thalistyline Chemische Eigenschaften,Einsatz,Produktion Methoden
Beschreibung
A quaternary bisbenzylisoquinoline alkaloid, thalistyline has been isolated from
Thalictrum longistylum DC and T. podocarpum Hunb. grown in Columbia,
South America. The base has been isolated as the chloride which forms needles
from H20 with m.p. ISO-3°C and a specific rotation of [α]
20D + 146° (c 0.1,
MeOH). The ultraviolet spectrum of this salt has absorption maxima at 276
and 283 nm. The base has also been characterized as the crystalline iodide,
m.p. 220-3°C (dec.) and methiodide, m.p. 266-8°C (dec.). Sodium-liquid
ammonia cleavage gives an optically inactive phenolic base, C22H31NO4 as an
oil and a phenolic base C18H21NO3 as colourless crystals, m.p. 221-2°C.
Einzelnachweise
Wu, Beal, Doskotch, Tetrahedron Lett., 3687 (1976)
thalistyline Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte