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| | Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Basic information | | Uses |
| Product Name: | Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate | | Synonyms: | Bis(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate,98% [Rh(COD)2]BF4;Bis(1,5-cyclooctadiene)rhodium(Ⅰ) tetrafluoroborate;Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate;(1Z,5Z)-cycloocta-1,5-diene,rhodium,tetrafluoroborate;RHODIUM(I) TETRAFLUOROBORATE 1,5-CYCLOOCTADIENE COMPLEX;Bis(cycloocta-1,5-dien)rhodium(I)-tetrafluoroborat for synthesis;BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE | | CAS: | 35138-22-8 | | MF: | C16H24BF4Rh | | MW: | 406.07 | | EINECS: | 460-220-1 | | Product Categories: | Rh;organometallic complex | | Mol File: | 35138-22-8.mol |  |
| | Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Chemical Properties |
| Melting point | 210 °C | | density | 0.42 g/cm3 (20℃) | | storage temp. | Inert atmosphere,Store in freezer, under -20°C | | solubility | Chloroform (Slightly), Methanol (Slightly) | | form | Powder | | color | Red | | PH | 7 (5g/l, H2O, 20℃) | | Water Solubility | insoluble | | Sensitive | Slightly air & moisture sensitive | | Exposure limits | ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 | | InChIKey | IEMMJJILGGBYNZ-GSLAGHMSSA-M | | CAS DataBase Reference | 35138-22-8(CAS DataBase Reference) |
| Hazard Codes | F,Xi | | Risk Statements | 11-34 | | Safety Statements | 16-45-36/37/39-26 | | RIDADR | UN 2921 | | WGK Germany | 2 | | Hazard Note | Irritant | | TSCA | No | | HazardClass | 8 | | PackingGroup | III | | HS Code | 28439000 |
| | Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Usage And Synthesis |
| Uses |
- Convenient catalyst precursor, for example, with (R,R)QuinoxP* for asymmetric alkylations and hydrogenations.
- Catalyst precursor with chiral biaryl bisphosphine ligands for [2+2+2] enantioenriched cycloadditions.
| | Chemical Properties | dark red | | Uses | Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is useful for hydrogenation, isomerization reactions and is also employed as a precursor for asymmetric hydrogenations. Furthermore, it is used in the synthesis of cationic COD-Rhodium complexes with phosphine ligands. In addition, it shows an important application for enantioselective hydrogenation and hydrosilylation. |
| | Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Preparation Products And Raw materials |
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