9-methoxy-5,11-dimethyl-6H-pyrido[4,3-b]carbazole

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CAS:10371-86-5
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9-methoxy-5,11-dimethyl-6H-pyrido[4,3-b]carbazole Basic information
Product Name:9-methoxy-5,11-dimethyl-6H-pyrido[4,3-b]carbazole
Synonyms:9-methoxy-5,11-dimethyl-6H-pyrido[4,3-b]carbazole;9-methoxyellipticine;9-Methoxyellipticin;ICIG-772;NSC-69187;6H-Pyrido[4,3-b]carbazole, 9-methoxy-5,11-dimethyl-
CAS:10371-86-5
MF:C18H16N2O
MW:276.33
EINECS:233-812-0
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Mol File:10371-86-5.mol
9-methoxy-5,11-dimethyl-6H-pyrido[4,3-b]carbazole Structure
9-methoxy-5,11-dimethyl-6H-pyrido[4,3-b]carbazole Chemical Properties
Melting point 286.5°C (rough estimate)
Boiling point 419.24°C (rough estimate)
density 1.1318 (rough estimate)
refractive index 1.5700 (estimate)
storage temp. -20°C
solubility DMSO: soluble
form A solid
pka16.29±0.40(Predicted)
Safety Information
MSDS Information
9-methoxy-5,11-dimethyl-6H-pyrido[4,3-b]carbazole Usage And Synthesis
DescriptionAn Ochrosia alkaloid present in O. oppositifolia and O. sandwicensis Gray, it occurs mainly in the bark of these species. It forms light yellow crystals and gives an ultraviolet spectrum in EtOH with absorption maxima at 242, 275, 290 and 335 mil. It may be characterized as the hydrochloride which has m.p. 288- 290°C following a change in crystal form at 255-265°C, or as the picrate, m.p. 273-5°C. The structure has been elucidated from the mass spectrum fragmentation pattern.
Synthesis Reference(s)The Journal of Organic Chemistry, 72, p. 7106, 2007 DOI: 10.1021/jo070774z
ReferencesBuzas, Osowiecki, Schindler., Cornpt. Rend., 247, 1390 (1958)
Goodwin, Smith, Horning.,!. Arner. Chern. Soc., 81,1903 (1959)
Mass spectrum:
Loder., Austral. J. Chern., 19, 1947 (1966)
Synthesis:
Dalton et aI., Austral. J. Chern., 20, 2715 (1967)
9-methoxy-5,11-dimethyl-6H-pyrido[4,3-b]carbazole Preparation Products And Raw materials
Tag:9-methoxy-5,11-dimethyl-6H-pyrido[4,3-b]carbazole(10371-86-5) Related Product Information
N,N-diethyl-N'-(9-methoxy-5,11-dimethyl-6H-pyrido[4,3-b]carbazol-1-yl)propane-1,3-diamine 9-methoxy-5,11-dimethyl-6H-pyrido[4,3-b]carbazole 5,11-Dimethyl-9-methoxy-6H-pyrido(4,3-b)carbazol-1-amine maleate 5,11-Dimethyl-N-ethyl-9-methoxy-6H-pyrido(4,3-b)carbazol-1-amine malea te 5,11-Dimethyl-9-methoxy-N-propyl-6H-pyrido(4,3-b)carbazol-1-amine male ate 9-METHOXY-2-METHYLELLIPTICINIUM ACETATE HYDRATE