ChemicalBook >> CAS DataBase List >>9-Anthracenylmethyl methacrylate

9-Anthracenylmethyl methacrylate

CAS No.
31645-35-9
Chemical Name:
9-Anthracenylmethyl methacrylate
Synonyms
Anthracen-9-ylmethyl methacrylate;ANMA;AMMA;DK738;POLYFLUOR(R) 407;(9-ANTHRYL) METHACRYLATE;9-Anthrylmethyl Methacrylate;9-ANTHRACENYLMETHYL METHACRYLATE;9-ANTHRACENE METHYL METHACRYLATE;9-Anthrylmethyl Methacrylate >
CBNumber:
CB3192708
Molecular Formula:
C19H16O2
Molecular Weight:
276.33
MDL Number:
MFCD00673247
MOL File:
31645-35-9.mol
MSDS File:
SDS
Last updated:2023-04-27 16:27:43

9-Anthracenylmethyl methacrylate Properties

Melting point 80-85 °C (lit.)
Boiling point 443.0±14.0 °C(Predicted)
Density 1.159±0.06 g/cm3(Predicted)
storage temp. Keep Cold
solubility Acetone, Chloroform, Dichloromethane, hot Ethanol, Ethyl Acetate,
form Solid
color Pale Yellow
InChIKey MJYSISMEPNOHEG-UHFFFAOYSA-N
CAS DataBase Reference 31645-35-9(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H318
Precautionary statements  P280-P305+P351+P338
Hazard Codes  Xi,F
Risk Statements  41
Safety Statements  25-26-36/39
WGK Germany  3
HS Code  29161290

9-Anthracenylmethyl methacrylate price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 579017 Poly(9-anthracenylmethyl methacrylate) 31645-35-9 100mg $252 2023-06-20 Buy
Sigma-Aldrich 578207 9-Anthracenylmethyl methacrylate 95% 31645-35-9 100mg $326 2023-06-20 Buy
TCI Chemical A2645 9-Anthrylmethyl Methacrylate >98.0%(HPLC) 31645-35-9 1g $286 2024-03-01 Buy
Usbiological 002786 9-Anthryl Methacrylate 31645-35-9 1g $403 2021-12-16 Buy
TRC A685000 9-Anthrylmethyl Methacrylate 31645-35-9 2.5g $1320 2021-12-16 Buy
Product number Packaging Price Buy
579017 100mg $252 Buy
578207 100mg $326 Buy
A2645 1g $286 Buy
002786 1g $403 Buy
A685000 2.5g $1320 Buy

9-Anthracenylmethyl methacrylate Chemical Properties,Uses,Production

Description

9-Anthrylmethyl Methacrylate is a fluorescent copolymer used as an optic fiber sensor for determination of Tetracycline.

Chemical Properties

Pale Yellow Crystals

Uses

A fluorescent copolymer as optic fiber sensor for determination of Tetracycline.

Synthesis

9-Anthracenylmethyl methacrylate (9-AMM)is generally synthesized by reacting 9-Anthracene-methanol with methylene chloride and methacryloyl chloride in the presence of a base triethylamine. 
Experimental procedrure: 9-Anthracene-methanol 9.3g (45mmol), methylene chloride 60ml and methacryloyl chloride 8g (77mmol) were charged into a 300ml three-necked flask equipped with a stirrer and thermometer. Methylene chloride 10ml solution of triethylamine 6.0g (59mmol) was added dropwise while cooling the slurry with ice water. After completion of the dropwise addition, the slurry became a homogeneous solution. Then allowed to stand overnight while cooling in ice water. The hydrochloride salt of triethylamine floating on the liquid surface and water 30ml were sufficiently added. Further stirred to dissolve. Again washed with water 30ml, the obtained methylene chloride solution was dried over anhydrous sodium sulfate. Further methanol was added to the filtered methylene chloride solution 100ml, stored in the refrigerator and recrystallized. After 2 days, the precipitated crystals were suction filtered and dried. Pale yellow microcrystals 7.1g were obtained. Analysis results of the obtained substance are as shown below, this compound was confirmed to be 9-Anthracenylmethyl methacrylate by 1H-NMR, IR. Yield 58mol%. Melting point: 59-60 ° CIR (KBr, cm-1): 1715, 1624, 1450, 1320, 1296, 1164, 1150, 1060, 1008, 964, 946, 892, 740, 700, 640, 600, 568, 500. 1H-NMR (CDCl3, ppm): δ1.92 (s, 3H, methyl), 5.50 (s, 1H, vinyl), 6.05 (s, 1H, vinyl), 6.22 (s, 2H, methylene group), 7.44-7.60 (m, 4H, anthracene ring), 8.03 (d, J = 10Hz, 2H, anthracene ring), 8, 38 (d, J = 10Hz, 2H, anthracene ring), 8.51 (s, 1H, anthracene ring).
synthesis of 	9-Anthracenylmethyl methacrylate

