Matridin-15-one, (5.beta.,7.beta.,11.alpha.)-

Matridin-15-one, (5.beta.,7.beta.,11.alpha.)- Struktur
6783-60-4
CAS-Nr.
6783-60-4
Englisch Name:
Matridin-15-one, (5.beta.,7.beta.,11.alpha.)-
Synonyma:
Leontine;Aids087429;Isoleontine;Aids-087429;ALLOMATRINE(RG);(-)-Allomatrine;Matrine Impurity 1;Matridin-15-one, (5.beta.,7.beta.,11.alpha.)-;1H,5H,10H-Dipyrido[2,1-F:3',2',1'-ij][1,6]naphthyridin-10-one, dodecahydro-, (7ar,13as,13bs,13cs)-
CBNumber:
CB12496552
Summenformel:
C15H24N2O
Molgewicht:
248.36
MOL-Datei:
6783-60-4.mol

Matridin-15-one, (5.beta.,7.beta.,11.alpha.)- Eigenschaften

Schmelzpunkt:
107~108℃
Siedepunkt:
190-210 °C(Press: 7 Torr)
Dichte
1.16±0.1 g/cm3(Predicted)
pka
9.47±0.20(Predicted)

Sicherheit

Matridin-15-one, (5.beta.,7.beta.,11.alpha.)- Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

A tetracyclic alkaloid present in Leontice Eversmanii Bge. this base is laevorotatory with [α]D - 7S.2°. It gives crystallines salts, e.g. the perchlorate, m.p. 252°C; methiodide, m.p. 297°C and the picrate as yellow needles, m.p. 177-9°C. The structure has been determined from the NMR and mass spectra. The optically inactive form has been synthesized and has m.p. S5-7° C, giving a crystalline hydrochloride, m.p. 215-7° C.

Einzelnachweise

Platonova, Kuzovkov, Massagetov., 1. Gen. Chern. USSR, 23,880 (1953)
Rulko, Proskurnina., ibid, 31, 308 (1961)
Synthesis:
Mandell et ai., 1. A mer. Chern. Soc., 87, 5234 (1965)

Matridin-15-one, (5.beta.,7.beta.,11.alpha.)- Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Matridin-15-one, (5.beta.,7.beta.,11.alpha.)- Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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  • Aids087429
  • Aids-087429
  • Isoleontine
  • Leontine
  • Matridin-15-one, (5.beta.,7.beta.,11.alpha.)-
  • ALLOMATRINE(RG)
  • 1H,5H,10H-Dipyrido[2,1-F:3',2',1'-ij][1,6]naphthyridin-10-one, dodecahydro-, (7ar,13as,13bs,13cs)-
  • (-)-Allomatrine
  • Matrine Impurity 1
  • 6783-60-4
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