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(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT

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(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Suppliers list
Company Name: CONIER CHEM AND PHARMA LIMITED
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Products Intro: Product Name:(r)-2,2-binaphthoyl-(s,s)-di(1-phenylethyl)aminoylphosphine
CAS:415918-91-1
Purity:0.99 Package:1kg
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Products Intro: Product Name:(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
CAS:415918-91-1
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Products Intro: Product Name:(R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine
CAS:415918-91-1
Purity:0.95&0.99 Package:0.1KG;1KG;1000KG Remarks:Factory Supply
Company Name: Hangzhou MolCore BioPharmatech Co.,Ltd.
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Products Intro: Product Name:(11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
CAS:415918-91-1
Purity:NLT 98% Remarks:MC553974
Company Name: PT CHEM GROUP LIMITED
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Products Intro: Product Name:(R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine
CAS:415918-91-1
Purity:0.95&0.99 Package:0.1KG;1KG;1000KG Remarks:Factory Supply
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Basic information
Reactions
Product Name:(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
Synonyms:(S,R,R)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine,dichloromethaneadduct,min.95%;(+)-N,N-Bis[(1R)-1-phenylethyl]-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-amine, (11bS);(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%;(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct;(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT;(R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine;(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a
CAS:415918-91-1
MF:C36H30NO2P
MW:539.61
EINECS:
Product Categories:Chiral Phosphine;CPN
Mol File:415918-91-1.mol
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Structure
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Chemical Properties
Melting point 102-103 °C
Boiling point 710.7±63.0 °C(Predicted)
alpha +427° (c 0.83, CHCl3)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka-0.57±0.20(Predicted)
form Powder
color white
Sensitive moisture sensitive
CAS DataBase Reference415918-91-1
Safety Information
Hazard Codes Xn
Risk Statements 36/37/38-22
Safety Statements 26-36/37/39
WGK Germany 3
HS Code 2934.99.4400
MSDS Information
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Usage And Synthesis
Reactions
  • A ligand for asymmetric conjugate addition of dialkyl zinc reagents to activated olefins.
  • Ligand used in the iridium-catalyzed, enantioselective addition of nucleophiles to achiral
  • allylic esters.
  • Asymmetric hydrogenation.
  • Ir-catalyzed regio- and enantioselective Friedel-Crafts allylic alkylation of indoles.
  • Asymmetric hydrovinylation.
  • Used in 1,3-dipolar cycloaddition reactions of azomethine ylides and alkenes,9a and
  • Rh-catalyzed [5+2] cycloaddition of alkyne-vinyl-cyclopropanes.9b
  • Palladium-catalyzed enantioselective de-epimerization in catalytic asymmetric allylic alkylation.
  • Palladium-catalyzed enantioselective diamination of alkyl dienes.
Reactions of 415918-91-1
Uses(R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a'']dinaphthalen-4-yl)bis(1-phenylethyl)amine (CAS# 415918-91-1) is an organic catalyst used in the stereoselective preparation of homoallylic nitriles.
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Preparation Products And Raw materials
Tag:(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT(415918-91-1) Related Product Information
BARIUM DINONYLNAPHTHALENESULFONATE (R)-MONOPHOS (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)[(1R)-1-PHENYLETHYL]AMINE (R)-N-(2-PROPYL)-1-PHENYLETHYLAMINE HYDROCHLORIDE (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (R)-MONOPHOS (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT (R)-(+)-N-BENZYL-1-PHENYLETHYLAMINE HYDROCHLORIDE (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) (R,R)-(+)-BIS(ALPHA-METHYLBENZYL)AMINE HYDROCHLORIDE (R,R)-(+)-BIS(ALPHA-METHYLBENZYL)AMINE HYDROCHLORIDE N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][