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(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE

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(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Suppliers list
Company Name: Aladdin Scientific
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Products Intro: Product Name:(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulfonate
CAS:136705-75-4
Purity:>=98%(S,S)-Me-DUPHOS-Rh Package:$169.9/100mg;$589.9/500mg;$2123.9/2g;Bulk package Remarks:98%(S,S)-Me-DUPHOS-Rh
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Products Intro: Product Name:(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulfonate, 98+% (S,S)-Me-DUPHOS-Rh
CAS:136705-75-4
Purity:98+% Package:100mg;2g;500mg
Company Name: Alfa Aesar  
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Products Intro: Product Name:(+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]benzene(1,5-cyclooctadiene)rhodiuM(I) trifluoroMethanesulfonate, 97%
CAS:136705-75-4
Package:100Mg Remarks:047051
Company Name: Energy Chemical  
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Products Intro: Product Name:1,2-Bis[(2S,5S)-2,5-diMethylphospholano]benzene(cyclooctadiene)rhodiuM(I) trifluoroMethanesulfonate
CAS:136705-75-4
Purity:97% Package:100MG,500MG
(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Basic information
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Product Name:(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE
Synonyms:(R,R)-ME-DUPHOS-RH;(S,S)-ME-DUPHOS-RH;(-)-1,2-BIS-((2R,5R)DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) TRIFLATE;(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE;(+)-1,2-BIS((2S,5S)-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) TRIFLATE;(-)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE;(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE;(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfon
CAS:136705-75-4
MF:C27H40F3O3P2RhS
MW:666.52
EINECS:
Product Categories:Chiral Catalysts, Ligands, and Reagents;DuPhos/BPE;Privileged Ligands and Complexes;organometallic complex
Mol File:136705-75-4.mol
(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Structure
(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Chemical Properties
Melting point 136.0-154.7 °C
storage temp. Refrigerator (+4°C)
form crystal
color orange
Sensitive air sensitive, store cold
CAS DataBase Reference136705-75-4
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 24/25-36/37-26
WGK Germany 3
MSDS Information
ProviderLanguage
ACROS English
(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Usage And Synthesis
ReactionsCatalyst for the enantioselective [2+2+2] cycloaddition of triynes. Reactions of 136705-75-4
Chemical Propertiesorange crystalline powder
UsesDuPhos and BPE Ligands: Highly Efficient Privileged Ligands
(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials
Tag:(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE(136705-75-4) Related Product Information
Cyclooctane Benzene (-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE 1,2-BIS(PHOSPHINO)BENZENE (-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE 1,5-Cyclooctadiene (+)-1,2-BIS[(2S,5S)-2,5-DIMETHYLPHOSPHOLANO]BENZENE (-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE