ChemicalBook--->CAS DataBase List--->69227-47-0

69227-47-0

69227-47-0 Structure

69227-47-0 Structure
IdentificationBack Directory
[Name]

TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE
[CAS]

69227-47-0
[Synonyms]

TRI(3,5-XYLYL)PHOSPHINE
Tris(3,5-dimethylphenyl)
TRIS(3,5-XYLYL)PHOSPHINE
Trisdimethylphenylphosphine
Tri(3,5-dimethylphenyl)phosphine
tris(3,5-dimethylphenyl)-phosphin
TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE
tris(3,5-dimethylphenyl)phosphane
Phosphine, tris(3,5-dimethylphenyl)-
Tris(3,5-dimethylphenyl)phosphine,98%
TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE, 97+%
Tris(3,5-dimethylphenyl)phosphineTris(3,5-xylyl)phosphine
[EINECS(EC#)]

624-162-2
[Molecular Formula]

C24H27P
[MDL Number]

MFCD03094579
[MOL File]

69227-47-0.mol
[Molecular Weight]

346.44
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystal powde
[Melting point ]

161-164 °C
[Boiling point ]

474.1±45.0 °C(Predicted)
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

crystal
[color ]

white
[EPA Substance Registry System]

Phosphine, tris(3,5-dimethylphenyl)- (69227-47-0)
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow crystal powde
[Uses]

Catalyst for:
  • Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones
  • Highly selective rhodium-catalyzed hydrogenation reactions
  • Classical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenes

Used for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes

Used for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

22
[Safety Statements ]

26-36/37/39-22
[WGK Germany ]

3
[TSCA ]

Yes
[HS Code ]

29310099
Spectrum DetailBack Directory
[Spectrum Detail]

TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE(69227-47-0)1HNMR
TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE(69227-47-0)31PNMR
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