- Triphenylphosphine oxide
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- $5.00 / 1KG
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2024-01-14
- CAS:791-28-6
- Min. Order: 1KG
- Purity: 99%
- Supply Ability: g-kg-tons, free sample is available
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| | Triphenylphosphine oxide Basic information |
| | Triphenylphosphine oxide Chemical Properties |
| Melting point | 150-157 °C(lit.) | | Boiling point | 360 °C | | density | 1,212 g/cm3 | | vapor pressure | <1 hPa (50 °C) | | Fp | 180 °C | | storage temp. | Store below +30°C. | | solubility | methanol: 25 mg/mL, clear | | form | Crystalline Powder or Flakes | | Specific Gravity | 1.212 | | color | White to pink-brown | | Water Solubility | slightly soluble | | Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions | | BRN | 745854 | | LogP | 2.8 | | CAS DataBase Reference | 791-28-6(CAS DataBase Reference) | | NIST Chemistry Reference | (C6H5)3PO(791-28-6) | | EPA Substance Registry System | Triphenylphosphine oxide (791-28-6) |
| Hazard Codes | Xn,Xi | | Risk Statements | 22-36/37/38-52/53 | | Safety Statements | 26-61-36 | | RIDADR | 3077 | | WGK Germany | 2 | | RTECS | SZ1676000 | | Autoignition Temperature | 590 °C | | TSCA | Yes | | HazardClass | 9 | | PackingGroup | III | | HS Code | 29310095 | | Toxicity | LD50 orally in Rabbit: 685 mg/kg |
| | Triphenylphosphine oxide Usage And Synthesis |
| Description | Triphenylphosphine oxide (TPPO) is a coordinating solvent used to activate crystallization of chemical compounds. It has been used in flame retardant applications, as an epoxy cure catalyst, and more recently, to produce nanostructures. | | Chemical Properties | White solid | | Uses | Triphenylphosphine oxide can be used:
As a catalyst in Appel-type chlorination reaction of acyclic primary and secondary alcohols.
As a catalyst in stereoselective poly and dibromination of α,β-unsaturated esters and β,γ-unsaturated α-ketoester compounds.
As a promotor in the diastereoselective synthesis of α-ribofuranosides through ribofuranosylation of alcohols with ribofuranosyl iodides. | | Uses | Triphenylphosphine Oxide (Orlistat USP Related Compound C) is a catalyst in the conversion of aldehydes into 1,1-dichlorides. Triphenylphosphine Oxide is used as a catalyst for the synthesis of hightly functionalized α-CF3 γ-keto esters. | | Uses | Triphenylphosphine oxide is a phosphine ligand used for coupling reactions, epoxidations, and Michael reactions | | Definition | ChEBI: A phosphine oxide in which the substituents on phosphorus are three phenyl groups. | | Synthesis Reference(s) | Tetrahedron Letters, 31, p. 5463, 1990 DOI: 10.1016/S0040-4039(00)97873-0 | | Flammability and Explosibility | Not classified | | Purification Methods | It crystallises from absolute EtOH and is dried in vacuo. The gold chloride complex has m 177.5-178.5o. [Addison & Sheldon J Chem Soc 2705 1956, Cox & Westheimer J Am Chem Soc 80 5441 1958, Beilstein 16 III 864, 16 1011.] |
| | Triphenylphosphine oxide Preparation Products And Raw materials |
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