD50 orally in rats: 3.4 g/kg (Smyth)
IDLA 200 ppm
기존화학 물질 KE-23282
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H226 인화성 액체 및 증기 인화성 액체 구분 3 경고
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P308+P313 노출 또는 접촉이 우려되면 의학적인 조치· 조언를 구하시오.
NFPA 704
2
2 0

2-메톡시에틸 아세테이트 C화학적 특성, 용도, 생산

화학적 성질

CLEAR LIQUID

물리적 성질

Colorless liquid with a mild, ether-like odor. Experimentally determined detection and recognition odor threshold concentrations were 1.6 mg/m3 (330 ppbv) and 3.1 mg/m3 (640 ppbv), respectively (Hellman and Small, 1974).

용도

Industrial solvent.

일반 설명

A clear colorless liquid with a pleasant odor. Flash point of 135°F. Denser than water and soluble in water. Vapors are heavier than air.

공기와 물의 반응

Flammable. Water soluble. Reacts slowly in water to form acetic acid and methyl alcohol; the reaction is not violent.

반응 프로필

Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

위험도

Toxic by ingestion, inhalation, and skin absorption. Moderate fire risk. Toxic by skin absorption.

건강위험

May cause irritation if splashed into eyes. Can be absorbed through the skin. Swallowing a large single dose or absorbing larged amount through skin could result in death. It is unlikely that air levels of the compound would be dangerous unless it is heated.

화재위험

Special Hazards of Combustion Products: Irritating vapors and toxic gases, such as carbon monoxide, may be formed when involved in fire.

Safety Profile

Moderately toxic by ingestion, intraperitoneal, and subcutaneous routes. hfddly toxic by inhalation and skin contact. Human systemic effects by inhalation: eye lachrymation, cough, and pulmonary changes. Experimental reproductive effects. Mutation data reported. An inhalation irritant in humans. An eye irritant. Flammable liquid when exposed to heat or flame; can react with oxidizing materials. A moderate explosion hazard. To fight fire, use CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also GLYCOL ETHERS.

잠재적 노출

Methoxyethyl acetate is used as a solvent for resins, oils, greases and inks. It is also an ingredient of lacquers, paints and adhesives.

환경귀착

Chemical/Physical. Hydrolyzes in water forming methyl cellosolve and acetic acid. At an influent concentration of 1,024 mg/L, treatment with GAC resulted in an effluent concentration of 886 mg/L. The adsorbability of the carbon used was 28 mg/g carbon (Guisti et al., 1974).

운송 방법

UN1189 Ethylene glycol monomethyl ether acetate, Hazard Class: 3; Labels: 3-Flammable liquid.

Purification Methods

Shake the methoxy-ethane with anhydrous Na2CO3, filter and distil it in a vacuum. Redistillation can be then be carried out at atmospheric pressure. [Dunbar & Bolstad J Org Chem 21 1041 1956, Beilstein 2 IV 214.]

폐기물 처리

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed. Beware of possible presence of peroxides in which case open burning may be used

2-메톡시에틸 아세테이트 준비 용품 및 원자재

원자재

준비 용품


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