INCANINE

480-77-3

CAS-Nr.: 480-77-3

Englisch Name:: INCANINE

Synonyma:: INCANINE;2H-[1,6]Dioxacycloundecino[2,3,4-gh]pyrrolizine-2,6(3H)-dione, 4,5,8,10,12,13,13a,13b-octahydro-5-hydroxy-4,5-dimethyl-3-(1-methylethyl)-, (3R,4S,5R,13aR,13bR)- (9CI)

CBNumber:: CB01426771

Summenformel:: C18H27NO5

Molgewicht:: 337.41

MOL-Datei:: 480-77-3.mol

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Eigenschaften Sicherheit Verwendungswort

INCANINE Eigenschaften

Schmelzpunkt:: 96-7°C

Sicherheit

RIDADR	1544
HazardClass	6.1(b)
PackingGroup	III

INCANINE Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

This alkaloid, and its N-oxide (q.v.), have been isolated from Heliotropium olgae Bge., and Trichodesma incanum (Bge.) D.C. The base forms colourless crystals from Me2CO and has a specific rotation of [α]_D 38.76° (c 1.625, EtOH). It forms a number of crystalline salts and derivatives, e.g. the hydrochloride, m.p. 199°C; hydrobromide, m.p. 206-8°C; hydriodide, m.p. 206-7°C; nitrate, m.p. 182°C; aurichloride, m.p. 154°C; picrate, m.p. 246°C and the methiodide, m.p. 227-8°C.

Einzelnachweise

Yunusov, Plekhanova, Dokl. Akad. Nauk. Uzbek SSR, 4, 28 (1953)
Yunusov, P1ekhanova, ibid, 4,31 (1957)
Yunusov, Plekhanova, ibid, 5,13 (1957)
Yunusov, Plekhanova, ibid, 6,19 (1957)
Yunusov, Plekhanova,J. Gen. Chem. USSR, 29, 677 (1959)
Rashkes, Abdullaev, Yunusov, Khim. Prir. Soedin., 10,40 (1974)

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INCANINE
2H-[1,6]Dioxacycloundecino[2,3,4-gh]pyrrolizine-2,6(3H)-dione, 4,5,8,10,12,13,13a,13b-octahydro-5-hydroxy-4,5-dimethyl-3-(1-methylethyl)-, (3R,4S,5R,13aR,13bR)- (9CI)
480-77-3