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(1R)-(+)-ALPHA-PINENE

CAS No.
7785-70-8
Chemical Name:
(1R)-(+)-ALPHA-PINENE
Synonyms
(1R)-2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene;FEMA 2902;α-Pinene dextro;(1R,5R)-2-6,6-TRIMETHYL-BICYCLO[3.1.1]HEPT-2-ENE;Alpha Pinene Dextro;2,6,6-trimethyl-,(1R)-Bicyclo[3.1.1]hept-2-ene;Pinene,95%;(+)-A-PINENE;(+)-à-pinene;(+)-α-Pinene
CBNumber:
CB3350144
Molecular Formula:
C10H16
Molecular Weight:
136.23
MDL Number:
MFCD00001346
MOL File:
7785-70-8.mol
MSDS File:
SDS
Last updated:2024-03-20 19:26:33

(1R)-(+)-ALPHA-PINENE Properties

Melting point −62 °C(lit.)
Boiling point 155-156 °C(lit.)
Density 0.858 g/mL at 20 °C(lit.)
vapor pressure 5 hPa (25 °C)
FEMA 2902 | ALPHA-PINENE
refractive index n20/D 1.465(lit.)
Flash point 91 °F
storage temp. Store at +2°C to +8°C.
form Liquid
color Clear colorless
Odor at 10.00 % in dipropylene glycol. harsh terpene aromatic minty
Odor Type herbal
optical activity [α]22/D +47.1°, neat
explosive limit 0.8-6%(V)
Water Solubility Soluble in Ether, Alcohols, Chloroform. Not miscible in water.
JECFA Number 1329
Merck 14,7445
BRN 3648264
Dielectric constant 2.7(20℃)
InChIKey GRWFGVWFFZKLTI-UHFFFAOYSA-N
LogP 4.44-4.46 at 20-37℃
CAS DataBase Reference 7785-70-8(CAS DataBase Reference)
FDA UNII H6CM4TWH1W
EPA Substance Registry System Bicyclo[3.1.1]hept-2-ene, 2,6,6-trimethyl-, (1R,5R)- (7785-70-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H226-H304-H315-H317-H400
Precautionary statements  P210-P273-P280-P301+P310+P331-P302+P352
Hazard Codes  Xi
Risk Statements  10-36/37/38
Safety Statements  26-36-16-23
RIDADR  UN 2368 3/PG 3
WGK Germany  3
RTECS  DT7000000
10
Autoignition Temperature 491 °F
TSCA  Yes
HS Code  2902 19 00
HazardClass  3
PackingGroup  III
NFPA 704
3
3 0

(1R)-(+)-ALPHA-PINENE price More Price(27)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich W290238 (1R)-(+)-α-Pinene 97%, FG 7785-70-8 1kg $96.2 2024-03-01 Buy
Sigma-Aldrich W290238 (1R)-(+)-α-Pinene 97%, FG 7785-70-8 8kg $349 2024-03-01 Buy
Sigma-Aldrich W290238 (1R)-(+)-α-Pinene 97%, FG 7785-70-8 20kg $568 2024-03-01 Buy
Sigma-Aldrich 268070 (+)-α-Pinene ≥99% 7785-70-8 5g $73.3 2024-03-01 Buy
Sigma-Aldrich 8.18632 (1R)-(+)-α-Pinene for synthesis 7785-70-8 100mL $82.7 2024-03-01 Buy
Product number Packaging Price Buy
W290238 1kg $96.2 Buy
W290238 8kg $349 Buy
W290238 20kg $568 Buy
268070 5g $73.3 Buy
8.18632 100mL $82.7 Buy

(1R)-(+)-ALPHA-PINENE Chemical Properties,Uses,Production

Chemical Properties

(1R)-(+)-ALPHA-PINENE is Clear colourless liquid

Uses

(1R)-(+)-α-Pinene is used in hydroboration reactions and the reduction of ketones.

Uses

(+)-alpha-Pinene is employed in the preparation of chiral hydroboration reagents. It is a bronchodilator in humans. α-Pinene is an anti-inflammatory and used as a broad-spectrum antibiotic.It exhibits activity as an acetylcholinesterase inhibitor, aiding memory. It is a biosynthetic base for CB2 ligands, such as HU-308.

Uses

(+)-α-Pinene has been used in a tolerance testing procedure to detect the genes in Marinobacter aquaeolei, for engineering a pinene tolerant Escherichia coli.

Definition

ChEBI: The (+)-enantiomer of alpha-pinene.

General Description

(+)-α-Pinene is a monoterpenoid compound mainly found in Pinus species.

