ChemicalBook >> CAS DataBase List >>4-Methoxybenzylchloride

4-Methoxybenzylchloride

CAS No.
824-94-2
Chemical Name:
4-Methoxybenzylchloride
Synonyms
PMBCl;4-METHOXYBENZYL CHLORIDE;P-METHOXYBENZYL CHLORIDE;PBMCl;4-(Chloromethyl)-1-methoxybenzene;4-Methoxybenzylchloride, stabilized, 98% 5GR;p-Anisyl chloride;NSC 172955;ANISYL CHLORIDE;AKOS BBS-00003861
CBNumber:
CB3330683
Molecular Formula:
C8H9ClO
Molecular Weight:
156.61
MDL Number:
MFCD00000915
MOL File:
824-94-2.mol
MSDS File:
SDS
Last updated:2024-04-08 13:48:25

4-Methoxybenzylchloride Properties

Melting point −1 °C(lit.)
Boiling point 117-118 °C14 mm Hg(lit.)
Density 1.155 g/mL at 25 °C(lit.)
refractive index n20/D 1.548(lit.)
Flash point 229 °F
storage temp. Inert atmosphere,2-8°C
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
form Liquid
color Clear colorless to pale yellow
Water Solubility slowly decomposes
Stability Moisture Sensitive
InChIKey MOHYOXXOKFQHDC-UHFFFAOYSA-N
CAS DataBase Reference 824-94-2(CAS DataBase Reference)
FDA UNII Q500ZS03TI
NIST Chemistry Reference «alpha»-Chloro-4-methoxytoluene(824-94-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H290-H314
Precautionary statements  P234-P260-P264-P280-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P390-P405-P406-P501
Hazard Codes  C
Risk Statements  34
Safety Statements  26-27-36/37/39-45
RIDADR  UN 3265 8/PG 3
WGK Germany  3
10-19-21
Autoignition Temperature 109℃
Hazard Note  Corrosive
TSCA  No
HazardClass  8
PackingGroup  III
HS Code  29093090
NFPA 704
1
3 0

4-Methoxybenzylchloride price More Price(24)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical M0676 4-Methoxybenzyl Chloride (stabilized with Amylene) >98.0%(GC)(T) 824-94-2 25mL $93 2024-03-01 Buy
TCI Chemical M0676 4-Methoxybenzyl Chloride (stabilized with Amylene) min. 98.0 % 824-94-2 100ML $267 2024-03-01 Buy
TRC M261105 4-MethoxybenzylChloride(Stabilized) 824-94-2 5g $95 2021-12-16 Buy
Chem-Impex 00213 4-Methoxybenzyl chloride,Contains Potassium carbonate as stabilizer. ≥ 99% (GC) 824-94-2 100G $120 2021-12-16 Buy
AK Scientific K468 4-Methoxybenzylchloride,contains1%potassiumcarbonateasstabilizer 824-94-2 100g $154 2021-12-16 Buy
Product number Packaging Price Buy
M0676 25mL $93 Buy
M0676 100ML $267 Buy
M261105 5g $95 Buy
00213 100G $120 Buy
K468 100g $154 Buy

4-Methoxybenzylchloride Chemical Properties,Uses,Production

Chemical Properties

Colorless liquid

Uses

O/N protecting group reagent which can be mildly oxidatively cleaved, e.g., with ceric ammonium nitrate.

Synthesis Reference(s)

Journal of Medicinal Chemistry, 20, p. 190, 1977 DOI: 10.1021/jm00212a002
The Journal of Organic Chemistry, 53, p. 3634, 1988 DOI: 10.1021/jo00250a048

General Description

4-Methoxybenzyl chloride undergoes mild oxidative claevage with ceric ammonium nitrate.

Purification Methods

Purify 4-anisyl chloride by fractional distillation under vacuum, and the middle fraction is redistilled at 10-6 mm at room temperature by intermittent cooling of the receiver in liquid N2, and the middle fraction is collected. [Mohammed & Kosower J Am Chem Soc 93 2709 1971, Beilstein 6 IV 2137.]

