ChemicalBook--->CAS DataBase List--->101-27-9

101-27-9

101-27-9 Structure

101-27-9 Structure
IdentificationBack Directory
[Name]

BARBAN
[CAS]

101-27-9
[Synonyms]

Oatax
A 980
a-980
C-847
S 847
s-847
Neoban
Caryne
CS-847
Karbin
Carbin
BARBAN
Carbine
Carbyne
Barbane
Barbamate
Chlorinat
fisonsb25
BARBANATE
ENT 28201
NSC 29168
CARBYNE(R)
Fisons B25
BARBAMATE(R)
BARBAN PESTANAL.
A 980 (herbicide)
Carbyne【pesticide】
carbyne(herbicide)
BARBAN, 100MG, NEAT
Carbyne (Herbicide)
Barban 100mg [101-27-9]
barban (ansi,bsi,wssa,iso)
chloro-2-butynylm-chlorocarbamate
Chloro-2-butynyl m-chlorocarbamate
4-chloro-2-butynyl3-chlorocarbanilate
4-Chloro-2-butynyl 3-chlorocarbanilate
2-Butynyl 4-chloro-m-chlorocarbanilate
2-butynyl-4-chloro-m-chlorocarbanilate
4-CHLORO-2-BUTYNYL-M-CHLOROCARBANILATE
4-Chlorobut-2-ynyl-m-chlorocarbanilate
4-chloro-2-butyn-1-om-chlorocarbanilate
4-chloro-2-butynylmeta-chlorocarbanilate
4-Chloro-2-butynyl3-Chlorophenylcarbamate
4-CHLOROBUT-2-YNYL-3-CHLOROPHENYLCARBAMATE
4-Chloro-2-butynyl 3-chlorophenylcarbamate
2-Butyn-1-ol, 4-chloro-, m-chlorocarbanilate
4-chloro-2-butynyl-N-(3-chlorphenyl)carbamate
m-chloro-carbanilicaci4-chloro-2-butynylester
m-chlorocarbanilicacid,4-chloro-2-butynylester
4-CHLORO-2-BUTYNYL N-(3-CHLOROPHENYL)CARBAMATE
4-Chlorobut-2-yn-1-yl (3-chlorophenyl)carbamate
n-(3-chlorophenyl)carbamatede4-chloro2-butynyle
carbanilicacid,m-chloro-,4-chloro-2-butynylester
3-CHLOROCARBANILIC ACID 4-CHLORO-2-BUTYNYL ESTER
(4-Chlor-but-2-in-yl)-N-(3-chlor-phenyl)-carbamat
m-Chlorocarbanilic acid, 4-chloro-2-butynyl ester
(4-Cloro-but-2-in-il)-N-(3-cloro-fenil)-carbammato
(3-chlorophenyl)-carbamicaci4-chloro-2-butynylester
(3-chlorophenyl)carbamicacid4-chloro-2-butynylester
(4-Chloor-but-2-yn-yl)-N-(3-chloor-fenyl)-carbamaat
N-(3-Chloro phenyl)carbamate de 4-chloro 2-butynyle
CARBANILICACID,META-CHLORO-,4-CHLORO-2-BUTYNYLESTER
Carbanilic acid, m-chloro-, 4-chloro-2-butynyl ester
4-[N-(3-Chlorophenyl)carbamoyloxy]-1-chloro-2-butyne
(3-Chlorophenyl)carbamic acid 4-chloro-2-butynyl ester
carbamicacid,(3-chlorophenyl)-,4-chloro-2-butynylester
n-(3-chlorophenyl)carbamatede4-chloro2butynyle(french)
Carbamic acid, (3-chlorophenyl)-, 4-chloro-2-butynyl ester
4-chlorbut-2-ynyl N-(3-chlorophenyl)carbamate,barban (ISO)
barban (ISO) 4-chlorbut-2-ynyl N-(3-chlorophenyl)carbamate
(4-chloor-but-2-yn-yl)-n-(3-chloor-fenyl)-carbamaat (dutch)
Carbamic acid, N-(3-chlorophenyl)-, 4-chloro-2-butyn-1-yl ester
[EINECS(EC#)]

202-930-4
[Molecular Formula]

C11H9Cl2NO2
[MDL Number]

MFCD00045297
[MOL File]

101-27-9.mol
[Molecular Weight]

258.1
Chemical PropertiesBack Directory
[Melting point ]

75-76℃
[Boiling point ]

340.8±32.0 °C(Predicted)
[density ]

1.403
[refractive index ]

1.6070 (estimate)
[storage temp. ]

0-6°C
[form ]

Powder/Solid
[pka]

12.30±0.70(Predicted)
[color ]

White
[Water Solubility ]

11mg/L(25 ºC)
[Merck ]

13,962
[BRN ]

2376181
[EPA Substance Registry System]

Barban (101-27-9)
Safety DataBack Directory
[Hazard Codes ]

Xn,N
[Risk Statements ]

22-43-50/53
[Safety Statements ]

24-36/37-60-61
[RIDADR ]

UN3077 9/PG 3
[WGK Germany ]

3
[RTECS ]

FD7700000
[HS Code ]

29242990
[Hazardous Substances Data]

101-27-9(Hazardous Substances Data)
[Toxicity]

LD50 orally in rats: 600 mg/kg (Bailey, White)
Raw materials And Preparation ProductsBack Directory
Hazard InformationBack Directory
[Chemical Properties]

Crystalline solid; melts at 75°C (167°F);insoluble in water [11 mg/L at 25°C (77°F)];slightly soluble in hexane; soluble in benzeneand chlorinated hydrocarbons.
[Chemical Properties]

Whitecrystallinesolid;meltsat75°C(167°F);insoluble in water, dissolves in benzene,toluene, and ethylene dichloride; hydrolyzedby acids and alkalies; alkaline hydrolysis liberates terminal chlorine atom.
[Uses]

Barban is used as a selective herbicide forwild oats.
[Uses]

Selective herbicide for wild oats.
[Definition]

ChEBI: A carbamate ester that is 4-chlorobut-2-yn-1-yl ester of N-(3-chlorophenyl)carbamic acid. A herbicide, it is no longer approved for use within the European Community.
[General Description]

Crystalline solid. Water solubility is 11 ppm at 20°C. Used as a selective herbicide.
[Air & Water Reactions]

Hydrolyzed by strong acid or base.
[Reactivity Profile]

BARBAN(101-27-9) is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.
[Health Hazard]

Moderately toxic by ingestion and inhalation;absorption through skin may be very slowand, therefore, almost nontoxic by dermalroute; used as a herbicide, rather than as apesticide; toxic symptoms are those of othercarbamate esters;
LD50 oral (rat): 600 mg/kg
LD50 skin (rabbit): >20,000 mg/kg.
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