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Methanol-d4

Methanol-d4 Structure
Methanol-d4 structure
CAS No.
811-98-3
Chemical Name:
Methanol-d4
Synonyms
CD3OD;Deuterated methanol;METHYL-D3 ALCOHOL-D;METHANOL-D4;METHANOL-4D;D4-Methanol;% (v/v) TMS;(2H4)methanol;Methan-d3-ol-d;METHANOL-12C-D4
CBNumber:
CB0111579
Molecular Formula:
CD4O
Molecular Weight:
36.07
MDL Number:
MFCD00044637
MOL File:
811-98-3.mol
MSDS File:
SDS
Last updated:2023-12-24 21:24:35
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Methanol-d4 Properties

Melting point -99 °C
Boiling point 65.4 °C(lit.)
Density 0.888 g/mL at 25 °C(lit.)
vapor pressure 129 hPa (20 °C)
refractive index n20/D 1.326(lit.)
Flash point 52 °F
storage temp. no restrictions.
solubility Chloroform (Slightly), Water (Slightly)
form Liquid
color Colorless
Specific Gravity 0.89
explosive limit 5.5-36.5%(V)
Water Solubility Miscible with water, ethanol, ether, acetone and chloroform.
BRN 1733278
Exposure limits ACGIH: TWA 200 ppm; STEL 250 ppm (Skin)
OSHA: TWA 200 ppm(260 mg/m3)
NIOSH: IDLH 6000 ppm; TWA 200 ppm(260 mg/m3); STEL 250 ppm(325 mg/m3)
Stability Stable. Incompatible with moisture, acids, acid chlorides, acid anhydrides, oxidizing agents, reducing agents, alkali metals. Highly flammable.
InChIKey OKKJLVBELUTLKV-MZCSYVLQSA-N
CAS DataBase Reference 811-98-3(CAS DataBase Reference)
EPA Substance Registry System Methanol-d4 (811-98-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS06,GHS08
Signal word  Danger
Hazard statements  H225-H301+H311+H331-H370
Precautionary statements  P210-P233-P280-P301+P310-P303+P361+P353-P304+P340+P311
Hazard Codes  F,T
Risk Statements  11-23/24/25-39/23/24/25
Safety Statements  7-16-36/37-45
RIDADR  UN 1230 3/PG 2
WGK Germany  1
RTECS  PC1400000
F  10-21
Autoignition Temperature 440 °C
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  28459000
Toxicity LD50 orally in Rabbit: 5628 mg/kg LD50 dermal Rabbit 17100 mg/kg
NFPA 704
3
1 0

Methanol-d4 price More Price(86)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 444758 Methanol-d4 "100%", 99.96 atom % D 811-98-3 1g $38.48 2024-03-01 Buy
Sigma-Aldrich 444758 Methanol-d4 "100%", 99.96 atom % D 811-98-3 10g $526 2024-03-01 Buy
Sigma-Aldrich 151947 Methanol-d4 ≥99.8 atom % D 811-98-3 1g $34.3 2024-03-01 Buy
Sigma-Aldrich 151947 Methanol-d4 ≥99.8 atom % D 811-98-3 10g $170 2024-03-01 Buy
Sigma-Aldrich 151947 Methanol-d4 ≥99.8 atom % D 811-98-3 50g $649 2024-03-01 Buy
Product number Packaging Price Buy
444758 1g $38.48 Buy
444758 10g $526 Buy
151947 1g $34.3 Buy
151947 10g $170 Buy
151947 50g $649 Buy

Methanol-d4 Chemical Properties,Uses,Production

Synthesis

A preparation method for providing per-deuterated methanol is provided, specifically: opening the valve of deuterium gas and carbon monoxide, and controlling the volume ratio to be 1:1 to carry out premixing (deuterium gas and carbon monoxide are respectively 2kg and 14kg, a total of 16kg). Under the pressure of 5.5MPa, at a speed of 2L/s, through the catalyst bed layer of gold oxide: platinum oxide: rhodium oxide = 1:3:2 (mass ratio) at 210~380℃, after continuous circulation reaction for 24 hours, in The per-deuterated methanol reaction solution was obtained from the separation kettle, and the obtained reaction solution was rectified to give Methanol-d4: 3.2 kg, yield 35.5%, purity 99.8%.

Chemical Properties

colourless liquid

Uses

Methanol-d4 may be used as a solvent to analyze the rate of exchange of methoxyl group in camphor and norcamphor dimethyl ketals.

Application

Methyl Alcohol-d4 is the labeled analog of methyl alcohol, a common laboratory solvent used primarily in spectroscopic techniques (UV/VIS, NMR, IR).

Definition

ChEBI: Methanol-d4 is a deuterated compound that is methanol in which all four hydrogen atoms are replaced by deuterium. It is commonly used as a solvent in NMR spectroscopy. It has a role as an amphiprotic solvent.

General Description

Methanol-d4 (CD3OD) is a deuterated NMR solvent used for NMR-based research and analyses. It has the highest isotopic enrichment and will not interfere with the desired level of detection.
The absolute infrared absorption intensities of CD3OD have been reported between 8000 and 350cm-1.

Synthesis

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Methanol-d4 Preparation Products And Raw materials

Raw materials

Preparation Products

TETRAHYDROFURAN-D8 ETHANOL-D 4-Methylbenzyl acetate KISVAASFGZJBCY-BMSJAHLVSA-N Methyl Salicylate-d3
3-Methyl-d3-indole

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Methanol-d4 Suppliers

Global( 223)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai UCHEM Inc. 		+862156762820 +86-13564624040 sales@myuchem.com China 6710 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 7845 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
Chongqing Chemdad Co., Ltd 		+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 49390 58
Richest Group Ltd 		18017061086 oled@richest-group.com CHINA 5601 58
Antai Fine Chemical Technology Co.,Limited 		18503026267 info@antaichem.com CHINA 9641 58
SHANGHAI T&W PHARMACEUTICAL CO., LTD. 		+86-021-61551413 +8618813727289 contact@trustwe.com China 5738 58
Hubei Ipure Biology Co., Ltd 		+8613367258412 ada@ipurechemical.com China 10326 58
Supplier Advantage
Shanghai UCHEM Inc. 		58
Henan Fengda Chemical Co., Ltd 		58
Henan Tianfu Chemical Co.,Ltd. 		55
career henan chemical co 		58
Chongqing Chemdad Co., Ltd 		58
CONIER CHEM AND PHARMA LIMITED 		58
Richest Group Ltd 		58
Antai Fine Chemical Technology Co.,Limited 		58
SHANGHAI T&W PHARMACEUTICAL CO., LTD. 		58
Hubei Ipure Biology Co., Ltd 		58

View Lastest Price from Methanol-d4 manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methanol-D4 pictures 2024-02-23 Methanol-D4
811-98-3
 US $54.00-606.00 / g 5g 0.99 25kg Shanghai UCHEM Inc.
Methanol-d4 pictures 2023-12-24 Methanol-d4
811-98-3
 US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Methanol-d4 pictures 2023-01-16 Methanol-d4
811-98-3
 US $20.00 / kg 1kg 99% 5000 tons Hebei Duling International Trade Co. LTD
  • Methanol-D4 pictures
  • Methanol-D4
    811-98-3
  • US $54.00-606.00 / g
  • 0.99
  • Shanghai UCHEM Inc.
  • Methanol-d4 pictures
  • Methanol-d4
    811-98-3
  • US $100.00-1.00 / KG
  • 99%
  • Henan Fengda Chemical Co., Ltd
  • Methanol-d4 pictures
  • Methanol-d4
    811-98-3
  • US $20.00 / kg
  • 99%
  • Hebei Duling International Trade Co. LTD

Methanol-d4 Spectrum

Methanol-d4(811-98-3)MSMethanol-d4(811-98-3)1HNMRMethanol-d4(811-98-3)13CNMRMethanol-d4(811-98-3)IR1Methanol-d4(811-98-3)Raman

811-98-3(Methanol-d4)Related Search:

Methanol-d4 METHANOL-D 18-CROWN-6-METHANOL (1,5-DIMETHYL-1H-PYRAZOL-3-YL)METHANOL 1,1,1-DIPHENYL-(N-METHYL-PYRROLINE-2YL)-METHANOL
1-AMINOCYCLOPROPYL-METHANOL (1,4-DIMETHYL-2-PIPERAZINYL)METHANOL,(1,4-DIMETHYLPIPERAZIN-2-YL)METHANOL (1-AMINOMETHYL-CYCLOHEXYL)-METHANOL (1-[(4-NITROPHENYL)SULFONYL]-3-PIPERIDINYL)METHANOL [1-(4-FLUOROBENZYL)PYRROLIDIN-2-YL]METHANOL
[1-(4-TRIFLUOROMETHYL-PHENYL)-CYCLOPROPYL]-METHANOL [1-(4-METHYLBENZYL)-1H-BENZIMIDAZOL-2-YL]METHANOL (1-AMINO-2,3-DIHYDRO-1H-BENZO[F]CHROMEN-2-YL)METHANOL HYDROCHLORIDE,(1-AMINO-2,3-DIHYDRO-1H-BENZO[F]CHROMEN-2-YL)-METHANOL HCL [1-(4-FLUORO-PHENYL)-CYCLOPROPYL]-METHANOL METHANOL-13C-D4
TMS (1-[5-(TRIFLUOROMETHYL)PYRIDIN-2-YL]PIPERIDIN-4-YL)METHANOL (1,4-DIOXA-SPIRO[4.5]DEC-8-YL)-METHANOL