Flammability and Explosibility

Flammable

Purification Methods

(1R)-(+)-ALPHA-PINENE is isomerised by heat, acids and certain solvents. It should be distilled under reduced pressure under nitrogen and stored in the dark. It has been purified via the nitrosochloride [Waterman et al. Recl Trav Chim, Pays-Bas 48 1191 1929]. For purification of optically active forms see Lynn [J Am Chem Soc 91 361 1919].

64234-27-1
7785-70-8
Synthesis of (1R)-(+)-ALPHA-PINENE from [(1R,2S,3R,5R)-2,6,6-Trimethylbicyclo[3.1.1]hept-3-yl]borane
Global( 254)Suppliers
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Hebei Mojin Biotechnology Co., Ltd
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View Lastest Price from (1R)-(+)-ALPHA-PINENE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(1R)-(+)-alpha-Pinene pictures 2024-04-25 (1R)-(+)-alpha-Pinene
7785-70-8
US $5.00 / KG 1KG 99% 500mt/year Jinan Finer Chemical Co., Ltd
(1R)-(+)-alpha-Pinene pictures 2024-04-22 (1R)-(+)-alpha-Pinene
7785-70-8
US $20.00 / kg 1kg 99% 2000kg hebei hongtan Biotechnology Co., Ltd
(1R)-(+)-ALPHA-PINENE pictures 2023-09-23 (1R)-(+)-ALPHA-PINENE
7785-70-8
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
(+)-ALPHA-PINENE (MIXTURE OF ISOMERS) (1R,5R)-2-PINENE (1R)-(+)-ALPHA-PINENE (1R)-(+)-a-pinene (+)-A-PINENE D-ALPHA PINENE (1R)-(+)-α-Pinene, 98% (80+% e.e.) PINENE, (1R)-(+)-ALPHA- (1R)-(+)-α-Pinene (+)-alpha-Pinene >=99% (+)-α-Pinene, 98%,ee92% (1R)-pin-2-ene 6,6-trimethyl-(1theta)-bicyclo[3.1.1]hept-2-en Bicyclo[3.1.1]hept-2-ene, 2,6,6-trimethyl-, (1R)- (1R)-(+)-pin-2-ene (1R)-(+)-α-pinene (1R)-(+)-alpha-Pinene, 80% ee, 98% (1R)-(+)-alpha-Pinene,98%,80% ee (+)-α-Pinene, (1R,5R)-2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene, (1R,5R)-2-Pinene (1R,5R)-2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene, (1R,5R)-2-Pinene (1R)-(+)-Alpha-pinene, 98%, ee:80% [1R,5R,(+)]-Pin-2-ene Bicyclo3.1.1hept-2-ene, 2,6,6-trimethyl-, (1R,5R)- (+)-à-pinene PINENE, (1R)-(+)-alpha-(SG) (1R)-(+)-ALPHA-PINENE, 98% (91+% E.E.) (+)-ɑ-Pinene, 98% (1R)-(+)-α-Pinene ,99% (1R)-(+)-α-Pinene ,98% (+)-alpha-Pinene, tech. 90% (1R)-(+)-α-Pinene,(+)-α-Pinene, (1R,5R)-2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene, (1R,5R)-2-Pinene (+)-|á-Pinene (1R)-(+)-alpha-Pinene, 80% ee, 98% 100GR (1R)-(+)-alpha-Pinene, 80% ee, 98% 250GR (1R)-(+)-alpha-Pinene, 80% ee, 98% 500GR (1R)-(+)-α-Pinene (90% ee) (ir)-(+)-A-pinene Pinene,95% (1R)-(+)-ALPHA-PINENE, TECH., 85% (+)-ALPHA-PINENE, TERPENE STANDARD (1R)-(+)-ALPHA-PINENE, 99+% (97% EE/GLC) (1R)-(+)-ALPHA-PINENE 97+% (+)-a-Pinene    98% (1R)-(+)-α-Pinene> (1R,5R)-(+)-α-Pinene, 99+% (1R)-(+)-α-Pinene (97% ee) (1R)-(+)-A-PINENE FOR SYNTHESIS (+)-α-Pinene (+)-alpha-Pinene 98% (1R)-(+)-α-Pinene Alpha Pinene Dextro 7785-70-8 (1R,5R)-2-6,6-TRIMETHYL-BICYCLO[3.1.1]HEPT-2-ENE FEMA 2902 2,6,6-trimethyl-,(1R)-Bicyclo[3.1.1]hept-2-ene (1R)-2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene α-Pinene dextro Alpha Pinene Dextro (1R)-(+)-α-Pinene (90% ee)