1-[[(1R,8aR)-2,3,4,5,6,7,8,8a-octahydro-1H-quinolizin-1-yl]methyl]pipe ridine-2,6-dione

1-[[(1R,8aR)-2,3,4,5,6,7,8,8a-octahydro-1H-quinolizin-1-yl]methyl]pipe ridine-2,6-dione Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

The leaves of Lamprolobium fruticosum yields this alkaloid as a colourless oil, [α]²⁰_Do + 29° (EtOH) and furnishing a crystalline picrate, m.p. 153-4°C. Acid hydrolysis of the alkaloid yields glutaric acid and (+ )-l-aminoethylquinolizidine. The stereochemistry of the latter has been established by demonstrating the identity of the N-acetyl derivative, m.p. l44-5°C; [α]²⁰_Do + 46° (EtOH) with that prepared from epilupinine. The structure has been confirmed from the infrared, NMR and mass spectra. The total synthesis of the optically inactive alkaloid and its epimer has been carried out.

Einzelnachweise

Hart, Johns, Lamberton., Chem. Commun., 302 (1968)
Hart, Johns, Lamberton., Austral. J. Chem., 21, 1619 (1968)
Synthesis:
Jeffcoat., Diss. Abstr. Int., 30B, 4973 (1970)
Yamada, Hatano, Matsui., Agr. Bioi. Chem., 34, 1536 (1970)

1-[[(1R,8aR)-2,3,4,5,6,7,8,8a-octahydro-1H-quinolizin-1-yl]methyl]pipe ridine-2,6-dione Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

1-[[(1R,8aR)-2,3,4,5,6,7,8,8a-octahydro-1H-quinolizin-1-yl]methyl]pipe ridine-2,6-dione Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Firmenname	Telefon	E-Mail	Land	Produktkatalog	Edge Rate
TargetMol Chemicals Inc.	+1-781-999-5354	support@targetmol.com	United States	19973	58

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• 1-[[(1R,8aR)-2,3,4,5,6,7,8,8a-octahydro-1H-quinolizin-1-yl]methyl]pipe ridine-2,6-dione
• (+)-1-[[(1R,9aβ)-Octahydro-2H-quinolizine-1-yl]methyl]-2,6-piperidinedione
• (+)-Lamprolobine
• 1-[[(1R,9aβ)-Octahydro-2H-quinolizine-1β-yl]methyl]piperidine-2,6-dione
• Lamprolobine
• 2,6-Piperidinedione, 1-[[(1R,9aR)-octahydro-2H-quinolizin-1-yl]methyl]-
• 18688-40-9