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PHOSFOLAN

PHOSFOLAN Basic information
Chemical Properties
Product Name:PHOSFOLAN
Synonyms:(Diethoxyphosphinyl)dithioimidocarbonic acid cyclic ethylene ester;(diethoxyphosphinyl)dithio-imidocarbonicacicyclicethyleneester;(diethoxyphosphinyl)dithioimidocarbonicacidcyclicethyleneester;1,2-Ethanedithiol, cyclic ester with P,P-diethyl phosphonodithioimidocarbonate;1,2-Ethanedithiol, cyclic S,S-ester with phosphonodithioimidocarbonic acid O,O-diethyl ester;1,2-ethanedithiol,cyclicesterwithp,p-diethylphosphonodithioimidocarbonat;1,2-ethanedithiol,cyclicesterwithp,p-diethylphosphonodithioimidocarbonate;1,2-ethanedithiol,cyclics,s-esterwithphosphonodithioimidocarbonicacidp,
CAS:947-02-4
MF:C7H14NO3PS2
MW:255.29
EINECS:213-423-2
Product Categories:INSECTICIDE;Alpha sort;Insecticides;N-PPesticides;OrganophorousAlphabetic;P;PER - POLA;Pesticides&Metabolites
Mol File:947-02-4.mol
PHOSFOLAN Structure
PHOSFOLAN Chemical Properties
Melting point 40.75°C
Boiling point 116.5°C
density 1.42±0.1 g/cm3(Predicted)
refractive index n25D 1.5463
storage temp. 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
pka-4.95±0.20(Predicted)
form solid
color White to Off-White
EPA Substance Registry SystemPhosfolan (947-02-4)
Safety Information
Hazard Codes T+
Risk Statements 27/28
Safety Statements 28-36/37-45
RIDADR 2783
RTECS NJ6475000
HazardClass 6.1(a)
PackingGroup I
Hazardous Substances Data947-02-4(Hazardous Substances Data)
MSDS Information
PHOSFOLAN Usage And Synthesis
Chemical PropertiesPhosfolan is a solid organophosphorus insecticide in yellow colour or colourless appearance. Phosfolan is susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. On heating, phosfolan gets decomposed and release/emits toxic gases and vapours, CO, NOx, SOx, and Pox. It does not undergo hazardous polymerisation reaction. Partial oxidation by oxidising agents may result in the release of toxic phosphorus oxides. Phosfolan is susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidising agents may result in the release of toxic phosphorus oxides. Phosfolan gets hydrolysed by alkalis.
Chemical PropertiesPhosfolan is a colorless to yellow solid.
UsesInsecticide.
UsesPhosfolan was identified and determined to be a residual pesticide in okra samples.
DefinitionChEBI: Phosfolan is a phosphoric ester.
General DescriptionColorless to yellow solid. Used as an insecticide.
Air & Water ReactionsHydrolyzed by alkalis. [EPA, 1998].
Reactivity ProfileOrganophosphates, such as PHOSFOLAN, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.
Health HazardSimilar to parathion. Death may result due to respiratory arrest as a result of paralysis of respiratory muscles and intense bronchoconstriction. Also considered a cholinesterase inhibitor.
Fire Hazard(Non-Specific -- Organophosphorus Pesticide, n.o.s.) PHOSFOLAN may burn but does not ignite readily. Container may explode in heat of fire. When heated to decomposition, PHOSFOLAN emits very toxic fumes of oxides of phosphorus, sulfur, and nitrogen. Hydrolyzed by alkalies.
Safety ProfilePoison by ingestion and skin contact. An insecticide used against leaf-feeding larvae of cotton insect pests. When heated to decomposition it emits very toxic fumes of POx, SOx, and NOx. See also ESTERS
Potential ExposureAn organophosphate, A potential danger to those involved in the manufacture, formulation and application of this insecticide.
ShippingUN3464 Organophosphorus compound, solid, toxic, n.o.s, Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN2783 Organophosphorus pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
IncompatibilitiesOrganophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrideds and active metals. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides Incompatible with nitrates and water. May hydrolyze upon contact with water, steam and moisture, and produce toxic oxides of phosphorus, nitrogen, sulfur, and chlorine
Waste DisposalConsult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.
PHOSFOLAN Preparation Products And Raw materials
Raw materialsSodium acetate-->Diphenyl ether-->DITHIOLAN-2-IMINE
Tag:PHOSFOLAN(947-02-4) Related Product Information
1,2-Ethanedithiol Phosfolan methyl PHOSFOLAN SOLUTION 100UG/ML IN ACETONITRILE 1ML PHOSFOLAN SOLUTION 100UG/ML IN TOLUENE 1ML 1,3-DITHIOLANE DIETHYL PHOSPHORAMIDATE DITHIOLAN-2-IMINE MEPHOSFOLAN PHOSFOLAN