Thiocarbonylchlorid Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R22:Gesundheitsschädlich beim Verschlucken.
R23:Giftig beim Einatmen.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S7:Behälter dicht geschlossen halten.
S9:Behälter an einem gut gelüfteten Ort aufbewahren.
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S7/9:Behälter dicht geschlossen an einem gut gelüfteten Ort aufbewahren.
Chemische Eigenschaften
Reddish liquid. Decomposes in water and alcohol; soluble
in ether.
Verwenden
Thiophosgene is a photo degradation product of the agricultural fungicide Folpet (F402000).
Allgemeine Beschreibung
A reddish liquid. Boiling point 73.5°C. A severe eye irritant. May severely burn skin on contact. Very toxic by inhalation and by skin absorption.
Air & Water Reaktionen
Reacts with water to evolve hydrogen chloride, carbon disulfide, and carbon dioxide. Reaction is slow unless the water is hot.
Reaktivität anzeigen
Thiophosgene is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Liberates hydrogen sulfide upon reaction with acids.
Hazard
Toxic by ingestion and inhalation.
Health Hazard
Inhalation causes irritation of respiratory system and delayed pulmonary edema. Vapor irritates eyes. Liquid burns skin and eyes. Ingestion causes irritation of mouth and stomach.
Sicherheitsprofil
Poison by intravenous
route. Moderately toxic by ingestion. A skin,
mucous membrane, and severe eye irritant.
When heated to decomposition it emits very
toxic fumes of Cland SOx. See also
PHOSGENE.
mögliche Exposition
Primary irritant (w/o allergic reaction). There is not large-scale production of the chemical in the United States It is used to make other chemicals and in laboratory synthesis.
Versand/Shipping
UN2474 Thiophosgene, Hazard class: 6.1; Labels: 6.1-Poison Inhalation Hazard; Inhalation Hazard Zone B. PG 2. STN: 49 232 98.
Inkompatibilitäten
Vapors may form explosive mixture with air. Incompatible with water and alcohols. Reacts with water releasing toxic hydrogen chloride, carbon disulfide, and carbon dioxide. Reaction is slow unless the water is hot. Decomposes above 200℃ to highly flammable carbon bisulfide and carbon tetrachloride. Corrodes metals, rubber and some plastics in the presence of moisture. Thiophosgene is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Liberates hydrogen sulfide upon reaction with acids
Waste disposal
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
Thiocarbonylchlorid Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
DI-2-PYRIDYL THIONOCARBONATE
2-(6-Hydroxy-3-oxo-(3H)-xanthen-9-yl)-5-isothiocyanatobenzoesure
o-Ethoxyphenylisothiocyanat
3,4-METHYLENEDIOXYPHENYL ISOTHIOCYANATE
3-ISOTHIOCYANATO-1,5-DIMETHYL-1H-PYRAZOLE
3-CHLORO-2-METHYLPHENYL ISOTHIOCYANATE
3,5-DIMETHYLPHENYL ISOTHIOCYANATE
2-(1,3-DIMETHYL-1H-PYRAZOL-5-YL)ETHENETHIONE
2,3-DIHYDRO-1,4-BENZODIOXIN-6-YL ISOTHIOCYANATE
5-BROMO-6-ISOTHIOCYANATE QUINOXALINE
1,4-Diisothiocyanatobenzol
Amoscanate
2-ISOTHIOCYANATO-4,6-DIMETHOXYPYRIMIDINE
4-CARBOXYPHENYL ISOTHIOCYANATE
4-(1H-PYRAZOL-1-YL)PHENYL ISOTHIOCYANATE
3,5-DIMETHOXYPHENYL ISOTHIOCYANATE
1,3-diisopropyl-2-isothiocyanato-5-phenoxybenzene
5-ISOTHIOCYANATO-1,3-DIMETHYL-1H-PYRAZOLE
3-Chlor-6-isothiocyanatotoluol
2-CHLORO-4-METHYLPHENYL ISOTHIOCYANATE