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Methanol-d4, 99.5 atom % D, for NMR Methanol-d4, 99.6+ atom % D, for NMR Methanol-d4, 99.8 atom % D, for NMR Methanol-d4, contains 0.03% V/V % TMS, 99.8 atom % D, for NMR Methanol-d4, packaged in 0.50 ml ampules, 100.0 atom % D, for NMR Methanol-d4, packaged in 0.75 ml ampules, 100.0 atom % D, for NMR 99.96 atom % D, 99% (CP) Methanol-d4 99 atom % D Methanol-d4 99.8 atom % D, contains 0.05 % (v/v) TMS 4X GC BUFFER I (10 X 1.5 ML) (2H4)methanol METHANOL-D4, 100.0 ATOM % D (1PK=10 X 0.25ML) METHANOL-D4 , 99.8 + ATOM % D (1PK=5 X 0.5ML) METHYL-D3 ALCOHOL-D, 99.8+ ATOM % D (CON TAINS 1% V/V TMS) Methanol-D4 METHANOL-D4, 99.8 + ATOM % D (1PK=10 X 1ML) METHYL-D3 ALCOHOL-D, 100.0 ATOM % D METHYL-D3 ALCOHOL-D, 99.8+ATOM % D (SEPTUM VIALS) METHYL-D3 ALCOHOL-D, 99.8+ ATOM % D (CON TAINS 0.03% V/V TMS) METHYL-12C-D3 ALCOHOL-D, 99.95 ATOM % 12 C, 99.5 ATOM % D METHYL ALCOHOL-D4+0.05% TMS (V/V) (~0.7 METHYL-D3 ALCOHOL-D, 99.8 ATOM % D, ANH& METHANOL-D4, 99.8 ATOM % D METHYL-D3 ALCOHOL-D, 99+ ATOM % D METHYL-D3 ALCOHOL-D, 99.95 ATOM % D (1PK =10 X 0.5ML) METHYL-D3 ALCOHOL-D, 99.8 ATOM % D (CONT METHYL-D3 ALCOHOL-D, 100 ATOM % D(CONTAINS 0.03% V/V TMS) METHANOL-D(4) VIAL WITH 10 ML >99.95 ( METHYL-D3 ALCOHOL-D, 99.8+ ATOM % D, AN& METHANOL-D4, 99.8 + ATOM % D (1PK=10 X 0.75ML) METHYL-D3 ALCOHOL-D, 99.8+ ATOM % D (CON TAINS 0.1% V/V TMS) METHYL-D3 ALCOHOL-D, 99.8 + ATOM % D (0.0 3% V/V TMS, 1PK=10 X 1ML) Methanol-d4, isotopic purity 99.5+% Methanol-d4,99.8%(Isotopic) Methanol-d4,99.8%(Isotopic),contains0.05%v/vTMS Methanol-d4, 100.0 atom % D, for NMR Methanol-d4 99.8atom%D (0.75mL*10) ACETIC ANHYDRIDE SOLUTION R1 PHE CALCIUM NITRATE TETRAHYDRATE GRAN HYDROXYDE CUPRIETHYLE SOL. PHE SOLUTION IC MORPHOLINE 1G/L IN H2O Methyl-d3 alcohol-d,99.5 atom Methanol-d4, contains 0.05% TMS, 99.8% Isotopic METHANOL-D4, >=99.8 ATOM % D, CONTAINS & MethanolD4>99.8%(+0.03%tms) MethanolD4>99.8%10x0.75ml MethanolD4>99.96%10x0.75ml MethanolD4>99.8%10X0.6ml Tetradeuterio-methanol Methanol-D4 "100%" >99.95 Atom % D Methanol-D4 >99.5 Atom % D Methanol-d4, 100%(Isotopic) Methyl-d3 alcohol d, Tetradeuteromethanol (1,1,1,O-2H4)Methanol (O-2H,2H3)Methanol Methanol-d4,for NMR,packaged in 0.50 ml ampules, 100.0 atom % D Methanol-d4,for NMR,contains 0.03 v/v% TMS, 99.8% atom% D Methanol-d4,for NMR,packaged in 0.75 ml ampules, 99.8 atom % D