105-13-5
824-94-2
Synthesis of 4-Methoxybenzylchloride from 4-Methoxybenzyl alcohol
Global( 497)Suppliers
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Nanjing Qiangshan New Material Co.,Ltd.
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View Lastest Price from 4-Methoxybenzylchloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Methoxybenzylchloride pictures 2024-04-08 4-Methoxybenzylchloride
824-94-2
US $10.00-1.00 / kg 1kg 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
4-Methoxybenzylchloride pictures 2023-07-26 4-Methoxybenzylchloride
824-94-2
US $100.00 / kg 1kg 99% 500t/month Henan Bao Enluo International TradeCo.,LTD
4-Methoxybenzylchloride pictures 2023-04-18 4-Methoxybenzylchloride
824-94-2
US $5.00-2.00 / KG 1KG 99% 10000kg Hebei Guanlang Biotechnology Co,.LTD
alpha-Chloro-4-methoxytoluene Anisole, p-(chloromethyl)- Benzene, 1-(chloromethyl)-4-methoxy- p-(Chloromethyl)anisole Anisyl Chloride 4-(Chloromethyl)anisole 4-Methoxybenzyl chloride contains potassiuM carbonate as stabilizer, 98% The Methoxy benzyl chloride para-chloromethylanisole METHOXYBENZYLCHLORIDE(P-) 1-CHLOROMETHYL-4-METHOXYBENZENE AKOS BBS-00003861 ANISYL CHLORIDE 4-(CHLOROMETHYL)ANISOL 4-(CHLOROMETHYL)ANISOLE P-methoxyl benzylchloride 4-Methoxybenzylchloride99% 4-Methoxybenzylchloride 99% 4-Methoxybenzene methyl chloride α-Chloro-4-methoxytoluene 4-Methoxybenzylchloride, stabilized, 98% 4-METHOXYBENZYL CHLORIDE (STABILIZED WITH CALCIUM CARBONATE) 4-METHYOXYBENZYL CHLORIDE 4-METHOXYBENZYLCHLORIDE / 4-(CHLOROMETHYL)ANISOLE 4) PARA METHOXY BENZYL CHLORIDE 1-(Chloromethyl)-4-methoxybenzene, 4-(Chloromethyl)anisole 4-Methoxybenzyl Chloride (stabilized with Amylene) 4-Methoxybenzylchloride, 98%, stabilized 4-Chloromethylphenyl methyl ether 4-Methoxy-1-(chloromethyl)benzene 4-Methoxybenzylchloride ,98% 4-Methoxybenzylchlor 4-Methoxybenzylchloride, stabilized, 98% 25GR 4-Methoxybenzyl chloride, 98%, stabilized with potassium carbonate 4-Methoxybenzyl chloride, 98% (Stabilized with Calcium carbote) 4-Methoxybenzyl chloride, 98%, for synthesis 4-MethoxybenzylChloride(stabilizedwithAmylene)> 4-methoxychlorobenzyl 1-(Chloromethyl)-4-(methyloxy)benzene 4-(Chloromethyl)anisole (stabilized with Amylene) 4-Methyloxybenzyl chloride Anisyl Chloride (stabilized with Amylene) NSC 172955 p-(Chloromethyl)(methoxy)benzene α-Chloro-4-methoxytoluene α-Chloro-p-methoxytoluene P-METHOXYBENZYL CHLORIDE p-Anisyl chloride 4-METHOXYBENZYL CHLORIDE PMBCl PBMCl 4-Methoxybenzylchloride, stabilized, 98% 5GR 4-(Chloromethyl)-1-methoxybenzene p-methoxychlorbenzyl 4-Methoxy Benzyl chloride, contains 1% potassium carbonate as stabilizer, 95% Monensin Impurity 4 4-Methoxybenzyl Chloride (stabilized with Potassium carbonate) 824-94-2 C8H9ClO