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TRIS(PENTAFLUOROPHENYL)BORANE

CAS No.
1109-15-5
Chemical Name:
TRIS(PENTAFLUOROPHENYL)BORANE
Synonyms
Tris(Pentafluorophenyl)Borate;TRIS(PENTAFLUOROPHENYL)BORON;Tris(pentafL;Perfluorotriphenylboron;perfluorotriphenylborone;PERFLUOROTRIPHENYLBORANE;TRIS(PENTAFLUOROPHENYL)BORANE;Tri (pentafluorobenzene) borane;Tris(pentafluorophenyl)borane,95%;Tris(pentafluorophenyl)borane 95%
CBNumber:
CB1113297
Molecular Formula:
C18BF15
Molecular Weight:
511.98
MDL Number:
MFCD00269813
MOL File:
1109-15-5.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

TRIS(PENTAFLUOROPHENYL)BORANE Properties

Melting point 126-131 °C (lit.)
Boiling point 327.3±42.0 °C(Predicted)
Density 0.73 g/mL at 20 °C
refractive index n20/D 1.41
Flash point 7 °C
storage temp. Inert atmosphere,Store in freezer, under -20°C
solubility Soluble in hexane, chloroform, dichloromethane, toluene, and polar solvents.
form Powder
color White to light yellow-beige
Specific Gravity 1.7
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
λmax 306nm(Toluene)(lit.)
Sensitive Moisture Sensitive
Merck 14,9755
BRN 2931347
InChIKey OBAJXDYVZBHCGT-UHFFFAOYSA-N
CAS DataBase Reference 1109-15-5(CAS DataBase Reference)
FDA UNII I3WU5E2578
EPA Substance Registry System Borane, tris(2,3,4,5,6-pentafluorophenyl)- (1109-15-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi,T,N,Xn,F
Risk Statements  36/37/38-25-67-65-50/53-38-11
Safety Statements  60-61-62-45-37/39-26-36
RIDADR  UN 1268 3/PG 2
WGK Germany  3
TSCA  No
HazardClass  6.1
PackingGroup  III
HS Code  29039990
NFPA 704
0
2 1

TRIS(PENTAFLUOROPHENYL)BORANE price More Price(37)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 442593 Tris(pentafluorophenyl)borane 95% 1109-15-5 1g $209 2024-03-01 Buy
Sigma-Aldrich 442593 Tris(pentafluorophenyl)borane 95% 1109-15-5 5G $620 2024-03-01 Buy
Sigma-Aldrich 442593 Tris(pentafluorophenyl)borane 95% 1109-15-5 100G $5420 2024-03-01 Buy
TCI Chemical T2313 Tris(pentafluorophenyl)borane >98.0%(NMR) 1109-15-5 1g $114 2024-03-01 Buy
TCI Chemical T2313 Tris(pentafluorophenyl)borane >98.0%(NMR) 1109-15-5 5g $396 2024-03-01 Buy
Product number Packaging Price Buy
442593 1g $209 Buy
442593 5G $620 Buy
442593 100G $5420 Buy
T2313 1g $114 Buy
T2313 5g $396 Buy

TRIS(PENTAFLUOROPHENYL)BORANE Chemical Properties,Uses,Production

Uses

Tris(pentafluorophenyl)borane (CAS# 1109-15-5) is a useful research chemical, used as a catalyst in the metal-free catalytic reductive cleavage of enol ethers via proposed mechanism of tandem hydrosilylation and silicon-​assisted β-​elimination. Tris(pentafluorophenyl)borane also appears as an ancillary ligand in luminescent isocyano Rh(I) complexes.

Chemical Properties

white powder

Uses

Tris(pentafluorophenyl)borane is used as an excellent activator component in homogeneous Ziegler-Natta chemistry. It is also used as a catalyst for reductions, alkylations, hydrometallation reactions and catalyzed aldol-type reactions. It is a useful Lewis acid and catalyzes hydrosilylation of aldehydes. Further, it is used in olefin polymerization catalysis. It serves as a reagent in the preparation of organometallic complexes. In addition to this, it is useful as polymerization catalysts and used to study the heterolytic cleavage of dihydrogen in associated with tri-tert-butylphosphine.

Uses

Catalyst in organic transformations; cocatalyst with group IV metallocene alkyls in olefin polymerization.

General Description

B(C6F5)3 is a Lewis acid, stronger than the inorganic parent molecule BF3. In contrast to the prominent Lewis acids, the pentafluorides of the heavier elements of group 15, B(C6F5)3 has no oxidizing properties. B(C6F5)3 forms adducts with neutral and weaker Lewis bases. B(C6F5)3 has the capability to easily accept anionic ligands bonded to metals.

TRIS(PENTAFLUOROPHENYL)BORANE Preparation Products And Raw materials

Global( 232)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
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View Lastest Price from TRIS(PENTAFLUOROPHENYL)BORANE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
TRIS(PENTAFLUOROPHENYL)BORANE pictures 2022-10-10 TRIS(PENTAFLUOROPHENYL)BORANE
1109-15-5
US $0.00-0.00 / kg 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
Tris(perfluorophenyl)borane pictures 2022-03-21 Tris(perfluorophenyl)borane
1109-15-5
US $11.60 / KG 1KG 99% 100KG Hong Kong Tiansheng New Material Trading Co., Ltd
TRIS(PENTAFLUOROPHENYL)BORANE pictures 2022-02-25 TRIS(PENTAFLUOROPHENYL)BORANE
1109-15-5
US $11.60 / KG 1KG 0.99 1KG Hong Kong Tiansheng New Material Trading Co., Ltd

TRIS(PENTAFLUOROPHENYL)BORANE Spectrum

PERFLUOROTRIPHENYLBORANE TRIS(PENTAFLUOROPHENYL)BORANE TRIS(PENTAFLUOROPHENYL)BORANE SOLUTION, ~3% IN ISOPAR TRIS(PENTAFLUOROPHENYL)BORON, 97+% Tris(pentafluorophenyl)boron,min.97% tris(pentafluorophenyl)borane solution TRIS(PENTAFLUOROPHENYL)BORON, 10% in toluene Tris(pentafluorophenyl)borane 95% perfluorotriphenylborone Tris(pentafluorophenyl)boron, min. 97% Tris(pentafluorophenyl)borane,95% Tris(pentafluorophenyl)borane ,94% Perfluorotriphenylboron Tris(2,3,4,5,6-pentafluorophenyl)borane Tris(pentafluorophenyl)borane, min. 97% Tris(pentafluorophenyl)borane, 97%, reagent grade Tris(pentafL Borane, tris(2,3,4,5,6-pentafluorophenyl)- TRIS(PENTAFLUOROPHENYL)BORON Tris(Pentafluorophenyl)Borate Tri (pentafluorobenzene) borane 1109-15-5 C18BF15 C18F15B C6F53B Analytical Standards Boranes B (Classes of Boron Compounds) Analytical Chromatography Product Catalog Alphabetic Reduction TP - TZ Synthetic Reagents organoboron compound BoronAlphabetic Precursors by Metal TP - TZ Vapor Deposition Precursors B (Classes of Boron Compounds) Boranes