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Dicarbonylacetylacetonato rhodium(I)

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Company Name: Shanghai Daken Advanced Materials Co.,Ltd
Tel: +86-371-66670886
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Products Intro: Product Name:Dicarbonylacetylacetonato rhodium(I)
CAS:14874-82-9
Purity:99% Package:100g ;1KG ;5KG 25KG
Company Name: ATK CHEMICAL COMPANY LIMITED
Tel: +undefined-21-51877795
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Products Intro: Product Name:Acetylacetonatodicarbonyl rhodium
CAS:14874-82-9
Purity:98% HPLC Package:5G;10G;25G;50G;100G;250G;1KG
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Products Intro: Product Name:Dicarbonylacetylacetonato rhodium(I)
CAS:14874-82-9
Purity:40% Package:10g,100g
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Products Intro: Product Name:Dicarbonylacetylacetonato rhodium(I)
CAS:14874-82-9
Purity:99% Package:1KG;1USD
Company Name: Accela ChemBio Inc.
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Products Intro: Product Name:(Acetylacetonato)dicarbonylrhodium(I)
CAS:14874-82-9
Purity:39% Rh Package:0.25g;1g Remarks:SY011804

Dicarbonylacetylacetonato rhodium(I) manufacturers
Dicarbonylacetylacetonato rhodium(I) Basic information
Reaction
Product Name:Dicarbonylacetylacetonato rhodium(I)
Synonyms:DICARBONYLACETYLACETONATO RHODIUM(I);DICARBONYLRHODIUM(I) 2,4-PENTANEDIONATE;Acetylacetonatorhodium(I) dicarbonyl~Dicarbonyl(2,4-pentanedionato)rhodium(I);Dicarbonyl-(2,4-pentandione)-rhodium;Dicarbonyl(2,4-pentanedionato)rhodium;Dicarbonylacetylacetonatorhodium;Dicarbonylrhodium acetylacetonate;Rhodium dicarbonylacetylacetonate
CAS:14874-82-9
MF:C7H7O4Rh
MW:258.03
EINECS:238-947-9
Product Categories:Rh;metal carbonyl complexes;chemical reaction,pharm,electronic,materials
Mol File:14874-82-9.mol
Dicarbonylacetylacetonato rhodium(I) Structure
Dicarbonylacetylacetonato rhodium(I) Chemical Properties
Melting point 154-156 °C (lit.)
density 1.96[at 20℃]
vapor pressure 0.13Pa at 25℃
storage temp. Inert atmosphere,Room Temperature
solubility Soluble in acetone
form Needles or Flakes
color Greenish-red
Water Solubility insoluble
Exposure limitsACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
LogP0.4 at 20℃
NIST Chemistry ReferenceRhodium, dicarbonyl(2,4-pentanedionato-o,o')-, (sp-4-2)-(14874-82-9)
EPA Substance Registry SystemRhodium, dicarbonyl(2,4-pentanedionato-.kappa.O2,.kappa.O4)-, (SP-4-2)- (14874-82-9)
Safety Information
Hazard Codes Xi,F,T
Risk Statements 36/37/38-44-43-25
Safety Statements 26-37/39-45-36/37/39-24/25
RIDADR 3282
WGK Germany 3
TSCA No
HazardClass 6.1
PackingGroup III
HS Code 28439000
MSDS Information
ProviderLanguage
(Acetylacetonato)dicarbonylrhodium(I) English
SigmaAldrich English
ACROS English
ALFA English
Dicarbonylacetylacetonato rhodium(I) Usage And Synthesis
Reaction
  1. Precatalyst for hydroformylation of olefins.
  2. Precatalyst for silylformylation of olefins.
  3. Precatalyst for carbonylative silylcarbo-cyclization in the syntheses of isodomoic acids.
  4. Precatalyst for the conjugate addition of aryl- and alkenylboronic acids to enones.
Reactions of 14874-82-9_1
Reactions of 14874-82-9_2
Chemical PropertiesRed/Green Crystalline Powder
UsesUmicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Catalyst for various carbonylation reactions, silylcarbocyclizations,conjugate additions to enones, carbamoylstannation,and reduction of aromatic nitro compounds
UsesEmployed in in situ formation of a fluorous-soluble hydroformylation catalyst of interest in molecular engineering.
Uses(Acetylacetonato)dicarbonylrhodium(I) is used in in situ formation of a floors-soluble hydroformylation catalyst of interest in molecular engineering. It is also used as a catalyst for various carbonylation reactions, silylcarbocyclizations, conjugate additions to eons, carbamoylstannation, and reduction of aromatic nitro compounds. It is also used in Hydroformylation reaction.
Flammability and ExplosibilityFlammable
Dicarbonylacetylacetonato rhodium(I) Preparation Products And Raw materials
Tag:Dicarbonylacetylacetonato rhodium(I)(14874-82-9) Related Product Information
Chloroplantinic acid Tris(triphenylphosphine)rhodiu Platinum dioxide Palladium (II) Acetate Rhodium (triphenylphosphine)carbonylacetylacetonate Rhodium(III) 2,4-pentanedionate VANADIUM(III) ACETYLACETONATE Ferric acetylacetonate Bis(acetylacetonato)cobalt Zinc(II) acetylacetonate Acetylacetone ZIRCONIUM(IV) ACETYLACETONATE Rhodium Aluminum acetylacetonate titanium (Ⅳ) acetylacetonate CARBON MONOXIDE Dicarbonylacetylacetonato rhodium(I) copper (Ⅱ) acetylacetonate