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3-(Aminomethyl)pyridine

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Products Intro: Product Name:Picolamine
CAS:3731-52-0
Purity:99% Package:1KG;122USD|1000KG;1USD
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Products Intro: Product Name:3-(Aminomethyl)pyridine
CAS:3731-52-0
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Products Intro: Product Name:3-(Aminomethyl)pyridine 3731-52-0
CAS:3731-52-0
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Products Intro: Product Name:3-(Aminomethyl)pyridine
CAS:3731-52-0
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Products Intro: Product Name:3-(Aminomethyl)pyridine
CAS:3731-52-0
Purity:0.99 Package:5KG;1KG Remarks:C6H8N2

3-(Aminomethyl)pyridine manufacturers

  • Picolamine
  • Picolamine pictures
  • $29.00 / 1g
  • 2024-10-28
  • CAS:3731-52-0
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  • Purity: 99.64%
  • Supply Ability: 10g
  • Picolamine
  • Picolamine pictures
  • $122.00 / 1KG
  • 2024-01-11
  • CAS:3731-52-0
  • Min. Order: 1KG
  • Purity: 99%
  • Supply Ability: g-kg-tons, free sample is available
  • 3-(Aminomethyl)pyridine
  • 3-(Aminomethyl)pyridine pictures
  • $15.00 / 1KG
  • 2021-07-13
  • CAS:3731-52-0
  • Min. Order: 1KG
  • Purity: 99%+ HPLC
  • Supply Ability: Monthly supply of 1 ton
3-(Aminomethyl)pyridine Basic information
Product Name:3-(Aminomethyl)pyridine
Synonyms:3-Pyridylmethanamine;Pyridine-3-methanamine;3-(Aminomethyl)pyrid;3-(AMinoMethyl)pyridine, 99+% 100ML;1-(Pyridin-3-yl)MethanaMine;NSC 59706;3-(AMINOMETHYL)PYRIDINE FOR SYNTHESIS;(Pyridin-3-yl)methylamine, Nicotinylamine
CAS:3731-52-0
MF:C6H8N2
MW:108.14
EINECS:223-091-0
Product Categories:Building Blocks;C6;Chemical Synthesis;Heterocyclic Building Blocks;Pyridines;Aromatics;Heterocycles;Miscellaneous Reagents;Nitrogen cyclic compounds;Pyridines derivates;Amines
Mol File:3731-52-0.mol
3-(Aminomethyl)pyridine Structure
3-(Aminomethyl)pyridine Chemical Properties
Melting point −21 °C(lit.)
Boiling point 73-74 °C1 mm Hg(lit.)
density 1.062 g/mL at 25 °C(lit.)
refractive index n20/D 1.551(lit.)
Fp 213 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility soluble in Chloroform, Ethyl Acetate, Methanol
form clear liquid
pka8.34±0.29(Predicted)
color Colorless to Light yellow
PH11-12 (100g/l, H2O, 20℃)
Water Solubility FREELY SOLUBLE
Sensitive Air Sensitive
BRN 108056
CAS DataBase Reference3731-52-0(CAS DataBase Reference)
NIST Chemistry ReferencePicolamine(3731-52-0)
EPA Substance Registry System3-Pyridinemethanamine (3731-52-0)
Safety Information
Hazard Codes C,Xi
Risk Statements 34-37-36/37/38
Safety Statements 26-36/37/39-45-25-36
RIDADR UN 2735 8/PG 2
WGK Germany 3
Hazard Note Irritant
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 29333999
MSDS Information
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3-(Aminomethyl)pyridine Usage And Synthesis
Chemical PropertiesCLEAR COLOURLESS TO SLIGHLY YELLOW LIQUID
UsesIt finds its application as a rubefacient.
Application3-(Aminomethyl)pyridine can be used to prepare metal complexes. A number of complexes of cobalt(II), nickel(II) and copper(II) thiocyanates, chlorides and bromides with 3-pyridine amine were prepared and the stereochemical configurations of these complexes were deduced using spectroscopy and magnetism, and the decomposition of the complexes was studied by thermogravimetry and differential thermal analysis[2].
SynthesisSynthesis of 3-(aminomethyl)pyridine by traceless C3-selective umpolung of 1-amidopyridin-1-ium salts?. A natural product inspired rapid access of 3-(aminomethyl)pyridine by one-pot reaction of 1-amidopyridin-1-ium salt with aminal followed by reductive cleavage of the N–N bond is developed. This C3-selective formal C–H activation of pyridine features a traceless umpolung of the 1-amidopyridin-1-ium salt toward a Mannich type C–C bond formation of the in situ generated 1-amido-2-dialkylamino-1,2-dihydropyridine intermediate[1].
References[1] TANG P, XIAO D, WANG B. Synthesis of 3-(aminomethyl)pyridine by traceless C3-selective umpolung of 1-amidopyridin-1-ium salts?[J]. Chemical Communications, 2017. DOI:10.1039/C6CC09582H.
[2] J. R. ALLAN  M. J P  A D Paton. The preparation, characterisation and thermal analysis studies on complexes of cobalt(II), nickel(II), and copper(II) with 3-picolylamine[J]. Journal of Thermal Analysis and Calorimetry, 1985. DOI:10.1007/BF01913603.
Tag:3-(Aminomethyl)pyridine(3731-52-0) Related Product Information
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