ChemicalBook--->CAS DataBase List--->7440-01-9

7440-01-9

7440-01-9 Structure

7440-01-9 Structure
IdentificationBack Directory
[Name]

NEON
[CAS]

7440-01-9
[Synonyms]

NEON
10Ne
neon(0)
neongas
neon atom
neonliquid
liquidneon
neonliquide
Chebi:33310
Neon, 99.999%
NEON, 99.99+%
neon,compressed
neon,refrigeratedliquid
NEON, PRESSURE TIN WITH 1 L
NEON, PRESSURE TIN WITH 600 ML
Neon, refrigerated liquid (cryogenic liquid).
[EINECS(EC#)]

231-110-9
[Molecular Formula]

Ne
[MDL Number]

MFCD00011136
[MOL File]

7440-01-9.mol
[Molecular Weight]

20.18
Chemical PropertiesBack Directory
[Definition]

Inert element of atomic number 10, noble gas group of the periodic table, aw 20.179. Three stable isotopes
[Appearance]

Neon is an inert, colorless, odorless, tasteless gas or liquid.
[Melting point ]

-248.67 °C(lit.)
[Boiling point ]

−246 °C(lit.)
[density ]

0.9002(0℃)
[vapor density ]

0.7 (21 °C, vs air)
[solubility ]

slightly soluble in H2O
[form ]

colorless gas
[color ]

colorless
[Stability:]

Stable. Very unreactive.
[Water Solubility ]

10.5mL/100g H2O (20°C, 101.32kPa) [KIR78]; Henry’s law constants, k×10?4: 13.023 (70.0°C), 12.022 (124.5°C), 9.805 (174.5°C), 7.166 (226.4°C), 4.160 (283.7°C) [POT78]
[Merck ]

13,6483
[Dielectric constant]

1.000127(20.0℃)
[History]

Discovered by Ramsay and Travers in 1898. Neon is a rare gaseous element present in the atmosphere to the extent of 1 part in 65,000 of air. It is obtained by liquefaction of air and separated from the other gases by fractional distillation. Natural neon is a mixture of three isotopes. Fourteen other unstable isotopes are known. It is very inert element; however, it is said to form a compound with fluorine. It is still questionable if true compounds of neon exist, but evidence is mounting in favor of their existence. The following ions are known from optical and mass spectrometric studies: Ne+, (NeAr)+, (NeH)+, and (HeNe+). Neon also forms an unstable hydrate. In a vacuum discharge tube, neon glows reddish orange. Of all the rare gases, the discharge of neon is the most intense at ordinary voltages and currents. Neon is used in making the common neon advertising signs, which accounts for its largest use. It is also used to make high-voltage indicators, lightning arrestors, wave meter tubes, and TV tubes. Neon and helium are used in making gas lasers. Liquid neon is now commercially available and is finding important application as an economical cryogenic refrigerant. It has over 40 times more refrigerating capacity per unit volume than liquid helium and more than three times that of liquid hydrogen. It is compact, inert, and is less expensive than helium when it meets refrigeration requirements. Neon costs about $800/80 cu. ft. (2265 l).
[EPA Substance Registry System]

Neon (7440-01-9)
Hazard InformationBack Directory
[Chemical Properties]

colourless odourless gas
[Uses]

Gas in neon light tubes; ingredient of gaseous fillers for antifog devices, warning signals, electrical current detectors, high-voltage indicators for high-tension electric lines, lightning arresters, wave-meter tubes; in Ne-He lasers; in mixtures with He and Ar in Geiger counters. Liquid as cryogen to produce low temperetures.
[General Description]

A colorless odorless noncombustible gas. Chemically inert. The vapors are lighter than air. Nontoxic, but can act as a simple asphyxiant. Exposure of the container to prolonged heat or fire may cause NEON to rupture violently and rocket. Principal use is to fill lamp bulbs and tubes.
[Reactivity Profile]

These substances undergo no chemical reactions under any known circumstances. They are nonflammable, noncombustible and nontoxic. They can asphyxiate.
[Health Hazard]

Vapors may cause dizziness or asphyxiation without warning. Vapors from liquefied gas are initially heavier than air and spread along ground.
[Fire Hazard]

Non-flammable gases. Containers may explode when heated. Ruptured cylinders may rocket.
[Hazard]

Simple asphyxiant
[Potential Exposure]

Neon is used in photoelectric bulbs and certain light tubes; in the electronic industry; in lasers; in plasma studies; and other research.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. If frostbite has occurred, seek medical attention immediately; do NOT rub the affected areas or flush them with water. In order to prevent further tissue damage, do NOT attempt to remove frozen clothing from frostbitten areas. If frostbite has NOT occurred, immediately and thoroughly wash contaminated skin with soap and water.
[Shipping]

UN1065 Neon and UN1913 Neon, refrigerated liquid (cryogenic liquid), Hazard Class: 2.2; Labels: 2.2-Nonflammable compressed gas. Cylinders must be transported in a secure upright position, in a well-ventilated truck. Protect cylinder and labels from physical damage. The owner of the compressed gas cylinder is the only entity allowed by federal law (49CFR) to transport and refill them. It is a violation of transportation regulations to refill compressed gas cylinders without the express written permission of the owner.
[Incompatibilities]

Compressed neon gas under pressure may explode when heated.
[Description]

