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(-)-Camphanic acid chloride

CAS No.
39637-74-6
Chemical Name:
(-)-Camphanic acid chloride
Synonyms
(+)-(1R,4S)-camphani;(-)-CAMPHANIC CHLORIDE;(-)-Camphanic Chloride;(-)-Camphanoyl chloride;(1S)-(-)CAMPHANYL CHLORIDE;(-)-Camphanic Chloride >(-)-CAMPHANIC ACID CHLORIDE;(1S)-(-)-CAMPHANIC CHLORIDE;(1S)-(-)-CAMPHANOYL CHLORIDE;(S)-(-)-1-CAMPHANYL CHLORIDE
CBNumber:
CB0352910
Molecular Formula:
C10H13ClO3
Molecular Weight:
216.66
MDL Number:
MFCD00135626
MOL File:
39637-74-6.mol
MSDS File:
SDS
Last updated:2023-08-17 18:11:45

(-)-Camphanic acid chloride Properties

Melting point 71-73 °C(lit.)
alpha -18 º (c=2, CCl4)
Boiling point 310.92°C (rough estimate)
Density 1.2072 (rough estimate)
refractive index 1.5390 (estimate)
storage temp. 2-8°C
solubility soluble in Dichloromethane, Ether, Ethyl Acetate, Methanol
form Powder
color Yellow to orange-brown
optical activity [α]23/D 18°, c = 2 in carbon tetrachloride
Water Solubility decomposes
Sensitive Moisture Sensitive
BRN 3590860
InChIKey PAXWODJTHKJQDZ-RGURZIINSA-N
CAS DataBase Reference 39637-74-6(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
Hazard Codes  C,Xi
Risk Statements  34-29
Safety Statements  26-36/37/39-45-8-27
RIDADR  UN 3261 8/PG 2
WGK Germany  3
10-21
HazardClass  8
PackingGroup  II
HS Code  29322090
NFPA 704
1
3 2
W

(-)-Camphanic acid chloride price More Price(38)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 21287 (1S)-(−)-Camphanic chloride for chiral derivatization, LiChropur?, ≥98.0% 39637-74-6 5G $274 2022-05-15 Buy
Sigma-Aldrich 21287 (1S)-(−)-Camphanic chloride for chiral derivatization, LiChropur?, ≥98.0% 39637-74-6 25g $1080 2022-05-15 Buy
TCI Chemical C1022 (-)-Camphanic Chloride >97.0%(T) 39637-74-6 1g $86 2024-03-01 Buy
TCI Chemical C1022 (-)-Camphanic Chloride >97.0%(T) 39637-74-6 5g $251 2024-03-01 Buy
Alfa Aesar L14148 (1S)-(-)-Camphanic chloride, 95% 39637-74-6 1g $41.65 2024-03-01 Buy
Product number Packaging Price Buy
21287 5G $274 Buy
21287 25g $1080 Buy
C1022 1g $86 Buy
C1022 5g $251 Buy
L14148 1g $41.65 Buy

(-)-Camphanic acid chloride Chemical Properties,Uses,Production

Chemical Properties

Off-White Powder

Uses

(1S)-(-)-Camphanic chloride is used as a resolving agent for alcohols as the diastereomeric esters by crystallization or chromatography and as a chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines.

Uses

An optically active resolving agent

Uses

(1S)-(-)-Camphanic chloride may be used in esterification of enantiomers in volatiles releasedf from wheat, in order to determine the proportion of enantiomers and also in quantifying the esters.

General Description

(1S)-(-)-Camphanic chloride is a chiral derivatizing agent. It can be prepared by reacting (-)-(1S,4R)-camphanic acid with thionyl chloride.

Purification Methods

It is soluble in toluene (50g/100mL at 0o) and crystallises from pet ether (b 40-60o). It sublimes at 70o/5mm, Store it dry at 0o, max (CCl4) 1805s and 1780m cm-1. Armarego et al. J Chem Soc, Perkin Trans I 2229 1976, Gerlach Helv Chim Acta 51 1587 1968, Gerlach Helv Chim Acta 68 1815 1985, Beilstein 18/8 V 101.]

