ChemicalBook--->CAS DataBase List--->12354-85-7

12354-85-7

12354-85-7 Structure

12354-85-7 Structure
IdentificationBack Directory
[Name]

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
[CAS]

12354-85-7
[Synonyms]

Bis[(pentamethylcycl
PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)&
PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER
Bis(dichloro(pentamethylcyclopentadienyl)rhodium)
Bis(pentamethylcyclopentadienylrhodium dichloride)
BIS[(PENTAMETHYLCYCLOPENTADIENYL)DICHLORO-RHODIUM]
Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium
Pentamethylcyclopentadienylrhodium(Ⅲ) chloride dimer
PentaMethyl cyclopentadienyl RhodiuM dichloride diMer
DICHLOROPENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) DIMER
PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER
Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer
PentaMethylcyclopentadienylrhodiuM(III) chloride diMer 97%
Dichloro(pentamethylcyclopentadienyl)rhodium(III)dimer,99%
(Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer
Di-μ-chlorodichlorobis(pentamethylcyclopentadienyl)dirhodate
DI-M-CHLORODICHLOROBIS(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE
1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex
di-ae-chlorodichlorobis(pentamethylcyclopentadienyl)dirhodate
DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE
Di-mu-chlorodichlorobis(pentamethyl-pi-cyclopentadienyl)dirhodium
Di-mu-chlorodichlorobis-(pentamethylcyclopentadienyl)dirhodate ,98%
Dichloro(pentaMethylcyclopentadienyl)rhodiuM(III) diMer,(Cp*RhCl2)2
Dichloro(pentaMethylcyclopentadienyl)rhodiuM(III) diMer,98% (Cp*RhCl2)2
Rhodium, di-mu-chlorodichlorobis[(1,2,3,4,5-eta)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-
Di-mu-chlorodichlorobis-(pentamethylcyclopentadienyl)dirhodate ,Rhodium≥31.3% Carbon≥39.0 [Rhodium≥31.3% Carbon≥39.0]
[Molecular Formula]

C20H30Cl4Rh2 10*
[MDL Number]

MFCD00061552
[MOL File]

12354-85-7.mol
[Molecular Weight]

618.08
Chemical PropertiesBack Directory
[Appearance]

burgundy solid
[Melting point ]

>300°C
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[solubility ]

Chloroform (Sparingly), Methanol (Slightly)
[form ]

crystal
[color ]

red
[Water Solubility ]

Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether
[NIST Chemistry Reference]

Rhodium, di-«mu»-chlorodichlorobis[(1,2,3,4,5-«eta»)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-(12354-85-7)
Hazard InformationBack Directory
[Chemical Properties]

burgundy solid
[Uses]

Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

20/21/22-36/37/38-R36/37/38-R20/21/22
[Safety Statements ]

26-36-S36-S26-24/25
[WGK Germany ]

3
[TSCA ]

No
[HS Code ]

28439000
Questions And AnswerBack Directory
[Reaction]

  1. Catalyst used in the functionalization of acetanilides under solventless conditions in a ball mill.
  2. Rhodiumcatalyzed regioselective direct C-H arylation of indoles with aryl boronic acids.
  3. Catalyst used in the asymmetric transfer hydrogenation of imines in water.
  4. Facile rhodium-catalyzed synthesis of fluorinated pyridines.
  5. Rhodium-catalyzed alkylation of azobenzenes with allyl acetates.
Reactions of 12354-85-7_1
Reactions of 12354-85-7_2
Spectrum DetailBack Directory
[Spectrum Detail]

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium](12354-85-7)1HNMR
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium](12354-85-7)Raman
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