ChemicalBook >> CAS DataBase List >>Tris(triphenylphosphine)rhodiu
Tris(triphenylphosphine)rhodiu
- CAS No.
- 14694-95-2
- Chemical Name:
- Tris(triphenylphosphine)rhodiu
- Synonyms
- Wilkinson;WILKINSON CATALYST;WILKINSON'S CATALYST;TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CHLORIDE;Tris(triphenylphosphine)rhodium chloride;Tetrakis(triphenlphosphine)palladium;TRIS(TRIPHENYLPHOSPHINE)CHLORORHODIUM;DECARBON;NSC 124140;Tris(triphenyL
- CBNumber:
- CB1494341
- Molecular Formula:
- C54H45ClP3Rh
- Molecular Weight:
- 925.21
- MDL Number:
- MFCD00010016
- MOL File:
- 14694-95-2.mol
- MSDS File:
- SDS
Last updated:2023-12-14 20:49:34
| Melting point | 245-250 °C (dec.) |
|---|---|
| Boiling point | >170°C |
| Density | 1.363; d 1.379 |
| vapor pressure | 0Pa at 25℃ |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| solubility | Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution |
| form | Crystalline Powder |
| color | Red-brown to maroon |
| Water Solubility | insoluble |
| Sensitive | air sensitive |
| Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
| Merck | 14,9758 |
| BRN | 4581440 |
| Exposure limits |
ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 |
| InChIKey | QEYYHUJFSQCTAE-UHFFFAOYSA-M |
| LogP | 5.69 at 20℃ |
| CAS DataBase Reference | 14694-95-2(CAS DataBase Reference) |
| FDA UNII | 0FV534BKEV |
| NIST Chemistry Reference | chlorotris(triphenylphosphine)rhodium(14694-95-2) |
| EPA Substance Registry System | Rhodium, chlorotris(triphenylphosphine)-, (SP-4-2)- (14694-95-2) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H317-H413 | |||||||||
| Precautionary statements | P261-P272-P273-P280-P302+P352-P333+P313 | |||||||||
| Hazard Codes | C,Xi | |||||||||
| Risk Statements | 34-36/38 | |||||||||
| Safety Statements | 22-24/25-37/39-28A-26-15-45-36/37/39 | |||||||||
| RIDADR | 1759 | |||||||||
| WGK Germany | 1 | |||||||||
| F | 8-10-23 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 28439090 | |||||||||
| NFPA 704 |
|
Tris(triphenylphosphine)rhodiu price More Price(51)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 199982 | Tris(triphenylphosphine)rhodium(I) chloride | 14694-95-2 | 1g | $260 | 2024-03-01 | Buy |
| Sigma-Aldrich | 199982 | Tris(triphenylphosphine)rhodium(I) chloride | 14694-95-2 | 5g | $1200 | 2024-03-01 | Buy |
| TCI Chemical | T0931 | Tris(triphenylphosphine)rhodium(I) Chloride >98.0%(T) | 14694-95-2 | 1g | $159 | 2024-03-01 | Buy |
| TCI Chemical | T0931 | Tris(triphenylphosphine)rhodium(I) Chloride >98.0%(T) | 14694-95-2 | 5g | $363 | 2021-12-16 | Buy |
| Alfa Aesar | 010468 | Chlorotris(triphenylphosphine)rhodium(I), 97% | 14694-95-2 | 1g | $264 | 2023-06-20 | Buy |
Tris(triphenylphosphine)rhodiu Chemical Properties,Uses,Production
Reactions
- A homogeneous hydrogenation catalyst which operates under mild conditions.
- Catalyst for the decarbonylation of aldehydes.
- Catalyst for regio- and stereoselective allylic substitution reactions.
- Alkyne hydro-phosphorylation
- Heck-type reaction with α,β-unsaturated esters.
- Alkyne arylation
- Allylic alcohol-olefin coupling.
- Terminal alkenes from ketones.
- Rh-catalyzed isomerization of α-aryl propargyl alcohols to indanones.
- Reductive deprotection of silyl groups.
Chemical Properties
magenta crystals
Uses
suzuki reaction
Uses
Tris(triphenylphosphine)rhodiu is also known as Wilkinson's catalyst and is commonly used to catalyze the hydrogenation of alkenes. Tris(triphenylphosphine)rhodiu is also used in the catalytic hydroboration of alkenes with catecholborane and pinacolborane and the selective 1,4-reduction of α, β-unsaturated carbonyl compounds.
Uses
Homogeneous hydrogenation catalyst.