124-83-4
39637-74-6
Synthesis of (-)-Camphanic acid chloride from D-(+)-Camphoric acid

(-)-Camphanic acid chloride Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 230)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12456 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15928 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555 +8617317452075 jack.li@time-chemicals.com China 1807 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32480 60
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8823 58
Xi'an Kono chem co., Ltd.,
029-86107037 13289246953 info@konochemical.com China 2995 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58

View Lastest Price from (-)-Camphanic acid chloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(-)-Camphanic acid chloride pictures 2023-08-18 (-)-Camphanic acid chloride
39637-74-6
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
Camphanic acid chloride pictures 2023-05-04 Camphanic acid chloride
39637-74-6
US $48.00-40.00 / KG 1KG 99% 20tons Guangzhou Sunton Biotechnology Co., Ltd.
(1S)-(-)-Camphanic acid chloride pictures 2023-02-18 (1S)-(-)-Camphanic acid chloride
39637-74-6
US $0.00-0.00 / kg 1kg 98% kgs Aromsyn Co., Ltd.
(-)-CAMPHANIC ACID CHLORIDE (-)-CAMPHANIC CHLORIDE (1S)-(-)-Camphanicacidchloride 3-oxa-2-oxobornane-4-carbonyl chloride (1S)-(-)-Camphanicchloride,95% (1S,4R)-(-)-Camphanic chloride (1S)-(-)-Camphanic chloride, 98% (99% EE) (-)-CAMPHANIC ACID CHLORIDE 98% 4,7,7-trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride (+)-(1R,4S)-Camphanoyl chloride 2-Oxabicyclo2.2.1heptane-1-carbonyl chloride, 4,7,7-trimethyl-3-oxo-, (1S,4R)- (-)-Camphanoyl chloride (-)-Camphanoyl chloride, (1S)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride 2-Oxabicyclo[2.2.1]heptane-1-carbonyl chloride, 4,7,7-trimethyl-3-oxo-, (1S)- (1S,4R)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid chloride (1S,4R)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid chloride [1S,4R,(-)]-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride [1S,4R,(-)]-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid chloride (-)-Camphanic acid chloride,98% (+)-(1R,4S)-camphani (-)-Camphanoyl chloride (-)-Camphanic acid chloride (1S)-(-)-Camphanic chloride 98% (1S)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride [1S]-3-OXO-4,7,7-TRIMETHYL-2-OXABICYCLO[2.2.1]HEPTANE-1-CARBONYL CHLORIDE (1S)-3-OXO-4,7,7-TRIMETHYL-2-OXABICYCLO[2.2.1]HEPTANE-1-CARBOXYL CHLORIDE (1S)-(-)-CAMPHANIC CHLORIDE (1S)-(-)-CAMPHANOYL CHLORIDE (1S)-(-)CAMPHANYL CHLORIDE (-)-(1S,4R)-CAMPHANOYL CHLORIDE (IS)-(-)-Camphenic acid chloride (-)-CaMphanic acid chloride, 98% 1GR (S)-(-)-1-CAMPHANYL CHLORIDE (1S)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chlorid (-)-Camphanic Chloride > (-)-Camphanic acid chloride, 98%, reagent grade (1S)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride(Chunks or pellets) TIANFU-CHEM (-)-Camphanic Chloride (4S)-1,7,7-trimethyl-2-oxo-3-oxabicyclo[2.2.1]heptane-4-carbonyl chloride (-)-Camphanic Chloride (-)-(1S,4R)-Camphanoyl Chloride 39637-74-6 C10H13ClO3 C10H13O3Cl Analytical Chromatography Product Catalog Asymmetric Synthesis Organic Building Blocks Acid Halides Derivatization Reagents Bicyclic Monoterpenes Terpenes for Resolution of Alcohols & Thiols Optical Resolution ACID CHLORIDE Chiral Building Blocks Chiral Derivatization Chiral Reagents Chiral Compound FINE Chemical & INTERMEDIATES