Cyanazin (ISO) Chemische Eigenschaften,Einsatz,Produktion Methoden
ERSCHEINUNGSBILD
WEISSES KRISTALLINES PULVER.
CHEMISCHE GEFAHREN
Zersetzung beim Erhitzen unter Bildung giftiger und ätzender Rauche (Chlorwasserstoff - s. ICSC 0163, Stickstoffoxide, Cyanide).
ARBEITSPLATZGRENZWERTE
TLV nicht festgelegt (ACGIH 2005).
MAK nicht festgelegt (DFG 2005).
AUFNAHMEWEGE
Aufnahme in den Körper durch Inhalation, über die Haut und durch Verschlucken.
INHALATIONSGEFAHREN
Verdampfung bei 20°C vernachlässigbar; eine gesundheitsschädliche Partikelkonzentration in der Luft kann jedoch schnell erreicht werden.
WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION
Tierversuche zeigen, dass die Substanz möglicherweise Fehlbildungen bei Neugeborenen hervorrufen kann.
LECKAGE
NICHT in die Kanalisation spülen. Verschüttetes Material in Behältern sammeln; falls erforderlich durch Anfeuchten Staubentwicklung verhindern. Reste sorgfältig sammeln. An sicheren Ort bringen.
R-Sätze Betriebsanweisung:
R22:Gesundheitsschädlich beim Verschlucken.
R50/53:Sehr giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
R39/23/24/25:Giftig: ernste Gefahr irreversiblen Schadens durch Einatmen, Berührung mit der Haut und durch Verschlucken.
R23/24/25:Giftig beim Einatmen, Verschlucken und Berührung mit der Haut.
R36:Reizt die Augen.
R20/21/22:Gesundheitsschädlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R11:Leichtentzündlich.
S-Sätze Betriebsanweisung:
S37:Geeignete Schutzhandschuhe tragen.
S60:Dieses Produkt und sein Behälter sind als gefährlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S16:Von Zündquellen fernhalten - Nicht rauchen.
Chemische Eigenschaften
Cyanazine is an off-white to tan crystalline
solid. Molecular
. Hazard identification (based on NFPA-704 M
Rating System): Health 2, flammability 1, reactivity 0.
Soluble in water. Physical properties may be altered by car-
rier solvents used in commercial formulations.
Verwenden
Selective pre-emergence herbicide.
Allgemeine Beschreibung
Colorless crystals. Non corrosive when dry. Used as a selective systemic herbicide.
Air & Water Reaktionen
Stable at pHs between 5.0 and 9.0, but is hydrolyzed by strong acids and bases.
Reaktivität anzeigen
A triazine derivative.
Hazard
Very toxic.
Landwirtschaftliche Anwendung
Herbicide: On August 2, 1995, the U.S. EPA announced a voluntary phase-out of the use of cyanazine. On January 6,
2000, the U.S. EPA announced the cancellation of all cyanazine registrations. It had been A U.S. EPA restricted Use
Pesticide (RUP) because of its teratogenicity and because it
has been found in groundwater. Not approved for use in EU
countries. Cyanazine is used as a pre-and post-emergent
herbicide to control annual grasses and broadleaf weeds. It
is used mostly on corn, some on cotton, and less than 1%
on grain sorghum and wheat fallow. The compound is formulated as a wettable powder, a flowable suspension, or as
granules. In California, major usages are on cotton, corn
and corn for forage, almonds, and uncultivated agricultural
areas. In 1995, cyanazine was the fourth most widely used
synthetic pesticide in the U.S. Cyanazine, atrazine, and simazine are collectively referred to as the triazines and may
be alternatively used for each other on corn and in some
other situations.
Handelsname
BLADEX®[C]; BLADEX® 80WP[C];
BULLET®; CYCLE®; CY-PRO®[C]; CYNEX®
41[C]; DW 3418®; EXTRAZINE®[C]; FORTROL®;
MATCH®; PAYZE®; SD 15418®; WL 19805®
mögliche Exposition
A potential danger to those involved
in the manufacture, formulation, and application of this her-
bicide used for preemergence or postemergence weed con-
trol in field corn.
Carcinogenicity
No increase in tumor incidence
was noted in rats fed up to 50 ppm of cyanazine for 2 years.
The same was true for mice given up to 1000 ppm in their
diets for 2 years.
Environmental Fate
Soil. In sandy loam soils (foc = 0.01), the half-life is 12–15 days. However, in silt loam
(foc = 0.028) and clay loam (foc = 0.03) soils, the reported half-life is 20–25 days (Humburg
et al., 1989). The half-life of cyanazine is longer in alkaline soils (pH >7.5) than in acidic
soils (pH <5.5) (Humburg et al., 1989)
Groundwater. According to the U.S. EPA (1986) cyanazine has a high potential to
leach to groundwater. Cyanazine amide was identified as a metabolite in groundwater in
corn fields (Muir and Baker, 1976)
Plant. In plants, cyanazine is degraded by elimination of the ethyl group, hydration
of the cyano group and the removal and replacement of the chlorine atom by a hydroxyl
group (Humburg et al., 1989).
Chemical/Physical. In laboratory tests, the nitrile group was hydrolyzed to the corresponding carboxylic acid. The rate of hydrolysis is faster under higher temperatures and
low pHs (Grayson, 1980). The chlorine atom may be replaced by a hydroxyl group forming
2((4-hydroxy-6-(ethylamino)-1,3,5-triazin-2-yl)amino)-2-methylpropanenitrile (Hartley
and Kidd, 1987)
Versand/Shipping
UN2763 Triazine pesticides, solid, toxic, Hazard
Class: 6.1; Labels: 6.1-Poisonous materials. UN3439
Nitriles, solid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-
Poisonous materials, Technical Name Required.
Inkompatibilitäten
Cyanazine decomposes in heat producing
very toxic fumes and gases of hydrogen cyanide, hydrogen
chloride; ethyl chloride; ammonia; acetone; and ethylene.
Nitriles may polymerize in the presence of metals and some
metal compounds. They are incompatible with acids; mixing
nitriles with strong oxidizing acids can lead to extremely
violent reactions. Nitriles are generally incompatible with
other oxidizing agents such as peroxides and epoxides. The
combination of bases and nitriles can produce hydrogen cya-
nide. Nitriles are hydrolyzed in both aqueous acid and base
to give carboxylic acids (or salts of carboxylic acids). These
reactions generate heat. Peroxides convert nitriles to amides.
Nitriles can react vigorously with reducing agents.
Acetonitrile and propionitrile are Soluble in water, but
nitriles higher than propionitrile have low aqueous solubility.
They are also insoluble in aqueous acids
.Attacksmetals
in the presence of heat and moisture.
Waste disposal
Dissolve or mix the material
with a combustible solvent and burn in a chemical incinera-
tor equipped with an afterburner and scrubber. All federal,
state, and local environmental regulations must be
observed. In accordance with 40CFR165, follow recom-
mendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following pack-
age label directions or by contacting your local or federal
environmental control agency, or by contacting your
regional EPA office.
Cyanazin (ISO) Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
