| Chemical Properties | Back Directory | [Appearance]
Cobalt hydrocarbonyl is an unstable, highly flammable and toxic gas or liquid which decomposes rapidly at room temperature to toxic cobalt carbonyl. It has an offensive odor, | [form ]
Flammable gas with an
offensive odor | [Exposure limits]
TLV-TWA 0.1 mg/m3 as Co (ACGIH)
PEL-TWA 0.1 mg/m3 as Co (OSHA). | [Uses]
Catalyst. | [EPA Substance Registry System]
Cobalt hydrocarbonyl (16842-03-8) |
| Safety Data | Back Directory | [RIDADR ]
2927 | [HazardClass ]
6.1(a) | [PackingGroup ]
II | [Safety Profile]
Poison by inhalation.
See also COBALT COMPOUNDS. |
| Hazard Information | Back Directory | [General Description]
Gas with an offensive odor. Mp: -26°C | [Air & Water Reactions]
Air [Note: Unstable gas that decomposes rapidly in air at room temperature to cobalt carbonyl & hydrogen.] | [Reactivity Profile]
COBALT HYDROCARBONYL is flammable. Reacts exothermically with strong oxidizing agents and acids. Decomposes rapidly in air at room temperature to cobalt carbonyl (an orange solid of formula Co(CO)4) and hydrogen. These products also act as reducing agents. The orange solid (cobalt carbonyl) decomposes at 52°C producing toxic fumes of carbon monoxide and cobalt; reacts with acids and strong oxidizing agents below that temperature. | [Hazard]
Flammable gas. Possible carcinogen. | [Potential Exposure]
A potential danger to those involved in manufacture and use of this material as a catalyst for organic reactions. | [First aid]
If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a Medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy. | [Shipping]
UN3281 Metal carbonyls, liquid, n.o.s., Hazard class: 6.1; Labels: 6.1 Technical Name Required, Potential Inhalation Hazard (Special Provision 5). Cylinders must be transported in a secure upright position, in a well-ventilated truck. Protect cylinder and labels from physical damage. The owner of the compressed gas cylinder is the only entity allowed by federal law (49CFR) to transport and refill them. It is a violation of transportation regulations to refill compressed gas cylinders without the express written permission of the owner. UN2927 Toxic liquids, corrosive, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, 8-Corrosive material, Technical Name Required. | [Incompatibilities]
Unstable gas; decomposes rapidly in air at room temperature to toxic cobalt carbonyl and explosive hydrogen gas. A strong metal hydride reducing agent; violent reaction with oxidizers and acids. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Aqueous solution is highly acidic. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides | [Description]
Cobalt hydrocarbonyl is a highly flammableand toxic gas or liquid which decomposes rapidly at roomtemperature to toxic cobalt carbonyl. It has an offensiveodor. Molecular weight =171.98; Boiling point =10℃;Freezing/Melting point =-26℃; Flash point = flammablegas. Hazard Identification (based on NFPA-704 M RatingSystem): Health 2, Flammability 4, Reactivity 1. Veryslightly soluble in water. | [Chemical Properties]
Cobalt hydrocarbonyl is an unstable, highly flammable and toxic gas or liquid which decomposes rapidly at room temperature to toxic cobalt carbonyl. It has an offensive odor, | [Waste Disposal]
Return refillable compressed gas cylinders to supplier. | [Health Hazard]
The toxic effects are similar to those ofnickel tetracarbonyl or iron pentacarbonyl.The acute toxicity, however, is lower thanthat of these two carbonyls. Inhalation ofthe gas can cause dizziness, giddiness, andheadache. It readily decomposes at roomtemperature producing toxic carbon monoxide.A 30-minute LC50 in rats is 165 mg/m3(Palmes et al. 1959). | [Fire Hazard]
Flammable gas; the liquid form can explode
when heated in a closed container due
to rapid decomposition and heavy pressure
buildup. | [storage]
Color Code—Yellow Stripe (strong reducingagent): Reactivity Hazard; Store separately in an area isolated from flammables, combustibles, or other yellow-codedmaterials. Prior to working with this chemical you shouldbe trained on its proper handling and storage. Store in acool, well-ventilated area. Procedures for the handling, use,and storage of cylinders should be in compliance withOSHA 1910.101 and 1910.169, as with the recommendations of the Compressed Gas Association. |
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