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Diethyl cyanomethylphosphonate

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Products Intro: Product Name:Diethyl cyanomethyl phosphonate
CAS:2537-48-6
Purity:0.99 Package:200L PLASTIC DRUM
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Products Intro: Product Name:Diethyl cyanomethylphosphonate
CAS:2537-48-6
Purity:98%, 99% Package:100g, 500g, 1kg, 25kg
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Products Intro: Product Name:Diethyl cyanomethylphosphonate
CAS:2537-48-6
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Products Intro: Product Name:Diethyl cyanomethylphosphonate
CAS:2537-48-6
Purity:99% Package:1KG;5KG ;10KG
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Products Intro: Product Name:Diethyl cyanomethylphosphonate
CAS:2537-48-6
Purity:99% Package:25KG;5KG;1KG

Diethyl cyanomethylphosphonate manufacturers

Diethyl cyanomethylphosphonate Basic information
Product Name:Diethyl cyanomethylphosphonate
Synonyms:Diethyl cyanoMethylphosphonate, 96% 10GR;Diethyl cyanoMethylphosphonate, 96% 50GR;Phosphonicacid, P-(cyanoMethyl)-, diethyl ester;With diethyl Methyl phosphoric acid;Diethyl cyanomethylphosphote;(Cyanomethyl)diethoxyphosphine oxide;2-(Diethylphosphonyl)acetonitrile;Diethyl cyanomethanephosphonate
CAS:2537-48-6
MF:C6H12NO3P
MW:177.14
EINECS:219-806-0
Product Categories:Pyridines;Wittig Reagents;Phosphorus compounds;Horner-Emmons Reaction;Synthetic Organic Chemistry;Wittig & Horner-Emmons Reaction;2537-48-6
Mol File:2537-48-6.mol
Diethyl cyanomethylphosphonate Structure
Diethyl cyanomethylphosphonate Chemical Properties
Boiling point 101-102 °C0.4 mm Hg(lit.)
density 1.095 g/mL at 25 °C(lit.)
refractive index n20/D 1.434(lit.)
Fp >230 °F
storage temp. Inert atmosphere,2-8°C
solubility Chloroform (Soluble), Methanol (Slightly)
form Liquid
color Clear colorless to light yellow
Specific Gravity1.1261.095
Water Solubility Miscible with water, chloroform, terahydrofuran, ethyl acetate and methylene chloride.
BRN 1772981
InChIInChI=1S/C6H12NO3P/c1-3-9-11(8,6-5-7)10-4-2/h3-4,6H2,1-2H3
InChIKeyKWMBADTWRIGGGG-UHFFFAOYSA-N
SMILESP(CC#N)(=O)(OCC)OCC
CAS DataBase Reference2537-48-6(CAS DataBase Reference)
NIST Chemistry ReferenceDiethyl cyanomethylphosphonate(2537-48-6)
Safety Information
Hazard Codes Xi,Xn,C
Risk Statements 38-36/37/38-20/21/22-34-36/38
Safety Statements 26-28-36/37/39-23-45-27-36/37-9
RIDADR UN 1760 8/PG 2
WGK Germany 3
Hazard Note Irritant
HazardClass 6.1
PackingGroup III
HS Code 29310095
MSDS Information
ProviderLanguage
Diethyl cyanomethylphosphonate English
SigmaAldrich English
ACROS English
ALFA English
Diethyl cyanomethylphosphonate Usage And Synthesis
Chemical Propertiesclear colorless to light yellow liquid
UsesWittig reagent.
UsesDiethyl cyanomethyl phosphonate is used as an intermediate in Horner-Emmons reaction for the synthesis of substituted nitriles and their amide and heterocyclic derivatives. It is known as a modified Wittig reagent used in the preparation of alpha, beta-unsaturated nitriles from ketones or aldehydes like 3-hydroxy-3-methylbutanal. It reacts with epoxides and nitrones to prepare cyano-substituted cyclopropanes and aziridines respectively. It is actively involved in the synthesis of alpha-arylated alkanenitriles via reaction with aryl iodides in presence of CuI.
Biological Functions Diethyl cyanomethylphosphonate can be used to inhibit and/0r prevent the growth of undesirable algae, bacteria, fungi, yeast, and other microorganisms.
General DescriptionDiethyl cyanomethylphosphonate is a useful chemical and medical intermediate, which can be used as raw material to synthesize nitrogen-haloamine precursor AEP-ADCT containing triazine-phosphate group
Tag:Diethyl cyanomethylphosphonate(2537-48-6) Related Product Information
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