ChemicalBook--->CAS DataBase List--->578743-87-0

578743-87-0

578743-87-0 Structure

578743-87-0 Structure
IdentificationBack Directory
[Name]

CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)
[CAS]

578743-87-0
[Synonyms]

[(iPr)CuCl]
Chloro[1,3-bis(2,6-diisopropylphenyl)iMidazol-2-ylidene]copp
[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper chloride
CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)
Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I)
Chloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]copper(I),98%
[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I) chloride
(1,3-Bis(2,6-diisopropylphenyl)-1H-imidazol-3-ium-2-yl) copper chloride
[1,3-Bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene](chloro)copper
[Molecular Formula]

C27H36ClCuN2 *-
[MDL Number]

MFCD09264276
[MOL File]

578743-87-0.mol
[Molecular Weight]

487.587
Chemical PropertiesBack Directory
[Melting point ]

>300 °C
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

Powder
[color ]

white
[Sensitive ]

air sensitive
[InChIKey]

JPUFNIIPFXQOCB-UHFFFAOYSA-M
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P280-P261
[WGK Germany ]

3
[HS Code ]

2933299090
Questions And AnswerBack Directory
[Reaction]

  1. Catalyst for the aziridination of olefins.
  2. Mild catalyst, superior to CuCl, in the methylenetriphenylphosphorane methyleneation of aldehydes and ketones.
  3. Copper(I) catalyzed alkylation of aryl and alkenylsilanes.
  4. Copper-catalyzed formal methylative and hydrogenative carboxylation of alkynes with carbon dioxide.
  5. Regioselective copper-catalyzed carboxylation of allylboronates with carbon dioxide.
  6. Carboxylation of organoboronic esters with potassium methyl carbonate under copper catalysis.
  7. Catalytic anti-Markovnikov hydrobromination of alkynes.
  8. Copper-catalyzed borylative cross-coupling of allenes and imines.
Reactions of 578743-87-0_1
Reactions of 578743-87-0_2
Reactions of 578743-87-0_3
Reactions of 578743-87-0_4
Hazard InformationBack Directory
[Uses]

"Use for reduction of olefin and carbonyl, carbene transfer reaction, aziridination of olefins, and methyleneation of aldehydes."
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