2,2'-(Butylimino)diethanol
Product identifier
- Product name: 2,2'-(Butylimino)diethanol
- CBnumber: CB4185107
- CAS: 102-79-4
- EINECS Number: 203-055-0
- Synonyms: bide,N-Butyldiethanolamine
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
- Uses advised against: none
Company Identification
- Company: Chemicalbook
- Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
- Telephone: 400-158-6606
GHS Label elements, including precautionary statements
-
Symbol(GHS)
- Signal wordDanger
Substance
- Product name: 2,2'-(Butylimino)diethanol
- Synonyms: bide,N-Butyldiethanolamine
- CAS: 102-79-4
- EC number: 203-055-0
- MF: C8H19NO2
- MW: 161.24
Description of first aid measures
General adviceMost important symptoms and effects, both acute and delayed
Indication of any immediate medical attention and special treatment needed
Extinguishing media
Suitable extinguishing mediaSpecial hazards arising from the substance or mixture
Carbon oxides, Nitrogen oxides (NOx) Combustible.
Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
Further information
No data available
NFPA 704
| HEALTH | |||
| FIRE | 1 | Materials that require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur. Includes some finely divided suspended solids that do not require heating before ignition can occur. Flash point at or above 93.3 °C (200 °F). (e.g. mineral oil, ammonia) | |
| REACT | 0 | Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2) | |
| SPEC. HAZ. |
Personal precautions, protective equipment and emergency procedures
For personal protection see section 8.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal.
Reference to other sections
For disposal see section 13.
Precautions for safe handling
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store in cool place.
Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
control parameter
Hazard composition and occupational exposure limitsExposure controls
Appropriate engineering controlsHandle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.
Full contact
Material: butyl-rubber
Minimum layer thickness: 0,3 mm Break through time: 480 min
Material tested:Butoject? (KCL 897 / Aldrich Z677647, Size M)
Splash contact Material: Nitrile rubber
Minimum layer thickness: 0,4 mm Break through time: 60 min
Material tested:Camatril? (KCL 730 / Aldrich Z677442, Size M)
data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Where risk assessment shows air-purifying respirators are appropriate use a full- face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Do not let product enter drains.
Information on basic physicochemical properties
- Appearancecolourless, to, light yellow liquid
- Odouramine-like
- Odour ThresholdNo data available d) pH 10,8 - 11,1 at 100 g/l at 20 °C Melting point/freezing point Initial boiling point and boiling range Melting point: -70 °C 284 °C at 1.013 hPa Flash point 143 °C - closed cup - Tested according to Annex V of Directive 67/548/EEC. Evaporation rate No data available Flammability (solid, gas) Upper/lower flammability or explosive limits No data available Upper explosion limit: 6,5 %(V) Lower explosion limit: 1,1 %(V) Vapour pressure 0,012 hPa at 25 °C - (calculated) 3,6 hPa at 120 °C Vapour density No data available Relative density 0,974 g/cm3 at 15 °C Water solubility completely miscible Partition coefficient: n-octanol/water Autoignition temperature Decomposition temperature log Pow: 0,58 at 25 °C - Bioaccumulation is not expected. No data available No data available Viscosity No data available Explosive properties No data available Oxidizing properties No data available
- Melting point/freezing pointMelting point: -70 °C
- Initial boiling point and boiling range284 °C at 1.013 hPa
- Flash point143 °C - closed cup - Tested according to Annex V of Directive 67/548/EEC.
- Evaporation rate260 °F
- Flammability (solid, gas)No data available
- Upper/lower flammability or explosive limits Upper explosion limit: 6,5 %(V) Lower explosion limit: 1,1 %(V)
- Vapour pressure0,012 hPa at 25 °C - (calculated) 3,6 hPa at 120 °C
- Vapour density1 mm Hg ( 25 °C)
- Relative density0,974 g/cm3 at 15 °C
- Water solubilitycompletely miscible
- Partition coefficient: n-octanol/waterlog Pow: 0,58 at 25 °C - Bioaccumulation is not expected.
- Autoignition temperatureNo data available
- Decomposition temperatureNo data available
- ViscosityNo data available
- Explosive propertiesNo data available
- Oxidizing propertiesNo data available
Other safety information
Solubility in other solvents
Methanol at 20 °C
-
soluble
Ethanol at ca.20 °C
-
completely miscible Benzene at ca.20 °C
-
completely miscible Toluene at 20 °C
-
soluble
Ether at ca.20 °C
-
completely miscible
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
No data available
Conditions to avoid
No data available
Incompatible materials
No data available
Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides, Nitrogen oxides (NOx)
Other decomposition products - No data available In the event of fire: see section 5
Information on toxicological effects
Acute toxicityResult: Corrosive - 20 h (OECD Test Guideline 404)
Result: Causes burns. Remarks: (External MSDS) Causes serious eye damage.
Result: negative
(OECD Test Guideline 406)
Escherichia coli/Salmonella typhimurium Result: negative
In vitro mammalian cell gene mutation test Mouse lymphoma test
Result: negative
Mutagenicity (mammal cell test): chromosome aberration. Human lymphocytes
Result: negative
Acute inhalation toxicity - mucosal irritations, Cough, Shortness of breath, Possible damages:, damage of respiratory tract
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Systemic effects:
cardiovascular disorders Other information
Under given conditions, contact with nitrites or nitric acid can lead to the formation of nitrosamines, which have shown themselves to be carcinogenic in animal experiments. Further data:
Other dangerous properties can not be excluded.
Handle in accordance with good industrial hygiene and safety practice.
Toxicity
static test EC50 - Daphnia magna (Water flea) - > 100 mg/l - 48 h (OECD Test Guideline 202)
static test NOEC - Daphnia magna (Water flea) - 100 mg/l - 48 h (OECD Test Guideline 202)
(OECD Test Guideline 201)
static test NOEC - Pseudokirchneriella subcapitata (green algae) - 25 mg/l - 72 h
(OECD Test Guideline 201)
(OECD Test Guideline 209)
Persistence and degradability
Biodegradability Result: - Readily biodegradable.
Biochemical Oxygen Demand (BOD)
Chemical Oxygen Demand (COD)
< 2 mg/g
Remarks: (External MSDS)
2.190 mg/g
Remarks: (External MSDS)
Bioaccumulative potential
Mobility in soil
Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Other adverse effects
Additional ecological information
Biological effects:
When discharged properly, no impairments in the function of adapted biological wastewater treatment plants are to be expected. Further information on ecology
Discharge into the environment must be avoided.
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself.
Contaminated packaging
Dispose of as unused product.
UN number
ADR/RID: 2735 IMDG: 2735 IATA: 2735
UN proper shipping name
ADR/RID: AMINES, LIQUID, CORROSIVE, N.O.S. (2,2'-Butyliminodiethanol)
IMDG: AMINES, LIQUID, CORROSIVE, N.O.S. (2,2'-Butyliminodiethanol)
IATA: Amines, liquid, corrosive, n.o.s. (2,2'-Butyliminodiethanol)
Transport hazard class(es)
ADR/RID: 8 IMDG: 8 IATA: 8
Packaging group
ADR/RID: II IMDG: II IATA: II
Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
Special precautions for user
No data available
Safety, health and environmental regulations/legislation specific for the substance or mixture
Regulations on the Safety Management of Hazardous ChemicalsAbbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/
【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.