Flammability and Explosibility
Non flammable
Purification Methods
It forms dark burgundy crystals from hot EtOH after refluxing for 30minutes. When the solution is heated for only 5minutes, orange crystals are formed. Heating the orange crystals in EtOH yields red crystals. Crystallisation from Me2CO gives the orange crystals. The two forms have similar IR spectra, but the X-ray diffraction patterns are slighly different. [Osborne et al. J Chem Soc (A) 1711 1966, Osborne & Wilkinson Inorg Synth X 67 1967, Bennett & Donaldson Inorg Chem 16 655 1977.] The solubilities are as follows: in CH2Cl2 ~2% (25o), in toluene 0.2% (25o), and less soluble in Me2CO, MeOH, BuOH and AcOH, but insoluble in pet ethers and cyclohexane. It reacts with donor solvents such as pyridine, DMSO and MeCN.
Tris(triphenylphosphine)rhodiu Preparation Products And Raw materials
Global( 416)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Weifang Wehibest Supply Chain Co.,Ltd | +8613583620690 | hotspotbiotech@163.com | China | 926 | 58 |
| Shanghai UCHEM Inc. | +862156762820 +86-13564624040 | sales@myuchem.com | China | 6710 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15928 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3012 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
| AB PharmaTech,LLC | 323-480-4688 | United States | 989 | 55 | |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Nanjing Dolon Biotechnology Co.,Ltd. | 18905173768 | sales@dolonchem.com | CHINA | 2972 | 58 |
View Lastest Price from Tris(triphenylphosphine)rhodiu manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-02-23 | Tris(triphenylphosphine)rhodium(I) chloride
14694-95-2
|
US $52.00-806.00 / g | 1g | 0.98 | 10kg | Shanghai UCHEM Inc. | |
 |
2023-11-01 | Tris(triphenylphosphine)chlororhodium
14694-95-2
|
US $0.00-0.00 / g | 0.10000000149011612g | 11.1%Rh | 10kg | Hangzhou ICH Biofarm Co., Ltd | |
 |
2023-08-14 | Tris(triphenylphosphine)rhodiu
14694-95-2
|
US $0.00-0.00 / g | 1g | 0.99 | 100kg | Weifang Wehibest Supply Chain Co.,Ltd |
-
- Tris(triphenylphosphine)rhodium(I) chloride
14694-95-2
- US $52.00-806.00 / g
- 0.98
- Shanghai UCHEM Inc.
-
- Tris(triphenylphosphine)chlororhodium
14694-95-2
- US $0.00-0.00 / g
- 11.1%Rh
- Hangzhou ICH Biofarm Co., Ltd
-
- Tris(triphenylphosphine)rhodiu
14694-95-2
- US $0.00-0.00 / g
- 0.99
- Weifang Wehibest Supply Chain Co.,Ltd
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DECARBON
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Rhodium(I) tris(triphenylphosphine) chloride, Wilkinsons catalyst
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Chlorotri (triphenyl
Tris(triphenylphosphine)rhodium(I) chloride, (trace metal basis), 99.99%
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Tris(triphenylphosphine)rhodiumchloride
Tris(triphenylphosphino)chlororhodium
RHODIUM(I) TRIS(TRIPHENYLPHOSPHINE) CHLORIDE
RHODIUM TRIS(TRIPHENYL-PHOSPHINE)CHLORIDE
Chlorotri (triphenylphosphine) rhodium
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Tris(tripehnylphosphine)rhodium(I)chloride
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NSC 124140
Tris(triphenylphosphine)chlororhodiu
Chlorotris(triphenylphosphine)rhodium(I)
Wilkinson Catalyst
Chlorotris(triphenylphosphine) RhodiuM(I) [ilkinson Catalyst
Tris(triphenylphosphine)rhodiuM(I) chloride, 99.99%, (trace Metal basis)
TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CHLOR
Tris(triphenylphosphine)chloro
Tris(triphenylphosphine)rodiuM(I) Chloride
Tetra(triphenylphosphine)-RhodiuM(I) chloride
Tris(triphenylphosphine)rhodium(Ⅰ) chlorideTris(triphenylphosphine)rhodium(Ⅰ) chloride
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Tris(triphenylphosphine)rhodium(I) chloride (11% Rh) for synthesis
chloridotris(triphenylphosphine)rhodium(I)
Rh11.1%Tris(triphenylphosphine)chlororhodium(I I)
Tris(triphenylphosphine)rhodiu
TRIS(TRIPHENYLPHOSPHINE)RH
Chlorotris(triphenylphosphine)rhodium(Ⅰ)
phosphine)rhodium(I) chL