In 1898, Dr William Ramsay and Morris M. Travers, a Scottish scientist and a British scientist, respectively, discovered neon as a condensation product in liquefied air, as in a process similar to that used to collect neon today. Neon’s use in lighting evolved from discoveries that gases under low pressure conduct electricity. When some flowing electrons collide with residual gas in an evacuated glass tube, the resulting ions emit light as they return to their nonexcited state. The color of the light depends on the residual gas; neon gas produces a red color and argon, another inert gas often used in tubes (which are frequently and incorrectly called neon lights), produces a blue color. These two basic colors are often modified into many different hues by the addition of such elements as mercury and cadmium. The neon found on the Earth is considered to be primordial in origin. Most of the neon is sequestered in the Earth’s rocks or dissolved in water, with small amounts escaping into the atmosphere during geologic weathering. The escaped gas is slowly lost into space faster than it is replenished. Consequently, neon constitutes only a small part (0.0018%) of the Earth’s atmosphere, although this element is estimated to be the fourth most abundant in the universe.
[Waste Disposal]

Return refillable compressed gas cylinders to supplier. Venting to atmosphere.
[Physical properties]

Neon is a monatomic atom that is considered relatively inert. It does not even combinewith itself to form a diatomic molecule, as do some other gases (e.g., H2 and O2). Duringthe 1960s it was discovered that the noble gases are not really inert. Neon and the heaviernoble gases (Kr, Xe, and Rn) can form compounds when in an ionized state with some otherelements. For example, neon can form a two-atom ionized molecule of NeH+. Neon has alsobeen forced to form a compound with fluorine.
Neon’s melting point is –248.59°C, its boiling point is –246.08°C, and its density is0.0008999 g/cm3.
[Isotopes]

There are a total of 11 isotopes of neon, three of which are stable. They are Ne-20, which makes up 90.48% of the natural abundance of neon on Earth; Ne-21, whichcontributes just 0.27% to all the neon found in nature; and Ne-22, which contributes9.25% to the natural abundance of neon. All the other isotopes have half-lives rangingfrom 3.746×10-21 seconds to 3.38 minutes.
[Origin of Name]

The word “neon” was derived from the Greek word neos, meaning “new.”
[Occurrence]

Neon is the fourth most abundant element in the universe, but it makes up only 18.18ppm of the Earth’s atmosphere. It is the 82nd most abundant element on Earth.
Neon is believed to be produced by radioactive decay deep in the Earth. As it rises to thesurface, it escapes into the atmosphere and is soon dissipated. Some neon is found mixed withnatural gas and several minerals.
Neon is produced as a secondary product of the fractional distillation of liquid nitrogenand oxygen. Air is liquefied, and as it warms, nitrogen and oxygen boil off, leaving behindseveral other colder gases, including about 75% neon, which is then passed through activatedcharcoal to remove hydrogen and other gases.
[Characteristics]

As with the other noble gases, neon is colorless, tasteless, and odorless. It glows bright redwhen electricity is passed through it in an enclosed glass tube. It will turn from a gas to a liquidat –245.92°C, and only under great pressure will it become solid. It is noncombustible andlighter than air, but not as light as helium.
[Production Methods]

Neon is derived commercially from the atmosphere. It is recovered from air after separation of oxygen and nitrogen in air separation plants. The recovery process is based on liquefaction of air. Neon and helium have boiling points below that of liquid air. Thus, at liquid air temperature, nitrogen, oxygen, argon, krypton, and xenon remain in the liquid form, while a gas stream consisting of neon, helium, and some nitrogen is collected as gaseous mixture. The composition of this mixture can vary with the condenser and rate of withdrawal. Nitrogen is removed further by passing the gaseous mixture at 5 to 6 atm through a condenser maintained at liquid nitrogen temperatures. The residue after this step contains neon as the major component, with significant amounts of helium, hydrogen, and nitrogen.
Such crude neon mixture is purified by various chemical and physical processes. Hydrogen is separated by chemically oxidizing it to water, which is removed by drying. Remaining nitrogen from the crude neon is removed by adsorption over charcoal at the liquid nitrogen temperature. After the removal of nitrogen and hydrogen, the technical grade neon may contain about 75% neon and 25% helium. Such neon-helium mixtures may be further separated into their individual components either by differential absorption on charcoal at cold temperatures or by fractional distillation of their liquefied mixture. Fractional distillation, based on the difference of boiling points between helium (-269°C) and neon (-223°C), is the more expensive process. Neon also may be obtained in liquid form if the charcoal in the adsorption process is maintained at its liquefaction temperature. Process conditions may vary depending on purity of the product desired.
[Purification Methods]

Pass the gas through a copper coil packed with 60/80 mesh 13X molecular sieves which is cooled in liquid N2, or through a column of Ascarite (NaOH-coated silica adsorbent).
[Toxicity evaluation]

Neon gas is a simple asphyxiant. It displaces the oxygen necessary to support life. When normal levels of oxygen are not present in the body, then all tissues, organs, and organ systems eventually malfunction. Tissues with particularly high oxygen and energy requirements, including the brain and heart, are particularly susceptible to harmful effects resulting from reduced levels of oxygen in the body.
Safety DataBack Directory
[Safety Statements ]

38
[RIDADR ]

UN 1065 2.2
[WGK Germany ]

3
[RTECS ]

QP4450000
[F ]

4.5-31
[DOT Classification]

2.2 (Nonflammable gas)
[HazardClass ]

2.2
[Safety Profile]

An inert asphpant gas.
[Hazardous Substances Data]

7440-01-9(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

HELIUM
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