1468-95-7
920-46-7
31645-35-9
Synthesis of 9-Anthracenylmethyl methacrylate from 9-Anthracenemethanol and Methacryloyl chloride

9-Anthracenylmethyl methacrylate Preparation Products And Raw materials

Global( 166)Suppliers
Supplier Tel Email Country ProdList Advantage
Changzhou waston chemical technology Co.,Ltd
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ATK CHEMICAL COMPANY LIMITED
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Richest Group Ltd
18017061086 oled@richest-group.com CHINA 5601 58
Fuxin Pharmaceutical
+86-021-021-50872116 +8613122107989 contact@fuxinpharm.com China 10297 58
SIMAGCHEM CORP
+86-13806087780 sale@simagchem.com China 17367 58

View Lastest Price from 9-Anthracenylmethyl methacrylate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
9-Anthracenylmethyl methacrylate pictures 2024-04-29 9-Anthracenylmethyl methacrylate
31645-35-9
US $0.00-0.00 / kg 1kg 98%+ 10000kgs per Month Shanghai Qyubiotech Co., Ltd.
9-Anthracenylmethyl methacrylate pictures 2022-10-12 9-Anthracenylmethyl methacrylate
31645-35-9
US $0.00 / L 1L 98% According to customer requirements Changzhou waston chemical technology Co.,Ltd
9-Anthracenylmethyl methacrylate pictures 2019-07-06 9-Anthracenylmethyl methacrylate
31645-35-9
US $1.00 / KG 1KG 98% 100KG Career Henan Chemical Co
ANMA 9-ANTHRACENE METHYL METHACRYLATE (9-ANTHRYL) METHACRYLATE 9-ANTHRACENYLMETHYL METHACRYLATE 9-Anthrylmethyl Methacrylate POLY(9-ANTHRACENYLMETHYL METHACRYLATE) POLYFLUOR(R) 407 2-Methyl-2-propenoic Acid 9-AnthrylMethyl Ester 9-(MethacryloyloxyMethyl)anthracene Methacrylic Acid 9-AnthrylMethyl Ester AMMA [9-Anthrylmethyl Methacrylate] AMMA 9-Anthracenylmethyl methacrylate 9-Anthrylmethyl Methacrylate > 2-Propenoic acid, 2-methyl-, 9-anthracenylmethyl ester Anthracen-9-ylmethyl methacrylate DK738 AMMA anthracen-9-ylmethyl 2-methylprop-2-enoate 31645-35-9 31654-35-9 Esters Organic Building Blocks Carbonyl Compounds C12 to C63 Building Blocks Fluorescent Monomers Photoluminescent Materials Building Blocks C12 to C63 Carbonyl Compounds Chemical Synthesis Materials Science Organic and Printed Electronics Organic Building Blocks Photonic and Optical Materials Aromatics Fluorescent Labels & Indicators Photoluminescent Materials > Fluorescent Polymers Photonic and Optical Materials C12 to C63Photonic and Optical Materials Carbonyl Compounds Esters Photoluminescent Materials > Fluorescent Monomers Aromatics Compounds